Conical parametric scattering of a single extraordinary beam in BaTiO3 crystal

In this paper, the parametric scattering of a single extraordinary polarized beam of laser in BaTiO₃ photorefractive crystal has been investigated experimentally and theoretically. The resulting pattern consists of beam fanning, isotropic ring, and anisotropic one. Among all parts of scattering pattern, isotropic ring has not been studied as much as beam fanning and anisotropic ring, and there still are some differences in reports about it. Therefore, the study has mainly focused on this part. In this experimental configuration, isotropic ring is just visible in positive angles although the other parts of parametric scattering pattern can be visible from behind and in front of the crystal. In addition to steady state pattern in forward and backward directions, its transient behavior with the rotation of crystal has been studied. The results of experiments have been analyzed carefully, and their theoretical explanations have been presented based on the standard theory of parametric scattering in photorefractive crystals. It has been shown that this configuration corresponds to the so called parametric B-process scattering.     

Numerical solutions of the acoustic eigenvalue equation in the rectangular room with arbitrary (uniform) wall impedances

Two numerical procedures for finding the acoustic eigenvalues in the rectangular room with arbitrary (uniform) wall impedances are developed. One numerical procedure applies Newton's method. Here, starting with soft walls, the eigenvalues are found by increasing the impedances of each wall pair in small increments up to the terminal impedances. Another procedure poses the eigenvalue problem as one of homotopic continuation from a non-physical reference configuration in which all eigenvalues are known and obvious. The continuation is performed by the numerical integration of two differential equations. The latter procedure was found to be faster and finds all possible solutions. The set of eigenvalues allowed the room modal natural frequencies and damping constants to be obtained. From sound decays measured in a hard-walled rectangular room, and from the collective-modal-decay curve, the impedances of the hard walls are estimated. These are then used to find the reverberation times of the modes in the room with the floor lined with sound absorbing material of known acoustic impedance. It was found that a single reverberation time, for all modes, is only supported in the rectangular room with hard walls and at the higher frequency bands, consistent with Sabine's theory, which assumes a diffuse sound field. In the rectangular room with hard walls and at the lower frequency bands, and in the rectangular room with the floor lined with sound absorbing material and for all frequency bands, modes with rather distinctive reverberation times may produce sound decays not always consistent with Sabine's prediction.     

The cyclodimerisation of 3-methyl-2-butenenitrile

3-Methyl-2-butenenitrile (1) cyclodimerised on treatment with lithium diisopropylamide in dimethoxyethane at temperatures between ?78°C and 0°C to 3-amino-4-cyano-1,5,5-trimethyl-1,3-cyclohexadiene (2) the structure of which was established by acid hydrolysis to the known 4-cyano-1,5,5-trimethyl-1-cyclohexene-3-one (3).     

Predicting reverberation times in a simulated classroom

By varying the sound-absorption treatments in a simulated classroom, experimental results were compared with analytical and computer predictions of reverberation time. Analytical predictions were made with different absorption exponents, which are the result of different weighting procedures involving room surface areas and the sound-absorption coefficients. Sound scattering was found to influence measured reverberation times. With the amount of sound scattering provided, more accurate analytical predictions were obtained with absorption exponents that give reverberation times longer than those obtained with the Sabine absorption exponent, which consistently underpredicted reverberation times. However, none of the absorption exponents could be singled out as more adequate because of similar average accuracy. Computer predictions of reverberation time were accomplished with two commercially available ray-based programs, RAYNOISE 3.0 and ODEON 2.6, with specular and calibrated diffuse reflection procedures. Neither type of procedure, in either program, was more accurate than the best analytical predictions. With RAYNOISE, neither the specular nor the calibrated diffuse reflection procedure could be singled out as more adequate. For ODEON, the calibrated diffuse reflection procedure gave consistently more accurate predictions than its specular reflection procedure, with the best accuracy of the computer predictions.     

A study of the influence of mounting conditions on the measured sound absorption in laboratory tests of suspended ceilings

This letter presents the results of an investigation into the influence of mounting conditions on the measured sound absorption coefficients of a suspended ceiling specimen. A series of measurements and analyses were carried out using a fixed standard sample, varying independently different mounting parameters and introducing controlled leaks. A correction of room volume in the calculation of the sound absorption coefficients was also examined. The tests were carried out in accordance with the ISO 354:2003 standard (International Organisation for Standardisation, Geneva, 2003), using the type E mounting. The test specimen consisted of fiberglass wool panels covered with a plastic film. Some of the experiments resulted in no statistically significant alteration. This included, unexpectedly, the sealing requirements of E type mountings.     

Self-chemical ionization of diethylzinc

The self-chemical ionization of diethylzinc is examined by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry and semiempirical molecular orbital calculations. Electron impact of diethylzinc neutral produces the radical cation, C(4)H(15)Zn(+) (m/z x 122), which reacts further with the neutral (C(2)H(5))(2)Zn to give the following product ions: Zn(+) (m/z x 64), C(2)H(5)Zn(+) (m/z x 93), C(4)H(9)Zn(+) (m/z x 121), C(4)H(11)Zn(2)(+) (m/z x 187), and C(6)H(15)Zn(2)(+) (m/z x 215). To determine the structure and pathways for production of these ions, monoisotopic (12)C(4)H(15)(64)Zn(+), (64)Zn(+) and (12)C(2)H(5)(64)Zn(+) were individually isolated and reacted with the neutral background. We also performed semiempirical molecular orbital calculations (ZINDO/1). The molecular orbital calculations and experimental data are consistent in predicting that the ethyl group on the diethylzinc cation carries the positive charge. Copyright 1999 John Wiley & Sons, Ltd.     

怀孕期头发中一些元素含量的变化趋势

用同步辐射激发X射线荧光分析,对11个产妇怀孕期间头发内一些元素含量的变化趋势进行了测量,在各自对比的基础上,得到了一些结果。     

Reverberation time and maximum background-noise level for classrooms from a comparative study of speech intelligibility metrics

Speech intelligibility metrics that take into account sound reflections in the room and the background noise have been compared, assuming diffuse sound field. Under this assumption, sound decays exponentially with a decay constant inversely proportional to reverberation time. Analytical formulas were obtained for each speech intelligibility metric providing a common basis for comparison. These formulas were applied to three sizes of rectangular classrooms. The sound source was the human voice without amplification, and background noise was taken into account by a noise-to-signal ratio. Correlations between the metrics and speech intelligibility are presented and applied to the classrooms under study. Relationships between some speech intelligibility metrics were also established. For each noise-to-signal ratio, the value of each speech intelligibility metric is maximized for a specific reverberation time. For quiet classrooms, the reverberation time that maximizes these speech intelligibility metrics is between 0.1 and 0.3 s. Speech intelligibility of 100% is possible with reverberation times up to 0.4-0.5 s and this is the recommended range. The study suggests "ideal" and "acceptable" maximum background-noise level for classrooms of 25 and 20 dB, respectively, below the voice level at 1 m in front of the talker.