A measure of dependence for stable distributions

A distance based measure of dependence is proposed for stable distributions that completely characterizes independence for a bivariate stable distribution. Properties of this measure are analyzed, and contrasted with the covariation and co-difference. A sample analog of the measure is defined and demonstrated on simulated and real data, including time series and distributions in the domain of attraction of a stable law.     

Coupled-states statistical investigation of vibrational and rotational relaxation of OH(2pi) by collisions with atomic hydrogen

We report state-to-state cross sections and thermal rate constants for vibrational and rotational relaxation of OH(2pi) by collision with H atoms. The cross sections are calculated by the coupled-states (CS) statistical method including the full open-shell character of the OH + H system. Four potential energy surfaces (PESs) ((1,3)A' and (1,3)A') describe the interaction of OH(X2pi) with H atoms. Of these, three are repulsive, and one (1A') correlates with the deep H2O well. Consequently, rotationally and ro-vibrationally inelastic scattering of OH in collisions with H can occur by scattering on the repulsive PESs, in a manner similar to the inelastic scattering of OH by noble gas atoms, or by collisions which enter the H2O well and then reemerge. At 300 K, we predict large (approximately 1 x 10(-10) cm3 molecule(-1) s(-1)) vibrational relaxation rates out of both v = 2 and v = 1, comparable to earlier experimental observations. This anomalously fast relaxation results from capture into the H2O complex. There exists a significant propensity toward formation of OH in the pi(A') lambda-doublet level. We also report state-resolved cross sections and rate constants for rotational excitation within the OH v = 0 manifold. Collisional excitation from the F1 to the F2 spin-orbit manifold leads to an inverted lambda-doublet population.     

The interval Shapley value: an axiomatization

The Shapley value, one of the most widespread concepts in operations Research applications of cooperative game theory, was defined and axiomatically characterized in different game-theoretic models. Recently much research work has been done in order to extend OR models and methods, in particular cooperative game theory, for situations with interval data. This paper focuses on the Shapley value for cooperative games where the set of players is finite and the coalition values are compact intervals of real numbers. The interval Shapley value is characterized with the aid of the properties of additivity, efficiency, symmetry and dummy player, which are straightforward generalizations of the corresponding properties in the classical cooperative game theory.     

On dominance core and stable sets for cooperative ellipsoidal games

Abstract

The allocation problem of rewards or costs is a central question for individuals and organizations contemplating cooperation under uncertainty. The involvement of uncertainty in cooperative games is motivated by the real world where noise in observation and experimental design, incomplete information and further vagueness in preference structures and decision-making play an important role. The theory of cooperative ellipsoidal games provides a new game theoretical angle and suitable tools for answering this question. In this paper, some solution concepts using ellipsoids, namely the ellipsoidal imputation set, the ellipsoidal dominance core and the ellipsoidal stable sets for cooperative ellipsoidal games, are introduced and studied. The main results contained in the paper are the relations between the ellipsoidal core, the ellipsoidal dominance core and the ellipsoidal stable sets of such a game.     

Organic/inorganic interfaced field-effect transistor properties with a novel organic semiconducting material

A novel 1,3,4-oxadiazole-substituted benzo[b]triphenylene was synthesized by three-step synthetic procedure and OFET device design was successfully designed after theoretical calculations made using Gaussian software. For investigating the field-effect properties of designed organic electronic device, a SiO₂ (300 nm) was thermally grown on p-Si wafer at 1000 °C as a dielectric layer and gate, source and drain contacts have been deposited using Au metal with physical vapour deposition. 1,3,4-Oxadiazole-substituted benzo[b]triphenylene was spin coated on the source and drain electrodes of our device, forming organic/inorganic interfaced field-effect transistors. Surface morphology and thin film properties were investigated using AFM. All electrical measurements were done in air ambient. The device showed a typical p-type channel behaviour with increasing negative gate bias voltage values. Our results have surprisingly shown that the saturation regime of this device has high mobility (μ_FET), excellent on/off ratio (I_on/I_off), high transconductance (g_m) and a small threshold voltage (V_Th). The values of μ_FET, I_on/I_off, g_m and V_Th were found as 5.02 cm²/Vs, 0.7 × 10³, 5.64 μS/mm and 1.37 V, respectively. These values show that our novel organic material could be a potential candidate for organic electronic device applications in the future.     

Cooperative games under interval uncertainty: on the convexity of the interval undominated cores

Uncertainty is a daily presence in the real world. It affects our decision making and may have influence on cooperation. Often uncertainty is so severe that we can only predict some upper and lower bounds for the outcome of our actions, i.e., payoffs lie in some intervals. A suitable game theoretic model to support decision making in collaborative situations with interval data is that of cooperative interval games. Solution concepts that associate with each cooperative interval game sets of interval allocations with appealing properties provide a natural way to capture the uncertainty of coalition values into the players’ payoffs. This paper extends interval-type core solutions for cooperative interval games by discussing the set of undominated core solutions which consists of the interval nondominated core, the square interval dominance core, and the interval dominance core. The interval nondominated core is introduced and it is shown that it coincides with the interval core. A straightforward consequence of this result is the convexity of the interval nondominated core of any cooperative interval game. A necessary and sufficient condition for the convexity of the square interval dominance core of a cooperative interval game is also provided.     

Synthesis and biological evaluation of structural variants of carbazoquinocin C

Some new structural variants of the alkaloid carbazoquinocin C were synthesized in a few steps with good to excellent yields. The key step comprises a cyclisation reaction of appropriate 2‐vinylindoles with oxalyl chloride. The carbazole‐3,4‐quinones are able to trap oxygen‐centred radicals. In some biological/biochemical assays some of these compounds exhibit extraordinary results including inhibition of cyclooxygenase‐1 and 5‐lipoxygenase in the μM‐range. Moreover some of the carbazoquinocin C‐variants inhibit significant oxidative damage of cellular DNA in nM‐range.     

Particle agglomeration and properties of nanofluids

The present study demonstrates the importance of actual agglomerated particle size in the nanofluid and its effect on the fluid properties. The current work deals with 5 to 100 nm nanoparticles dispersed in fluids that resulted in 200 to 800 nm agglomerates. Particle size distributions for a range of nanofluids are measured by dynamic light scattering (DLS). Wet scanning electron microscopy method is used to visualize agglomerated particles in the dispersed state and to confirm particle size measurements by DLS. Our results show that a combination of base fluid chemistry and nanoparticle type is very important to create stable nanofluids. Several nanofluids resulted in stable state without any stabilizers, but in the long term had agglomerations of 250 % over a 2 month period. The effects of agglomeration on the thermal and rheological properties are presented for several types of nanoparticle and base fluid chemistries. Despite using nanodiamond particles with high thermal conductivity and a very sensitive laser flash thermal conductivity measurement technique, no anomalous increases of thermal conductivity was measured. The thermal conductivity increases of nanofluid with the particle concentration are as those predicted by Maxwell and Bruggeman models. The level of agglomeration of nanoparticles hardly influenced the thermal conductivity of the nanofluid. The viscosity of nanofluids increased strongly as the concentration of particle is increased; it displays shear thinning and is a strong function of the level of agglomeration. The viscosity increase is significantly above of that predicted by the Einstein model even for very small concentration of nanoparticles.     

Instabilities in viscoelastic flow past a square cavity

Elastic flow transitions in viscoelastic flow past a square cavity adjacent to a channel are reported. The critical conditions for the onset of flow transitions and the qualitative and quantitative characterization of the secondary flows generated by the instability have been examined using streakline photography and instantaneous pressure measurements. Cellular type of instabilities inside the cavity is observed for flow rates beyond a critical value. Small and large scale eddies are observed at high flow rates. The flow inside the cavity and in the channel upstream and downstream of the cavity becomes weakly time-dependent for high flow rates.     

Cross sections and thermal rate constants for the isotope exchange reaction: D(2S)+OH(2Pi)-->OD(2Pi)+H(2S)

We report state-to-state and overall thermal rate constants for the isotope exchange reaction D((2)S)+OH((2)Pi)-->OD((2)Pi)+H((2)S) for 0 K相似文献