全文获取类型
收费全文 | 4766篇 |
免费 | 183篇 |
国内免费 | 88篇 |
专业分类
化学 | 3130篇 |
晶体学 | 30篇 |
力学 | 175篇 |
综合类 | 1篇 |
数学 | 655篇 |
物理学 | 1046篇 |
出版年
2023年 | 49篇 |
2022年 | 36篇 |
2021年 | 97篇 |
2020年 | 93篇 |
2019年 | 116篇 |
2018年 | 72篇 |
2017年 | 74篇 |
2016年 | 140篇 |
2015年 | 92篇 |
2014年 | 153篇 |
2013年 | 247篇 |
2012年 | 333篇 |
2011年 | 369篇 |
2010年 | 221篇 |
2009年 | 182篇 |
2008年 | 251篇 |
2007年 | 306篇 |
2006年 | 290篇 |
2005年 | 237篇 |
2004年 | 203篇 |
2003年 | 142篇 |
2002年 | 124篇 |
2001年 | 85篇 |
2000年 | 70篇 |
1999年 | 73篇 |
1998年 | 53篇 |
1997年 | 52篇 |
1996年 | 37篇 |
1995年 | 36篇 |
1994年 | 40篇 |
1993年 | 43篇 |
1992年 | 44篇 |
1991年 | 31篇 |
1990年 | 31篇 |
1989年 | 36篇 |
1988年 | 35篇 |
1987年 | 26篇 |
1985年 | 49篇 |
1984年 | 49篇 |
1983年 | 28篇 |
1982年 | 31篇 |
1981年 | 38篇 |
1980年 | 26篇 |
1979年 | 22篇 |
1978年 | 31篇 |
1977年 | 25篇 |
1976年 | 28篇 |
1975年 | 22篇 |
1974年 | 21篇 |
1973年 | 17篇 |
排序方式: 共有5037条查询结果,搜索用时 109 毫秒
1.
2.
3.
Jigneshkumar P. Patel Zou Guo Xiang Shaw Ling Hsu Andrew B. Schoch Sena Ada Carleen Dean Matsumoto 《Journal of Polymer Science.Polymer Physics》2015,53(21):1519-1526
A uniform dispersion of reactants is necessary to achieve a complete reaction involving multicomponents. In this study, we have examined the role of plasticizer in the reaction of two seemingly unlikely reactants: a highly crystalline hexamethylenetetramine (HMTA) and a strongly hydrogen bonded phenol formaldehyde resin. By combining information from NMR, infrared spectroscopy and differential scanning calorimetry, we were able to determine the role of specific intermolecular interactions necessary for the plasticizer to dissolve the highly crystalline HMTA and to plasticize the phenol formaldehyde resin in this crosslinking reaction. The presence of the plasticizer increased the segmental mobility, disrupted the hydrogen bonded matrix, and freed the hydroxyl units, which further increased the solubility of the HMTA. Both the endothermic and exothermic transitions are accounted for in the calorimetric data obtained. For the first time, it is possible to obtain the effective molar ratio of each component needed to complete the crosslinking reaction efficiently. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1519–1526 相似文献
4.
Briana L. Simms Nan Ji Indika Chandrasiri Mohammad Farid Zia Chinwe S. Udemgba Ravinder Kaur Jared H. Delcamp Alex Flynt Chalet Tan Davita L. Watkins 《Journal of polymer science. Part A, Polymer chemistry》2021,59(19):2177-2192
Here, we demonstrate the applicability of self-assembling linear-dendritic block copolymers (LDBCs) and their nanoaggregates possessing varied surfaces as therapeutic nanocarriers. These LDBCs are comprised of a hydrophobic, linear polyester chemically coupled to a hydrophilic dendron polyamidoamine (PAMAM)—the latter of which acts as the surface of the self-assembled nanoaggregate in aqueous media. To better understand how surface charge density affects the overall operability of these nanomaterials, we modified the nanoaggregate surface to yield cationic (NH3+), neutral (OH), and anionic (COO−) surfaces. The effect of these modifications on the physicochemical properties (i.e., size, morphology, and surface charge density), colloidal stability, and cellular uptake mechanism of the polymeric nanocarrier were investigated. This comparative study demonstrates the viability of nanoaggregates formed from PDLLA-PAMAM LDBCs to serve as nanocarriers for applications in drug delivery. 相似文献
5.
Ling-Yang Hsu Qiumin Liang Zhiheng Wang Hsin-Hung Kuo Wun-Shan Tai Shi-Jian Su Xiuwen Zhou Yi Yuan Yun Chi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(67):15375-15386
Iridium complexes bearing chelating cyclometalates are popular choices as dopant emitters in the fabrication of organic light-emitting diodes (OLEDs). In this contribution, we report a series of blue-emitting, bis-tridentate IrIII complexes bearing chelates with two fused five-six-membered metallacycles, which are in sharp contrast to the traditional designs of tridentate chelates that form the alternative, fused five-five metallacycles. Five IrIII complexes, Px-21 – 23 , Cz-4 , and Cz-5 , have been synthesized that contain a coordinated dicarbene pincer chelate incorporating a methylene spacer and a dianionic chromophoric chelate possessing either a phenoxy or carbazolyl appendage to tune the coordination arrangement. All these tridentate chelates afford peripheral ligand–metal–ligand bite angles of 166–170°, which are larger than the typical bite angle of 153–155° observed for their five-five-coordinated tridentate counterparts, thereby leading to reduced geometrical distortion in the octahedral frameworks. Photophysical measurements and TD-DFT studies verified the inherent transition characteristics that give rise to high emission efficiency, and photodegradation experiments confirmed the improved stability in comparison with the benchmark fac-[Ir(ppy)3] in degassed toluene at room temperature. Phosphorescent OLED devices were also fabricated, among which the carbazolyl-functionalized emitter Cz-5 exhibited the best performance among all the studied bis-tridentate phosphors, showing a maximum external quantum efficiency (EQEmax) of 18.7 % and CIEx,y coordinates of (0.145, 0.218), with a slightly reduced EQE of 13.7 % at 100 cd m−2 due to efficiency roll-off. 相似文献
6.
The object of this note is to prove the followingTheorem Let{a_n}and{b_n}be sequences of real numbers such that0<∑∑a_n~2<+∞and0<∑b_n~2<+∞.Then we have the inequalitysum from m=1 to∞sum from n=1 to∞a_mb_n/m+n<{sum from n=1 to∞(π-θ/n~(1/2)a_n~2}~1/2{sum from n=1 to∞(π-θ/n~(1/2)b_n~2}~1/2 (1)whereθ=3/2~(1/2)-1=1.121320343. 相似文献
7.
Barium ferrite particulates prepared by a salt-melt method 总被引:1,自引:0,他引:1
Tsung-Shune Chin S.L. Hsu M.C. Deng 《Journal of magnetism and magnetic materials》1993,120(1-3):64-68
Barium ferrite particulates have been prepared by coprecipitation and calcination in a flux of NaCl-KCl. It was found that a flux containing more than 30 wt% KCl tends to seriously deteriorate the magnetic properties of resultant perticulates. The flux with 10 wt% KCl or less showed promising results. A Ba(CoZr)0.75Fe10.5O19 particulate showed the best properties, i.e., a saturation magnetization of 68.5, a squareness ratio of 0.49, and a coercivity of 1280 Oe, when calcined in NaCl at 900°C for 4 h. 相似文献
8.
Alex Hellsten 《Archive for Mathematical Logic》2006,45(6):705-714
We extract some properties of Mahlo’s operation and show that some other very natural operations share these properties. The weakly compact sets form a similar hierarchy as the stationary sets. The height of this hierarchy is a large cardinal property connected to saturation properties of the weakly compact ideal. 相似文献
9.
10.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献