g-C3N4/Bi2O2CO32D纳米片复合材料的制备及可见光催化性能研究

采用自组装和化学沉淀法分别制得两种可见光驱动复合材料石墨相氮化碳/碳酸氧铋(g-C_3N_4/Bi_2O_2CO_3).采用X射线衍射光谱(XRD),紫外可见光谱、扫描电镜(SEM)、N_2吸附、电化学阻抗谱(EIS)和X射线光电子能谱(XPS)等分析手段对制备的催化剂进行了表征.结果表明,制备方法对纳米复合材料的晶相、形态及光学性能没有影响,但是影响g-C_3N_4和Bi_2O_2CO_3之间的相互作用力,导致光生电子-空穴对的分离速率存在显著差异.以可见光驱动苯酚和罗丹明B的降解实验为探针反应检测催化剂的光催化性能.实验结果表明自组装法得到的异质结催化剂中相互作用力更强,催化效果最高.O_2-是罗丹明B降解反应的主要活性物种,染料的光敏化、Bi_2O_2CO_3与g-C_3N_4综合效应,导致光生载流子电荷分离效率更高.     

扑翼尾流脱落涡特性的PIV实验研究

通过色流实验和粒子成像测速技术(particle image velocimetry, PIV)对扑翼近场尾流脱落涡的结构轨迹和能量进行了定性及定量研究.结果表明:因展向流动充分性的不同, 存在两种牛角型涡系结构; 上下扑时翅翼交替产生顺时针和逆时针脱落涡, 两涡运动轨迹呈近似弧形对称, 对称轴的仰角略大于攻角; 脱落涡的涡心涡量在上下扑极点达到最大值, 环量最大值出现在到达极点前的1/5~2/5周期之间; 产生脱落涡的半周期内, 涡的平均环量都随减缩频率的增大而增大, 减缩频率较低时, 下扑平均环量大于上扑平均环量, 减缩频率较高时则相反; 振幅对涡能量影响明显, 减缩频率为2~2.5时, 振幅±40°时的涡平均环量约是振幅±30°时的两倍, 减缩频率越大振幅影响越明显.      

Numerical Investigation of Particle Focusing Patterns in Laminar Pipe Flow With High Reynolds Numbers北大核心CSCD

The inertial focusing characteristics of particles in laminar flow pipes with high Re numbers were studied based on the “relative motion model”. In order to solve the problem of long pipes with high Re number flow, periodic boundary conditions were imposed on the inlet and outlet of the pipe. The research results show that the use of periodic boundary conditions can effectively reduce the computational, and the mechanical properties of particles in high Re flow can be calculated by using L=4D pipe. The difference from the low Re number is that as the Re number continues to increase,the lift force of the particles in the radial direction is no longer distributed as a parabola. The lift curve has a concave area between r+ =0.5 ~ 0.7, and there is a tendency for a new inertial focus point to appear in this section. By means of particles of a+ =1/17 for Re > 1 000, this new focus point position is solvable. In addition, in the analysis of the flow field, a secondary flow occurs around the particle, and its intensity gradually increases with the Re number and the closeness of the particle to the wall. The generation of the secondary flow affects the spatial distribution of the particle lift. © 2023 Editorial Office of Applied Mathematics and Mechanics. All rights reserved.