酯基取代的吲哚衍生物的红外和荧光光谱研究

Tryptophan derivatives have long been used as site-specific biological probes. 4-Cyanotryptophan emits in the visible region and is the smallest blue fluorescent amino acid probe for biological applications. Other indole or tryptophan analogs may emit at even longer wavelengths than 4-cyanotryptophan. We performed FTIR, UV-Vis, and steady-state and time-resolved fluorescence spectroscopy on six ester-derivatized indoles in different solvents. Methyl indole-4-carboxylate emits at 450 nm with a long fluorescence lifetime, and is a promising candidate for a fluorescent probe. The ester-derivatized indoles could be used as spectroscopic probes to study local protein environments. Our measurements provide a guide for choosing esterderivatized indoles to use in practice and data for computational modeling of the effect of substitution on the electronic transitions of indole.     

基于环形微腔的多频段三角晶格光子晶体耦合腔波导光学传输特性

本文理论研究了近红外波段硅基三角晶格光子晶体环形微腔的光场局域特性,通过将微腔在空间周期性排列组成耦合腔光波导,研究了多个导带区域内光束传输时的群速度,最大和最小值分别为0.0028c和0.00028c.将环形微腔在垂直于光传输方向上进行交错排列,通过改变相邻微腔之间的耦合区域,可以大幅降低多频段范围内光束在耦合腔波导中传输时群速度之间的差异,并提高部分频段的透过率数值.在不改变介质柱半径条件下,通过去掉三角晶格光子晶体中距中心介质柱距离分别为2a和√3a的六个介质柱构成了两种微腔,研究了两种微腔所支持的谐振波长之间的差异,在此基础上构造了两种耦合腔波导,进而将这两种耦合腔光波导与W1型输入/输出波导相连,最终实现了在多个不同频率范围内降低群速度的同时实现频段选择和频段分束功能,其导模群速度可降低到0.00047c.