Phase Transition Behavior of LiCr 0.35 Mn0.65O2 under High Pressure by Electrical Conductivity Measurement

The electrical conductivity of powdered LiCr 0.35 Mn0.65O2 is measured under high pressure up to 26.22 GPa in the temperature range 300-413 K by using a diamond anvil cell. It is found that both conductivity and activation enthalpy change discontinuously at 5.36 GPa and 21.66 GPa. In the pressure range 1.10-5.36 GPa, pressure increases the activation enthalpy and reduces the carrier scattering, which finally leads to the conductivity increase. In the pressure ranges 6.32-21.66 GPa and 22.60-26.22 GPa, the activation enthalpy decreases with pressure increasing, which has a positive contribution to electrical conductivity increase. Two pressure-induced structural phase transitions are found by in-situ x-ray diffraction under high pressure, which results in the discontinuous changes of conductivity and activation enthalpy.     

高压下AlN纳米线的介电性质

利用高压X射线衍射和高压原位电化学阻抗谱法研究了AlN纳米线的高压结构和电学性质.研究结果表明:AlN纳米线的电学参数均在22.6 GPa发生了突变,该突变与样品发生了从纤锌矿到岩盐矿的结构相变相关.岩盐相中晶格对电子的散射在电传导中起主导作用;不同于纤锌相中的长程传导,岩盐相中存在短程传导,且其作用随压力增加而增大;纤锌相的介电损耗峰在1Hz且不受压力影响;岩盐相的介电损耗峰随压力减小且向低频方向移动.本研究将为AlN及其相关材料的进一步研究和应用提供实验依据.     

管线上卷极限弯矩分析

利用弹塑性理论对卷管施加弯矩载荷时的截面屈服过程进行了理论分析,得出了卷管上卷时卷管所能承受的极限弯矩;通过实例分析得出X65钢在发生塑性应变为2.5%时的卷管两端截面夹角为1.98rad、滚筒直径为5.05m、极限弯矩为99.2kN m。根据DNV-OS-F101和API-RP-1111的相关规定,可将99.2kN m界定为对卷管施加弯矩的上限值;卷管弯矩上限值对应卷管上卷时的滚筒直径上限值,表明卷管上卷时可通过滚筒直径来限制卷管弯矩值。本文结果可为深水管线卷轴铺设的应用提供理论依据。