P(VDF-TrFE)铁电聚合物薄膜不对称铁电开关现象

报道了铁电聚合物薄膜中观测到的不对称铁电开关双峰现象．当薄膜被略低于其矫顽场的电场极化时可观测到铁电开关双峰,当进一步连续施加超过矫顽场的电场后这一开关双峰现象消失．用空间电荷的注入和再分布模型对这一不对称现象进行了探讨．     

Polarization fatigue in poly(vinylidene fluoride (78%)-trifluoroethylene (22%)) ferroelectric thin films: a pulse train study

This paper investigates the influences of polarization fatigue on remanent polarization and switching time by pulse train measurements in ferroelectric poly(vinylidene fluoride (78%) and trifluoroethylene (22%)) thin films. Fatigue was carried out by a series of bipolar switching pulses with constant pulse width (on-time) and various interval times between pulses (off-time). The experimental observations indicated that the off-time period showed no obvious influence on fatigue rate and the switching time increased with the increase of fatigue cycles. The origination of these phenomena was discussed according to the charge injection model.