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Structural stability in terms of the decomposition temperature in LiMn2O4 was systematically investigated by a series of high-temperature and high-pressure experiments.LiMn2O4 was found to have structural stability up to 5 GPa at room temperature.Under ambient pressure,the compound decomposed at 1300℃.The decomposition temperature decreased with increasing pressure,yielding more complex decomposed products.Below the decomposition temperature,the crystal structure of LiMn2O4 varied with pressure.The presented results in this study offer new insights into the thermal and pressure stability of LiMn2O4 materials as a cathode for lithium-ion batteries that can operate under extreme conditions.Therefore,these findings may serve as a useful guide for future work for improving lithium-ion batteries. 相似文献
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Structural stability of ultra-high temperature refractory material MoSi_2 and Mo_5Si_3 under high pressure 下载免费PDF全文
In-situ angle dispersive x-ray diffraction(ADXRD) with synchrotron radiation source is performed on an ultra-high temperature refractory of MoSi_2 and Mo_5Si_3 by using a diamond anvil cell(DAC) at room temperature. While the pressureinduced volume reduction is almost constant, the value of the bulk modulus increases with the decrease of molybdenum content in the system. According to the Brich–Murnaghan equation, the bulk modulus 222.1(2.1) GPa with its pressure derivative 4 of MoSi_2, and the bulk modulus 308.4(7.6) GPa with its pressure derivative 0.7(0.1) of Mo_5Si_3 are obtained.The experimental data show that MoSi_2 has distinct anisotropic behavior, Mo_5Si_3 is less anisotropic than MoSi_2. The result shows that MoSi_2 and Mo_5Si_3 have the structural stabilities under high pressure. When the pressure reaches up to 41.1 GPa, they can still maintain their body-cantered tetragonal structures. 相似文献
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