机械合金化Fe-B合金的Mssbauer谱研究

用Mossbauer谱分析方法研究了配料原子比为Fe_(70)B_(30),Fe_(55)B_(45)和Fe_(30)B_(70)各样品经机械合金化所形成的合金相的结构特点及其非晶相在退火过程中的转变。揭示出此类非晶相与相应的Fe-B化合物之间存在一定程度的联系。     

CALCULATION ON A CLUSTER MODEL FOR THE ELECTRONIC CHARGE DENSITY AT NUCLEAR SITE AND THE ELECTRONIC STRUCTURE PARAMETERS OF α IRON

In order to investigate the M6ssbauer isomer shifts and its related electronic charge densities for some substances, the electronic charge density at nuclear site of a iron have been computed for an octahedral cluster Fe₆ with SCF MS-X_α method. Some other electronic structure parameters of the cluster have also been obtained, such as the orbital energy distri- bution, the electron density of states, the Fermi level and various kinds of electron energies, etc. The cohesive energy of α iron have also been calculated and discussed.     

机械合金化Fe-B合金的M?ssbauer谱研究

用M?ssbauer谱分析方法研究了配料原子比为Fe₇₀B₃₀,Fe₅₅B₄₅和Fe₃₀B₇₀各样品经机械合金化所形成的合金相的结构特点及其非晶相在退火过程中的转变。揭示出此类非晶相与相应的Fe-B化合物之间存在一定程度的联系。