排序方式: 共有11条查询结果,搜索用时 46 毫秒
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以可再生的异长叶烷酮为原料,设计合成了五种六氢喹唑啉-2-胺基衍生物.化合物在固体状态时呈现出增强的荧光强度以及从暗绿色到亮黄色的荧光颜色的转变.除了良好的热稳定性之外,化合物的固态荧光不容易受到多种常见因素的干扰,比如长时间的紫外照射、增强的制片压力以及升高的加热温度.与遭受严重不利的聚集荧光猝灭效应(ACQ)的化合物相反,二甲氨基取代基构建的1-(((6,6,10,10-四甲基-4-(4'-(二甲基氨基)苯基)-5,7,8,9,10,10a-六氢-6H-6a,9-桥亚甲基苯并[h]-2-喹啉基)亚胺基)甲基)萘-2-酚(3e)呈现出明显的聚集诱导发光现象(AIE).而且,荧光化合物在水溶液中还可以用于对锌离子的专一和灵敏的检测.而后,采用密度泛函理论计算对化合物的光物理性质进行研究.荧光探针还被成功的应用于蜀葵的花粉粒内的锌离子成像. 相似文献
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在色噪声间的关联程度受时间周期调制的激光系统中,研究噪声受信号调制情况下的随机共振.用线性化近似的方法计算了光强关联函数及信噪比.具体讨论信噪比随噪声强度、噪声自关联时间、信号频率以及时间周期调制频率的变化关系.发现一种新的随机共振:信噪比随时间周期调制频率的变化出现周期振荡型随机共振;发现广义随机共振:信噪比随抽运噪声自关联时间的变化、随信号频率的变化出现随机共振;同时也存在典型的信噪比随噪声强度的变化而出现的随机共振.而信噪比随量子噪声自关联时间的变化表现为抑制.
关键词:
信号调制
时间周期调制
噪声间关联程度
周期振荡型随机共振 相似文献
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Intensity correlation time of a single-mode laser driven by two coloured noises with coloured cross-correlation with direct signal modulation 下载免费PDF全文
In this paper, the intensity correlation time T is studied for the gain-noise model of a single-mode laser driven by coloured pump noise and coloured quantum noise with coloured cross-correlation with a direct signal modulation. By using the linear approximation method, it is found that when the pump noise is modulated directly by a signal, the effects of the cross-correlation between the pump noise and the quantum noise will disappear. In addition, there exists a maximum (i.e. resonance) in the curve of the intensity correlation time $T$ versus the pump noise self-correlation time \tau1. Furthermore, when \tau1\le\tau2, the intensity correlation time T increases monotonically with the increase of $D$ and decreases monotonically with the increase of Q, but when \tau1>\tau2, the intensity correlation time T increases monotonically with the increase of Q and decreases monotonically with the increase of D. 相似文献
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Ferrimagnetism induced by asymmetrical ferromagnetic next-nearest-neighbour exchange interactions in an antiferromagnetic spin-1/2 zigzag chain 下载免费PDF全文
The magnetic properties of an antiferromagnetic bond alternating spin-1/2 zigzag chain with asymmetrical ferromagnetic next-nearest-neighbour exchange interactions at finite temperature are investigated by using the many-body Green's function theory. It is found that the ferrimagnetic ordering does not appear in the symmetrical next-nearest-neighbour coupling case, and takes place only for the asymmetrical next-nearest-neighbour case at finite temperature rather than the ground state. Furthermore, as the asymmetry degree of the next-nearest-neighbour exchange interactions increases, the ferrimagnetism becomes more and more dominant. It is shown that the elementary excitation spectra are responsible for the observed magnetic behaviour. 相似文献
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采用线性化近似方法计算了单模激光系统的光强关联函数,讨论了光强关联函数随时间的演化关系,发现光强关联函数呈现周期振荡的现象.关联函数振荡的幅度和周期不受量子噪音强度、抽运噪音强度和交叉关联程度的影响,输入信号频率会改变关联函数振荡的周期和幅度,但不改变振荡的平衡位置,量子噪音强度会改变振荡极值的位置,四个参量都改变关联函数衰减的初始值,但关联函数对时间周期调制频率不敏感. 相似文献
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以二(2-吡啶甲基)胺(DPA)和三聚茚为原料,设计合成了一种"turn-off"型荧光探针化合物6,表征了其结构,研究了它对不同金属离子的识别作用.结果表明,化合物6对Cu2+和Ni2+具有较高的灵敏性和选择性,在N,N-二甲基甲酰胺(DMF)/H2O(V/V=8/2,p H=7.0)溶液中对Cu2+、Ni2+显示出荧光淬灭效应,且对Cu2+检测几乎不受其他金属离子的干扰;高分辨质谱证明化合物6与Cu2+、Ni2+结合计量比为1∶1;化合物6对Cu2+的检测极限可低至28 nmol/L,对Ni2+的检测极限可低至41nmol/L,检测极限均低于世界卫生组织(WHO)规定的饮用水中两种离子最大含量,有潜在的应用价值. 相似文献
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