Superamphiphobic,light-trapping FeSe2 particles with a micro-nano hierarchical structure obtained by an improved solvothermal methodSuperamphiphobic,light-trapping FeSe2 particles with a micro-nano hierarchical structure obtained by an improved solvothermal methodSuperamphiphobic,light-trapping FeSe2 particles with a micro-nano hierarchical structure obtained by an improved solvothermal method

Wettability and the light-trapping effect of FeSe2 particles with a micro-nano hierarchical structure have been inves- tigated. Particles are synthesized by an improved solvothermal method, wherein hexadecyl trimetbyl ammonium bromide （CTAB） is employed as a surfactant. After modifying the particles with heptadecafluorodecyltrimethoxy-silane （HTMS）, we find that the water contact angle （WCA） of the FeSe2 particles increases by 6.1~ and the water sliding angle （WSA） decreases by 2.5~ respectively, and the diffuse reflectivity decreases 29.4% compared with similar FeSe2 particles synthe- sized by the conventional method. The growth process of the particles is analyzed and a growth scenario is given. Upon altering the PH values of the water, we observe that the superhydrophobic property is maintained quite consistently across a wide PH range of 1-14. Moreover, the modified particles were also found to be superoleophobic. To the best of our knowledge, there is no systematic research on the wettability of FeSe2 particles, so our research provides a reference for other researchers.     

Hot deformation in nanocrystalline Ndben Feben B backward extruded rings

Radially oriented Nd-Fe-B rings are prepared by backward extrusion of fine grained melt-spun powder. Melt-spun powder with the nominal composition of Nd_30.5Fe_bal.Co_6.0Ga_0.6Al_0.2B_0.9 (wt%) is used as starting material. The effects of process variables, such as deformation temperature (T_d), strain rate (ε) and height reduction (Δh%), on the magnetic properties of the rings are investigated. A scanning electron microscope (SEM) equipped with an energy spectrum device is used to study the metallograph and microfracture of the extruded rings. The B_r and (BH)_max reach the optimum values at T_d=800℃, ε =0.01 mm/s, and Δh% =70%. It is found by SEM observations that the particle boundaries, which seemingly correspond to the interfaces of the starting melt-spun powders, emerge after the corrosion of metallography specimens. This is helpful for studying the effects of powder-powder interface on the local deformation and deformation homogeneity in the rings. For different spatial positions of the extruded rings, there are characteristic metallographies and microfractures. The upper end of the rings has the least deformation and worst texture, and therefore the worst magnetic properties. The magnetic properties in the radial direction increase slightly along the axis from the bottom to the middle, then steeply decrease at the upper end of the ring. The deformation and the formation-of-texturing processes are discussed. The deformation and the texturing formation of melt-spun Nd-Fe-B alloys probably involve grain boundary sliding and grain rotation, the solution-precipitation process and preferential growth of Nd₂Fe₁₄B nanograins along the easy growth a-axis.     

压缩载荷下孔隙结构变化的CT实验研究

为了研究孔隙对岩石力学性能的影响,利用自制的孔隙物理模型,通过 单轴压缩和CT扫描实验研究了受载条件下孔隙率对岩石孔隙结构的演化及其对外部物理力 学性能的影响,得到了不同加载阶段和不同CT观察尺度下孔隙模型的裂纹扩展规律以及孔隙 和固体介质的损伤变化情况. 实验结果表明：孔隙模型在受载条件下裂纹主要发生在峰值荷 载之后,主裂纹大都集中在孔隙密集的地方且伴随许多细小裂纹的产生;峰值载荷前出现了 少数微裂纹,微裂纹的产生与演化主要发生在孔隙周边.     

一种具有高比表面积的Ag@ZnO微-纳复合结构的合成及其在光催化还原二氧化碳方面的应用

采用简单的水热法制备了比表面积高达7.9801m~2/g的ZnO微米星状结构(ZnO star),利用AgNO_3紫外光照还原反应在其表面附着Ag纳米颗粒,构成Ag@ZnO star微-纳米复合分型结构,其光学吸收波长尺度涵盖从近紫外至近红外的太阳光谱波段.用X射线衍射光谱(XRD)、X射线光电子能谱(XPS)等测定了样品的相结构和组成元素.用扫描电子显微镜(SEM)、透射电子显微镜(TEM)以及高分辨透射电子显微镜(HRTEM)确定了所合成样品的形貌和晶面结构并且证实了Ag@ZnO star异质结构的存在.紫外-可见-近红外分光光度计(UV-VIS-NIR spectrophotometer,UVNS)测试显示样品在近紫外至近红外波段都具有良好的光吸收性能.用Labsolar-6A高气密性自动在线光催化分析系统测量了样品的CO_2光催化还原为CO的性能,结果表明Ag@ZnOstar微-纳复合结构显著地提高了CO_2光催化还原的能力,较商用ZnO粉末提高了4倍,其原因归于两点:一是ZnO的分型结构显著提高了比表面积,二是Ag粒子与ZnO的耦合产生的等离激元增强效应以及使非极性面的活性得到增强.此工作对高效微-纳复合结构CO_2光催化还原剂的构建具有重要的指导意义.     

Pr2Fe14(C,B)/α-(Fe,Co)型纳米晶复合磁体的结构与磁性

研究了Pr_xFe_82-x-yTi_yCo₁₀B₄C₄ (x=9—10.5;y=0, 2)纳米晶薄带的结构与磁性. 结果表明,所有薄带皆主要由2∶14∶1, 2∶17和α-(Fe, Co)三相组成. 对于y=0的合金,其内禀矫顽力随Pr含量x的增加而增加,剩磁随Pr含量x的增加而减小. 以Ti置换部分Fe (y=2),合金的磁性能得到显著提高,表现为:添加Ti后,合金的剩磁B_r基本不降低,x=10.5时合金的B_r值甚至有较明显的提高;同时添加Ti后,合金的内禀矫顽力及退磁曲线的方形度都明显改善. 当x=10.5,y=2时,合金薄带的磁性能达到最佳值为: B_r=9.6 kGs(1 Gs=10^-4 T),_iH_c =10.2 kOe(1 Oe=79.5775 A/m)和(BH)_max＝17.4 MGOe. 随着Pr含量的提高,合金中的硬磁相2 ∶14 ∶1的含量相对增加,内禀矫顽力提高;而Ti置换Fe抑制了软磁相α-(Fe, Co)在快淬和热处理过程中的优先长大,使合金中软磁相和硬磁相的晶粒尺寸及比例趋向最佳组合,交换耦合作用明显增强. 关键词： 纳米晶永磁材料 2Fe₁₄(C')" href="#">Pr₂Fe₁₄(C B) Ti添加 交换耦合     

Nano Ag-enhanced photoelectric conversion efficiency in all-inorganic,hole-transporting-layer-free CsPbIBr2 perovskite solar cells

All-inorganic, hole-transporting-layer-free CsPbIBr₂ perovskite solar cells have great potential for development, but their device performance needs to be further improved. Recently, metal nanostructures have been successfully applied in the field of solar cells to improve their performance. Nano Ag-enhanced power conversion efficiency (PCE) in one CsPbIBr₂ perovskite solar cell utilizing localized surface plasmons of Ag nanoparticles (NPs) on the surface has been researched experimentally and by simulation in this paper. The localized surface plasmon resonance of Ag NPs has a near-field enhancement effect, which is expected to improve the light absorption of CsPbIBr₂ perovskite photovoltaic devices. In addition, Ag NPs have a forward-scattering effect on the incident light, which can also improve the performance of CsPbIBr₂-based perovskite photovoltaic devices. By directly assembling Ag NPs (with a size of about 150 nm) on the surface of fluorine-doped tin oxide it is found when the particle surface coverage is 10%, the CsPbIBr₂ perovskite photovoltaic device achieves a best PCE of 2.7%, which is 9.76% higher than that of the control group. Without changing any existing structure in the ready-made solar cell, this facile and efficient method has huge applications. To the best of our knowledge, this paper is the first report on nano Ag-enhanced photoelectric conversion efficiency in this kind of CsPbIBr₂ perovskite solar cell.     

Extraordinary optical transmission through a subwavelength composite hole-pillar array

We numerically investigate the transmission properties of a subwavelength composite hole-pillar array. As the radius of the pillar increases, the transmission properties experience a complex evolution. It is found that the magnetic dipole resonance of the pillar suppresses the surface plasmon polariton resonance(SPPR) at the gold-air interface. There are two strong transmission peaks associated with the magnetic dipole resonance of pillar and SPPR at the gold-silica interface. A peak associated with magnetic quadrupole resonance of the pillar is observed. Moreover, there is a weak peak associated with the coupling between the whispering-gallery plasmon(WGP) mode and magnetic dipole. Our work is helpful for making a dual band optical filter.     

Superamphiphobic,light-trapping FeSe2 particles with a micro-nano hierarchical structure obtained by an improved solvothermal method

Wettability and the light-trapping effect of FeSe2particles with a micro-nano hierarchical structure have been investigated. Particles are synthesized by an improved solvothermal method, wherein hexadecyl trimethyl ammonium bromide(CTAB) is employed as a surfactant. After modifying the particles with heptadecafluorodecyltrimethoxy-silane(HTMS), we find that the water contact angle(WCA) of the FeSe2 particles increases by 6.1 and the water sliding angle(WSA) decreases by 2.5 respectively, and the diffuse reflectivity decreases 29.4% compared with similar FeSe2 particles synthesized by the conventional method. The growth process of the particles is analyzed and a growth scenario is given. Upon altering the PH values of the water, we observe that the superhydrophobic property is maintained quite consistently across a wide PH range of 1–14. Moreover, the modified particles were also found to be superoleophobic. To the best of our knowledge, there is no systematic research on the wettability of FeSe2 particles, so our research provides a reference for other researchers.     

Ordered silicon nanorod arrays with controllable geometry and robust hydrophobicity

Highly ordered silicon nanorod(Si NR)arrays with controllable geometry are fabricated via nanosphere lithography and metal-assisted chemical etching.It is demonstrated that the key to achieving a high-quality metal mask is to construct a non-close-packed template that can be removed with negligible damage to the mask.Hydrophobicity of Si NR arrays of different geometries is also studied.It is shown that the nanorod structures are effectively quasi-hydrophobic with a contact angle as high as 142°,which would be useful in self-cleaning nanorod-based device applications.