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自然界中,糖类不仅作为生命体系的能量物质和结构物质,而且还作为信息分子在生命过程的细胞识别和调控中扮演着重要的角色,因此对糖识别的研究将极大地有助于糖类参与生理和病理过程的研究。生命体系中糖识别过程一方面基于受体的极性基团与糖羟基的氢键作用,另一方面依靠受体结构中的含芳环非极性基团与糖CH基相互作用,所以在极性溶液水中通过非共价键相互作用实现糖识别过程是当今化学界一个十分吸引人且又极具挑战性的研究课题。人工合成糖识别受体为研究自然界中糖识别过程的基本机制提供了一种有参考价值的模型系统,同时为仿生应用提供了有力的技术支持。本文从超分子化学、多分枝型、合成凝集素类和聚合物界面4种体系论述了近年来非硼酸类人工糖识别受体在水相中识别糖的研究进展及其潜在应用,并且对合成凝集素和界面糖识别体系做了特殊点评,最后对仿生人工合成受体在水相中对糖识别的未来的发展方向做了展望。 相似文献
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利用环氧树脂(EP)对碳酸氢钠(SB)进行包覆合成微胶囊碳酸氢钠,通过红外光谱仪(FTIR)、扫描电子显微镜(SEM)、差示扫描量热计(DSC)和热重分析仪(TG)等表征手段,分析了合成反应温度、环氧树脂与碳酸氢钠的质量比对微胶囊碳酸氢钠的结构、表面形貌特征以及热分解特性的影响。结果表明:当反应温度为70℃,环氧树脂与碳酸氢钠的质量比为1∶5时,碳酸氢钠的改性效果较理想,表面形貌比较规整,起始分解温度由118℃提高至154.9℃,分解温度区间从46.3℃缩短到24.8℃;使用微胶囊碳酸氢钠制备的微发泡聚丙烯材料,发泡质量较理想。 相似文献
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Computational model investigating the effect of magnetic field on neural-astrocyte microcircuit 下载免费PDF全文
Li-Cong Li 《中国物理 B》2021,30(6):68702-068702
Extremely low-frequency magnetic field is widely used as a noninvasive stimulation method in clinical practice and basic research. Electrical field induced from magnetic pulse can decrease or increase neuronal electrical activity. However, the cellular mechanism underlying the effects of magnetic field is not clear from experimental data. Recent studies have demonstrated that "non-neuronal" cells, especially astrocytes, may be the potential effector for transcranial magnetic stimulation (TMS). In the present study, we implemented a neural-astrocyte microcircuit computational model based on hippocampal architecture to investigate the biological effects of different magnetic field frequencies on cells. The purpose of the present study is to elucidate the main influencing factors of MS to allow a better understanding of its mechanisms. Our model reproduced the basic characteristics of the neuron and astrocyte response to different magnetic stimulation. The results predict that interneurons with lower firing thresholds were more active in magnetic fields by contrast to pyramidal neurons. And the synaptic coupling strength between the connected neurons may be one of the critical factor to affect the effect of magnetic field on cells. In addition, the simulations show that astrocytes can decrease or increase slow inward currents (SICs) to finely tune neuronal excitation, which suggests their key role in excitatory-inhibitory balance. The interaction between neurons and astrocytes may represent a novel target for effective therapeutic strategies involving magnetic stimulation. 相似文献
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设L为与Calder6n—Zygmund型相关的Toeplitz算子,通过建立Toeplitz算子的sharp极大函数的点态估计并应用该估计证明了当b∈BMO(Rn)时,Tb分别在加权Lp(w)空间,Morrey空间Lp,λ(P)和加权Morrey空间L(w)上有界. 相似文献
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设Tb 为与Calderón-Zygmund型相关的Toeplitz算子,通过建立Toeplitz算子的sharp极大函数的点态估计并应用该估计证明了当b∈BMO(Rn)时,Tb 分别在加权Lp(ω)空间, Morrey空间Lp,λ(Rn)和加权Morrey空间Lp,λ(ω)上有界. 相似文献
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