Structural Evolution of D5h（1）-C90 under High Pressure:A Mediate Allotrope of Nanocarbon from Zero-Dimensional Fullerene to One-Dimensional Nanotube

The hybridization of fullerene and nanotube structures in newly isolated C₉₀ with the D_{5 h} symmetric group(D_{5 h}（1）-C₉₀) provides an ideal model as a mediating allotrope of nanocarbon from zero-dimensional（OD） fullerene to one-dimensional nanotube.Raman and infrared spectroscopy combined with classical molecular dynamics simulation were used to investigate the structural evolution of D_{5 h}（1）-C₉₀ at ambient and high pressure up to35...     

单壁碳纳米管的高压拉曼研究

采用金刚石对顶砧装置对直径分布在1.3 nm左右的单壁碳纳米管进行了高压拉曼光谱研究.实验结果表明随压力的增加碳管的截面形状发生了由圆到椭圆再到扁平的变化,这和我们之前的研究结果一致.从31 GPa卸压至常压后碳管的结构得到了较好的保持,这个压力值明显高于传统的Sp2键结构的碳材料所能稳定存在的压力范围(20 GPa以...