热塑弹性体超临界流体间歇发泡过程中的基本问题

超临界流体间歇发泡的体系黏弹性易于调节、加工参数易于控制、加工装备便于设计和实现,是热塑弹性体物理发泡领域中最受关注的技术路线.本文首先综述了热塑弹性体物理发泡相关文献、研发历程和应用现状;阐明间歇发泡技术的相关概念、技术特点以及热塑弹性体与超临界流体的相互作用,重点讨论热塑弹性体间歇发泡的“高弹态发泡”特征以及处于高弹态状态下的泡孔成核、泡孔生长、泡孔结构定型、泡沫收缩机制及其调控策略.其次,综述了热塑弹性体发泡薄膜的制备方法、热塑弹性体发泡珠粒水蒸气成型过程、珠粒界面黏结强度和分子链界面扩散机制.此外,还从分子链化学结构、泡孔结构、材料宏观结构等角度总结了热塑弹性体发泡材料弹性性能,揭示热塑弹性体发泡材料的结构—弹性性能关系.最后对热塑弹性体超临界流体间歇发泡技术进行了展望.     

Influence of intramolecular hydrogen bond formation sites on fluorescence mechanism

The fluorescence mechanism of HBT-HBZ is investigated in this work. A fluorescent probe is used to detect HClO content in living cells and tap water, and its structure after oxidation by HClO (HBT-ClO) is discussed based on the density functional theory (DFT) and time-dependent density functional theory (TDDFT). At the same time, the influence of the probe conformation and the proton transfer site within the excited state molecule on the fluorescence mechanism are revealed. Combined with infrared vibrational spectra and atoms-in-molecules theory, the strength of intramolecular hydrogen bonds in HBT-HBZ and HBT-ClO and their isomers are demonstrated qualitatively. The relationship between the strength of intramolecular hydrogen bonds and dipole moments is discussed. The potential energy curves demonstrate the feasibility of intramolecular proton transfer. The weak fluorescence phenomenon of HBT-HBZ in solution is quantitatively explained by analyzing the frontier molecular orbital and hole electron caused by charge separation. Moreover, when strong cyan fluorescence occurs in solution, the corresponding molecular structure should be HBT-ClO(T). The influence of the intramolecular hydrogen bond formation site on the molecule as a whole is also investigated by electrostatic potential analysis.     

内封光纤高温超导CORC©缆线电磁特性仿真研究

内封光纤高温超导 CORC?? (Conductor on Round Core) 缆线在传统 CORC?? 缆线结构的基础上, 将光纤嵌于铜芯骨架内, 不仅能够保持原有集束缆线表面形貌的完整性, 还能通过外置分布式光纤传感解调设备, 实现对缆线失超的快速检测. 然而, 改变缆线结构有可能引起缆线电磁特性发生变化, 继而影响高场磁体的设计与应用. 本文以高温超导CORC?? 缆线为研究对象, 采用有限元仿真技术研究了直流供电的内封光纤CORC?? 缆线在正常运行工况下的电磁场分布特性, 通过对比普通CORC?? 缆线, 分析了内封光纤对CORC?? 缆线电磁性能产生的影响. 研究结果表明, 两种缆线在正常运行工况下的电流密度及磁通密度分布特性较一致, 初步论证了内封光纤高温超导CORC?? 缆线在高场磁体应用的可行性.