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First-principle calculations are performed to study the infrared optical and electronic properties of the tetragonal CaTiO3. We find that dielectric function and reflectivity exhibit a new single-peak infrared spectrum. It is shown that strong orbital hybridization can form the dipole distribution of covalent bonds (Ti-O1 and Ti-O2)and can result in anomalous optical behaviour. The tetragonal structure that determines the dipole configuration and leads to the optical dipole-dipole transition forbidden is therefore realized to be vital to cause such optical phenomena with the insulator feature. 相似文献
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First-Principles Study of Electronic and Optical Properties of Y1-xCaxTiO3 (x=0, 0.25, 0.5, 0.75) 下载免费PDF全文
The full potential linearized augmented plane wave (FP-LAPW) method with the generalized gradient approximation (GGA) is applied to study the electronic and optical properties of perovskite-type compounds Y1-xCaxTiO3. The lattice parameters, magnetic moment, band structure, density of states and optical conductivity are obtained. The results show that the Ca ion plays an important role in the electronic properties and optical responses. Moreover, the optical properties including the dielectric function, absorption spectrum, extinction coefficient, energy-loss spectrum and refractive index are also discussed. 相似文献
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The structural stability and elastic properties of wurtzite thallium nitride (TIN) under hydrostatic pressure are studied for the first time by first-principles calculations. The enthalpy calculations predict that TIN undergoes a phase transition from the wurtzite structure to the rocksalt structure at 19.2 GPa with a volume collapse of 13.0%. Our calculated results also show that this nitride is ductile in nature and exhibits high elastic anisotropy. Our ground-state results are in good agreement with the data of other theoretical calculations. 相似文献
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Structural, Electronic and Elastic Properties of Cubic Perovskites SrSnO3 and SrZrO3 under Hydrostatic Pressure Effect 下载免费PDF全文
Using the plane-wave pesudopotential (PWPP) method within the generalized gradient approximation (GGA'), we investigate the hydrostatic pressure induced effect on the structural, electronic and elastic properties of cubic perovskites SrSn03 and SrZr03. The pressure dependence of the lattice constants, some indirect and direct band gaps, the upper valence bandwidths, the elastic stiffness constants and the aggregate elastic moduli, as well as the Debye temperature are investigated. Our calculated ground-state results are in good agreement with the available experimental and theoretical data. 相似文献
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Phase transition and band structure of Cu2O are systematically investigated by using the HSE06 range-separated hybrid functional. Cubic Cu2O under pressure transforms to the metastable hexagonal phase. Our further investigations reveal that the first-order phase transition is driven by the elastic and dynamical instabilities. Furthermore, the stable band gap of cubic phase is always direct and greatly enhanced by pressure, whereas the hexagonal phase shows the semi-metallic band structure. 相似文献
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Tunable anharmonicity versus high-performance thermoelectrics and permeation in multilayer (GaN)1-x(ZnO)x 下载免费PDF全文
Hanpu Liang 《中国物理 B》2022,31(7):76301-076301
Nonisovalent (GaN)$_{1-x}$(ZnO)$_x$ alloys are more technologically promising than their binary counterparts because of the abruptly reduced band gap. Unfortunately, the lack of two-dimensional (2D) configurations as well as complete stoichiometries hinders to further explore the thermal transport, thermoelectrics, and adsorption/permeation. We identify that multilayer (GaN)$_{1-x}$(ZnO)$_x$ stabilize as wurtzite-like $Pm$-(GaN)$_3$(ZnO)$_1$, $Pmc2_1$-(GaN)$_1$(ZnO)$_1$, $P3m1$-(GaN)$_1$(ZnO)$_2$, and haeckelite $C2/m$-(GaN)$_1$(ZnO)$_3$ via structural searches. $P3m1$-(GaN)$_1$(ZnO)$_2$ shares the excellent thermoelectrics with the figure of merit $ZT$ as high as 3.08 at 900 K for the p-type doping due to the ultralow lattice thermal conductivity, which mainly arises from the strong anharmonicity by the interlayer asymmetrical charge distributions. The $p$-$d$ coupling is prohibited from the group theory in $C2/m$-(GaN)$_1$(ZnO)$_3$, which thereby results in the anomalous band structure versus ZnO composition. To unveil the adsorption/permeation of H$^+$, Na$^+$, and OH$^-$ ions in $AA$-stacking configurations, the potential wells and barriers are explored from the Coulomb interaction and the ionic size. Our work is helpful in experimental fabrication of novel optoelectronic and thermoelectric devices by 2D (GaN)$_{1-x}$(ZnO)$_x$ alloys. 相似文献
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We perform first-principle calculations for the study of the orthorhombic Rb2Cd2 (SO4)3 structure. Electronic energy bands, total and partial densities of states are reported and analysed. It is found that oxygen atomic 2p electrons strongly hybridize with Rb/or Cd 4d and S 2p states, resulting in two-type ionic groups with weak couplings. It is shown that macroscopic domain walls originate from such weak-coupling ionic groups, arising at the cell boundaries. The asymmetric cation bonds (Rb-O and Cd-O) and the subsequent rotations of the S04 tetrahedra can lead to the driving force of the ferroelectric behaviour. The predicted pyroelectric current effects are observed experimentally in the ferroelectric phase. 相似文献
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