Preparation and optical properties of a Rhodamine 6G-doped sol-gel AlPO4-SiO2 film

AlPO4-SiO2 films doped with Rhodamine 6G （Rh6G） are prepared using the sol-gel dip-coating method. The surface morphology is characterized by atomic force microscopy. The results indicate that the surface morphology of the films is not significantly affected by the amount of dyes loaded. The absorption and excitation spectra indicate low aggregation even at a Rh6G doping concentration of 1.0×10-3 mol/L. Efficient fluorescence with a band centered at 553 nm is observed.     

Efficient fluorescence from perylene orange encapsulated in AlPO_4 mesoporous glass

<正>AlPO_4 mesoporous glass doped with perylene orange(PO) is prepared using two steps.The effects of dipping time and PO concentration on the fluorescent properties and molecular formation are investigated through absorption spectra,excitation spectra,and emission spectra.A slight increase in the intensity of excitation bands formed at 499 and 468 nm is ascribed to PO J-dimers aggregates as the dipping time increased from 2 to 24 h at high PO concentration(4×10~(-3) mol/L).This is also the reason behind the concentration increase from 4×10~(-6) to 4×10~(-3) mol/L for the 16 h dipping.The excitation spectra,and the emission spectra of samples doped with PO show a slight red shift as the dipping time and the PO concentration increase.AlPO_4 mesoporous glass is suitable to host the PO at high concentration.     

Optical Properties of Rhodamine 6G Doped AlPO4 Gel

Homogeneous monolith of A1PO4 gel doped with rhodamine 6G （Rh6G） at different dye loadings is prepared by a one-step process with sol-gel method using the precursors A1（lact）3 and H3PO4. The optical properties of A1PO4 gel doped with Rh6G are characterized by UV-Visible absorption spectra and fluorescence spectra. Rh6G molecular J-dimers and H-dimers even multimers are analyzed by excitation spectra based on exciton theory. The A1PO4 gel doped with Rh6G dye with molar ratio of Rh6G/A1（lact）3 of 1 × 10-4 has excellent optical properties without obvious aggregates.