高纯锗探测器的广泛应用和自主研制进展

以目前国际上极为活跃开展的暗物质探测、无中微子双 衰变研究为例,评述了高纯锗探测器的重要性及其广泛的应用前景。介绍了己开展的高纯锗单晶、探测器制备的关键技术研究进展:合作单位已研制出了用于高纯锗单晶材料制备的区熔炉、单晶炉;并制备出直径为20  50 cm、纯度为12N(< 41011  atoms/cm3)、位错< 5000 atoms/cm2 的锗单晶;掌握了高纯锗探测器(平面型、同轴型)制备的关键技术,用进口高纯锗单晶材料制备出的同轴型高纯锗探测器对射线的能量分辨率及探测效率均达到进口产品指标,使用自制的12N 高纯锗单晶材料己制备出平面型高纯锗探测器。呼吁加速高纯锗研制的自主创新步伐,尽早实现其国产化目标。The article reviews importance and wide applications of HPGe detector, especially the application on the dark matter search experiment and double beta decay experiment. The research progress on the Highpurity germanium single crystal and HPGe detector in China has been introduced. The cooperation partner developed new type zone-refining furnace and single crystal furnace. The ultra-purity germanium single crystal with 20~50 cm, purity up to 12N(net impurity concentration is less than 41011 atoms/cm3), and dislocation less than 5 000 /cm3 was prepared. The key technologies for preparing planar and coaxial HPGe detector were mastered. The coaxial detector, which has been made of imported ultra-purity germanium single crystal has excellent energy resolution and efficiency as the imported commercial detector. The planar detector using selfmade germanium single crystal was also successfully manufactured. The research group appeals for speeding up the pace of independent innovation on the high-purity germanium, and achieving the high-purity germanium localization as soon as possible.     

红外光谱法测定三唑锡中三环锡

三唑锡中三环锡含量大于等于10%时,以三环锡的红外特征吸收峰强度来直接测定三环锡;当三唑锡中三环锡含量小于10%时,以三唑锡的红外特征吸峰强度来测定三唑锡含量,再以衍生化法气相色谱测定得出的三唑锡和三环锡总量计算出三环锡含量.测定三环锡方法RSD为0.33%,回收率在100.1%-101.7%之间,测定三唑锡方法RSD为0.12%,回收率在100.6%-101.6%之间.     

低本底液闪中子探测器的材料测试研究

为测量中国锦屏地下实验室（China JinPing underground Laboratory,CJPL）极低通量的中子本底,需要建造大型快中子液体闪烁体探测器。建造探测器需要选用低放射性本底材料,并且化学性质稳定,不与液体闪烁体发生反应而影响液体闪烁体（EJ-335）的性能。为此,建造了小型液闪探测器,在其中分别放入聚四氟乙烯、无氧铜、氟橡胶、全氟醚橡胶这4种材料进行长期浸泡,并分别进行了如下测试:液闪长时间浸泡各种材料前后液闪的吸收光谱测试;用60Co γ源检测小型液闪探测器光产额随时间的变化情况;用Am-Be中子源检验探测器在浸泡前后的n-γ甄别性能。最终实验结果表明,聚四氟乙烯和全氟醚这2种材料与液闪有很好的兼容性,可作为大型快中子液闪探测器的容器和密封圈的备选材料。In order to measure the flux and spectrum of neutron background which is extremely low in China JinPing underground Laboratory (CJPL), liquid scintillator detector with large scale used to detect fast neutron need to be fabricated. Surrounding materials used in detector require the excellent performance, such as low radioactivity as well as stable chemical properties, which do not react with liquid scintillator, so as to avoid affecting the performance of detector. Polytetrafluoroethylene(PTFE), highly purified no-oxygen copper, fluororubber and perfluoroelastomer had been put in a small detector and soaked for a long time. The change of absorption spectrum and light yield along with time as well as the performance of n-γ discrimination after soaked were tested. The results show that PTFE and Perfluoroelastomer are compatible with liquid scintillator, which offers a reference for the selection of material used in container and seal of liquid scintillator detector used to detect fast neutron.