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Hydrothermal reaction between 1,4-phenylenediacetic acid (H2PDA) and Zn(NO3)2·6H2O at the presence of the second ligand of 1,2-bis((1H-imidazol-1-yl) methyl)benzene (obix) yields a new 2D metal-organic coordination polymer [Zn(PDA)(obix)] (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermal analysis. Complex 1 presents a two-dimensional (2D) sheet structure and displays strong luminescent emission at room temperature. CCDC: 716984. 相似文献
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A coordination polymer of Zn(IBT)2 (2) (HIBT=5-(4-((1H-imidazol-1-yl)methyl)phenyl)-2H-tetrazole) has been prepared by hydrothermal method and characterized by IR spectroscopy,elemental analysis and single-crystal X-ray diffraction structure analysis. Compound 2 has one-dimensional (1D) hinged chain structure and displays strong photoluminescent emission at room temperature. 相似文献
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本文运用分步傅里叶变换,对满足高阶耦合非线性薛定谔方程的超短艾里脉冲与超短高斯脉冲,利用MATLAB数值模拟了在高阶效应下两脉冲相互作用后的演化过程以及时域上的强度变化.获得了负三阶色散效应使超短脉冲相互作用能传输更远距离;正三阶色散效应会减慢超短脉冲相互作用的传输.自陡峭效应通过孤子分裂现象的形式使超短脉冲相互作用产生时域位移.内拉曼效应可以将超短脉冲相互作用的能量由前沿处转移到后沿处. 相似文献
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三种新型铜配合物的合成、结构及理论计算 总被引:1,自引:0,他引:1
合成了一个柔性配体1,3-二(N-咪唑基甲基)苯(mbix)(1), 并将其与不同Cu盐组装, 得到3个新配合物[Cu(mbix)2(H2O)]·2NO3·CH3OH(2), [Cu(mbix)(N3)(OAc)]·CH3OH(3)和[Cu(mbix)2]·SiF6·2CH3OH(4), 并对其进行了元素分析、红外光谱及X 射线单晶结构分析表征. 配合物2拥有二维二重贯穿结构, 配合物3中两个铜离子通过两个叠氮酸根桥连成双核铜, 它再通过配体连接形成一维绞链状结构, 而配合物4通过配体桥联成一维无限链状结构. 结果显示, 平衡阴离子在配合物的组装过程中起着非常重要的作用. 此外还对配体及3个配合物中配体的构象进行了理论计算. 相似文献
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Perovskite materials show exciting potential for light-emitting diodes (LEDs) owing to their intrinsically high photoluminescence efficiency and color purity. The research focusing on perovskite light-emitting diodes (PeLEDs) has experienced an exponential growth in the past six years. The maximum external quantum efficiency of red, green, and blue PeLEDs has surpassed 20%, 20%, and 10%, respectively. Nevertheless, the current PeLEDs are still in the laboratory stage, and the key for further development of PeLEDs is large-area fabrication. In this paper, we briefly discuss the similarities and differences between manufacturing high-quality and large-area PeLEDs and perovskite solar cells. Especially, the general technologies for fabricating large-area perovskite films are also introduced. The effect of charge transport layers and electrodes on large-area devices are discussed as well. Most importantly, we summarize the advances of large-area (active area ≥ 30 mm2) PeLEDs reported since 2017, and describe the methods for optimizing large-area PeLEDs reported in the literature. Finally, the development perspective of PeLEDs is presented for the goal of highly efficient and large-area PeLED fabrication. It is of great significance for the application of PeLEDs in future display and lighting. 相似文献
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A one-dimensional zigzag chain complex of Cd(FA)(pyim)(H2O) (1) (H2FA=4,4′-(hexafluoroisopropylid-ene)bis(benzoic acid) and pyim=2-(2-pyridyl)imidazole) was hydrothermal synthesized from Cd(NO3)2·4H2O, 4,4′-(hexafluoroisopropylidene)bis(benzoic acid) and 2-(2-pyridyl)imidazole. Single-crystal X-ray analysis revealed that the zigzag chains of 1 are linked into three-dimensional supramolecular networks by both O-H…O hydrogen-bonds and π…π stacking interactions. The crystal is of monoclinic, space group P21/n with a=0.856 34(10) nm, b=1.020 49(12) nm, c=2.809 0(3) nm, β=98.115(2)°, V=2.430 2(5) nm3, Dc=1.820 g·cm-3, Z=4, F(000)=1 320, Goof=1.009, R1=0.047 0, wR2=0.115 5. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 733837. 相似文献
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本文采用分步傅里叶法,研究了在反常色散区孤子和艾里脉冲相互作用的规律,并且对相互作用后的孤子和艾里脉冲各自的强度、时域和时移进行了MATLAB仿真.通过仿真发现光孤子和艾里脉冲在光纤中相互重叠时,交叉相位调制(XPM)就会建立并且这种调制会影响孤子和艾里脉冲的性质.在相互作用过程中,孤子的形状保持不变,但是受到艾里脉冲自加速特性的影响孤子会发生偏移.艾里脉冲受XPM的影响会转化为孤子,传播方向也会发生偏移.可见,XPM使得艾里脉冲和孤子各自的性质都相互影响着对方.艾里脉冲和孤子的时域也会受到XPM的影响,使得原本不相同的脉冲形状都转变为含有一个主峰和一个次峰的相似结构,并且主峰和次峰的位置和脉冲宽度也大致相同,这也是艾里脉冲能够转换为孤子的一个依据.另外本文还模拟了不同输入强度r下的孤子和艾里脉冲的变化情况,模拟发现不管是艾里脉冲还是孤子时移都随着输入强度r的增大而增大,并且它们的变化趋势都是一样的,同时模拟还发现在相同的的r值下,时移也会随着a值的增大而增大. 相似文献