无机化学的教学创新探索

通过增加学科前沿内容将基本知识讲授与创新意识培养相结合,并改进教学方式,对无机化学教学进行了创新探索。     

[100]金刚石薄膜的辐照响应特性研究

采用热丝辅助化学气相沉积(HFCVD)方法生长得到25μm厚的[100]取向金刚石膜,用以制备辐射探测器.在100 V偏压下,测得暗电流为16.1 nA,55Fe X射线(5.9 keV)和241Am α粒子(5.5 MeV)辐照下的净光电流分别为15.9nA和7.0nA.光电流随时间的变化先快速增加随后由于"pumping"效应逐渐达到稳定.X射线和α粒子辐照下的平均电荷收集效率分别为45;和19;,并由Hecht理论计算得到对应的电荷收集距离为11.25μm和4.75μm.     

Synthesis and Crystal Structure of a New Coordination Polymer: {[AgL]ClO_4}_n(L = 2,5-Bis(3-pyridinylmethylthio)-l,3,4-thiadiazole)

The title complex {[AgL]ClO4}n(L=2,5-bis(3-pyridinylmethylthio)-1,3,4-thiadiazole) was synthesized by the reaction of Ag(I) salt and a novel flexible ligand L.Its structure was determined by X-ray crystallography with the following data:monoclinic,space group P21/n,a=16.5068(13),b=7.6548(4),c=16.5521(13),β=115.119(3)o,V=1893.7(2)3,Z=4,Dc=1.893 g/cm3,μ=1.565 mm-1,F(000)=1072,C14H12AgClN4O4S3,Mr=539.78,T=293(2) K,S=1.067,the final R=0.0342 and wR=0.0870.The silver ion in the complex is in a trigonal coordin...     

Two Discrete Cu-Complexes Constructed from a Multidentate N-Containing Dinucleating Ligand

Two comparable discrete complexes [CuⅡ(CH3CN)2L2]·2(ClO4) 1 and [CuI2I2L2]·(DMF)2 2 were successfully synthesized by the reaction of CuⅡ and CuⅠ salts with a novel dinucleating ligand 2,5-bis(3-pyridinylmethylthio)-1,3,4-thiadiazole)(L),respectively.Complex 1 presents a single nuclear structure while 2 has a dimeric structure where two CuI ions are doubly bridged by halide ions in a μ2-fashion.Both discrete molecules were outspreaded into a one-dimensional supramolecular chain via aromatic interactions such as C-H…π and π…π interactions.     

单组分多相系统驱替过程的格子Boltzmann模拟

结合格子Boltzmann方法中的Shan-Chen单组分多相模型,引入流体相间的内聚力和流体与 固体壁面间的黏附力,对二维孔隙网格中非浸润气相驱替完全浸润液相的过程进行模拟,流 体相间的交界面自然形成,整个驱替过程属于毛细指进. 随着毛细数的增加,黏性力的主导 作用增强,使得气相入侵的孔隙尺度减小,因此驱替形态随毛细数的不同有很大差别. 在微 重力的作用下,整个驱替过程受毛细力、重力和黏性力的共同作用,重力起到了稳定交界面 避免窜流的作用.     

金属原子簇化合物的拉曼光谱研究

金属原子簇化合物的拉曼光谱研究李淑玲（地矿部岩矿测试研究所北京１０００３７）任玲（北京理工大学化工与材料学院北京１０００８１）ＲａｍａｎＳｐｅｃｔｒｏｓｃｏｐｉｃＳｔｕｄｙｏｆＭｅｔａｌｃｌｕｓｔｅｒＣｏｎｐｏｕｎｄｓＬｉＳｈｕｌｉｎｇ（Ｉｎｓｔｉｔ...     

固态六羰基钼的FT-拉曼光谱研究

固态六羰基钼的ＦＴ┐拉曼光谱研究李淑玲（地矿部岩矿技术研究所北京１０００３７）任玲（北京理工大学化学与材料学院北京１０００８１）ＦＴ┐ＲａｍａｎＳｐｅｃｔｒａｏｆＳｏｌｉｄＭｏ（ＣＯ）６ＬｉＳｈｕｌｉｎｇ（ＩｎｓｔｉｔｕｔｅｏｆＲｏｃｋａｎｄＭｉｎｅ...     

Linear Stability of Taylor-Couette Flows with Axial Heat Buoyancy

The linear stability is studied of flows confined between two concentric cylinders, in which the radial temperature gradient and axial gravity are considered for an incompressible Newtonian fluid. Numerical method based on the Petrov-Galerkin scheme is developed to deal with the buoyancy term in momentum equations and an additional temperature perturbation equation. Computations of the neutral stability curves are performed for different rotation cases. It is found that the flow instability is influenced by both centrifugal and axial shear instabilities, and the two instability mechanisms interact with each other. The outer cylinder rotation plays dual roles of stabilizer and destabilizer under different rotating stages with the inner cylinder at rest. For the heat buoyancyinduced axial flow, spiral structures are found in the instability modes.     

Linear Stability of Flows in a Squeeze Film

We study linear stability of viscous flows in a squeeze lubrication film, in which the flow varies slowly in space and time, between two parallel plates moving normal to each other with a slow constant speed, generalizing the inviscid results of Aristov and Gitman [J. Fluid Mech. 464 (2002) 209]. The temporal evolution of twodimensional disturbances for this physical situation, including the asymptotic behaviour of a long term or the transient behaviour of some time interval, is obtained by the construction of a low-dimensional Galerkin method.It is found that the wall boundaries typically play dual roles of stabilizer and destabilizer. They constrain the development of disturbances and have stabilizing influences. However, they give rise to velocity shear, which is diffused by viscosity and thereby tends to destabilize the flow.     

α-胰凝乳蛋白酶在相转移Fe_3O_4纳米粒子表面的固定化

采用高温热分解前驱体乙酰丙酮铁法合成了尺寸均一且分散性好的油溶性Fe3O4纳米粒子,通过表面配体置换直接将其表面换为水溶性分子聚乙二醇二酸(PEG diacid),形成了具有表面功能基的稳定无毒的水溶性磁性复合体系.TEM,M-H曲线,FTIR和TGA等表征结果表明,油溶性Fe3O4纳米粒子已成功转移至水相,且具有很好的顺磁性及生物相容性.研究结果表明,α-胰凝乳蛋白酶(α-ChT)被成功地固载到水溶性Fe3O4纳米粒子表面,与自由酶相比,固定化酶的热稳定性明显提高,并体现出良好的可重复利用性.