随机共振实验

介绍了随机共振现象的基本原理、模拟电路,给出了一组实验结果,并绘制了实验曲红,分析了随机共振产生的原因。     

Solvent Suppression in Intermolecular Magnetic Resonance Spectra Multiple-Quantum Coherence Nuclear with Only z-axis Gradients

The solvent peak in the intermolecular multiple-quantum coherence spectra can be suppressed by either applying pulse field gradients or spinning sample along the magic angle direction （φ = 54.7）. However, these two methods also suppress the signals of the solute. We design two pulse sequences with only z-axis gradients to suppress the solvent peak without reducing the intensity of solute signals. Compared to the former pulse sequence, the latter pulse sequence is insensitive to the imperfection of pulse flip angles. When the flip angles of the second pulse sequence are purposely deviated 1/10 from the optimal values, the solvent peak is still weak. Theoretical expressions, experimental observations and computer simulations demonstrate that the two methods can be used to effectively suppress solvent peak in intermolecular multiple-quantum coherence spectra.