Some transformations of N-(2,3-epoxypropyl)-1,8-naphthosultam

A method of synthesis has been developed for N-(2,3-epoxypropyl)-1,8-naphthosultam and some transformations of this compound were studied.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 236–242, February, 2000.     

Properties of spectral covariance for linear processes with infinite variance

We consider a measure of dependence for symmetric α-stable random vectors, which was introduced by the second author in 1976. We demonstrate that this measure of dependence, which we suggest to call the spectral covariance, can be extended to random vectors in the domain of normal attraction of general stable vectors. We investigate the asymptotic of the spectral covariance function for linear stable (Ornstein–Uhlenbeck, log-fractional, linear-fractional) processes with infinite variance and show that, in comparison with the results on the properties of codifference of these processes, obtained two decades ago, the results for the spectral variance are obtained under more general conditions and calculations are simpler.     

On-chip fraction collection for multiple selected ssDNA fragments using isolated extraction channels

High efficiency and high-purity fraction collection is highly sought in analysis of fragments-of-interest from selective polymerase chain reaction (PCR) products generated by High Coverage Gene Expression Profiling (HiCEP) methods. Here we demonstrate a new electrophoretic chip device enabling automatic high-efficient fractionation of multiple ssDNA target fragments during a run of separation. We used thoroughly isolated extraction channels for each selected target to reduce the risk of cross-contamination between targets due to cross-talk of extraction channels. Fragments of 35, 108 and 138 b, were successfully isolated, then the recovery was PCR-amplified and assessed by capillary electrophoresis (CE) analysis. Total impurity level of the targets due to unwanted fragments of 0.7%, 2% and 6% respectively, was estimated. Difficulties in collecting multiple target factions are due to band diffusion and DNA adsorption to the walls for the fragments in the separation channel, which is generated by transferring the DNA target fraction from the extraction section to the target reservoir. Therefore, we have carefully measured band broadening and analyzed its influence on the separation resolution due to the delay.     

Nanoparticle plasmon-assisted two-photon polymerization induced by incoherent excitation source

We demonstrate the possibility to achieve optical triggering of photochemical reactions via two-photon absorption using incoherent light sources. This is accomplished by the use of arrays of gold nanoparticles, specially tailored with high precision to obtain high near-field intensity enhancement.