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排序方式: 共有63条查询结果,搜索用时 234 毫秒
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J. Wt Timmermans D. de Wit H. Toumois B. R. Leeflang J. F. G. Vliegenthart 《Journal of carbohydrate chemistry》2013,32(7):969-979
Abstract Molecular Dynamics (MD) calculations have been performed on nystose in water. According to these calculations the glycosidic linkages of the molecule are flexible. Structures obtained with MD calculations are compared with NMR data of several inulin related oligosaccharides and inulin, resulting in a model for the conformation of their fructofuranosyl residues. To extend the set of available NMR data of inulin related oligosaccharides, the complete assignment of the 1H and 13C NMR signals of β-D-fructofuranosyl-(2->l)-ß-D-fructofuranosyl-(2->l)-ß-D-fructofuranosyl-(2->l)-ß-D-fructofuranosyl-(2->l)-α-D-glucopyranoside has been given here, using several 2D homo- and heteronuclear NMR experiments. Accurate coupling constants have been obtained by simulation of the 600 MHz 1D NMR spectra. 相似文献
3.
J. W. Timmermans M. B. van Leeuwen H. Tournois D. de Wit J. F.G. Vliegenthart 《Journal of carbohydrate chemistry》2013,32(6):881-888
Abstract A method, using anion exchange chromatography and pulsed amperometric detection, is described for quantitative analysis of the oligosaccharides present in inulin. The analysis of a number averaged and molecular weight averaged degree of polymerisation and the dispersion of inulin and inulin fractions is given. 相似文献
4.
J. W. Timmermans P. M.P. Bogaert D. de Wit J. F.G. Vliegenthart 《Journal of carbohydrate chemistry》2013,32(7):1145-1158
Abstract The complete assignment of the 1H and 13C NMR spectra for permethylated sucrose, 1-kestose and nystose are given. Methylation of these inulin oligosaccharides did not change the conformation of the ring structures. A partially methylated derivative of nystose has been prepared using water as the solvent. The difference in reactivity of the various hydroxyl groups of nystose appeared to be very small. 相似文献
5.
Piotr Fryzlewicz Catherine Timmermans 《Journal of computational and graphical statistics》2016,25(3):879-898
We propose the shape-adaptive Haar (SHAH) transform for images, which results in an orthonormal, adaptive decomposition of the image into Haar-wavelet-like components, arranged hierarchically according to decreasing importance, whose shapes reflect the features present in the image. The decomposition is as sparse as it can be for piecewise-constant images. It is performed via a stepwise bottom-up algorithm with quadratic computational complexity; however, nearly linear variants also exist. SHAH is rapidly invertible. We show how to use SHAH for image denoising. Having performed the SHAH transform, the coefficients are hard- or soft-thresholded, and the inverse transform taken. The SHAH image denoising algorithm compares favorably to the state of the art for piecewise-constant images. A clear asset of the methodology is its very general scope: it can be used with any images or more generally with any data that can be represented as graphs or networks. 相似文献
6.
Simultaneous microdetermination of carbon, hdrogen and iodine in organic substances is practically possible on a five milligramme sample. The two first mentioned elements are gravimetrically deetermined, iodine being titrated. The available results are quite good.New calibration technique of capillary instruments enables precise titration of very small quantities of Iodine. It will help to improve precision of this determination. 相似文献
7.
Sans résuméAvec 4 figures. 相似文献
8.
M. Nuñez Portela E. A. Dijck A. Mohanty H. Bekker J. E. van den Berg G. S. Giri S. Hoekstra C. J. G. Onderwater S. Schlesser R. G. E. Timmermans O. O. Versolato L. Willmann H. W. Wilschut K. Jungmann 《Applied physics. B, Lasers and optics》2014,114(1-2):173-182
A single Ra+ ion stored in a Paul radio frequency ion trap has excellent potential for a precision measurement of the electroweak mixing angle at low momentum transfer and as the most stable optical clock. The effective transport and cooling of singly charged ions of the isotopes 209Ra to 214Ra in a gas filled radio frequency quadrupole device is reported. The absolute frequencies of the transition 7s2S1/2–7d2D3/2 at wavelength 828 nm have been determined in 212–214Ra+ with ≤19 MHz uncertainty using laser spectroscopy on small samples of ions trapped in a linear Paul trap at the online facility Trapped Radioactive Isotopes: µicrolaboratories for fundamental Physics (TRIµP) of the Kernfysisch Versneller Instituut. 相似文献
9.
Sisu E Bosker WT Norde W Slaghek TM Timmermans JW Peter-Katalinić J Cohen-Stuart MA Zamfir AD 《Rapid communications in mass spectrometry : RCM》2006,20(2):209-218
A combined methodology for obtaining at the preparative scale and characterization by nanoelectrospray ionization (nanoESI) quadrupole time-of-flight (QTOF) mass spectrometry (MS) and tandem MS (MS/MS) of linear polysaccharides modified at the reducing end is presented. Two polydisperse maltodextrins (1000 and 3000 Da) and a high molecular weight polydisperse dextran (6000 Da) were coupled with hexamethylenediamine (HMD). The coupling products were analyzed by nanoESI-QTOF-MS in the positive ion mode and MS/MS using collision-induced dissociation (CID) at low energies. In the HMD-M1000 mixture, the polysaccharide chains containing from 2 to 8 Glc residues were detected, while in HMD-M3000 we identified a complete series of chains containing from 8 to 21 Glc moieties. The employed ESI conditions enhanced the detection of chains with up to 46 Glc residues in the HMD-D6000 sample. By optimized MS/MS, HMD-modified polysaccharides of 3, 4, 5, 12 and 46 degrees of polymerization yielded product ion spectra exhibiting the whole set of Y- and B-fragment ions. The MS structural data were obtained within a few minutes of signal acquisition, with a sample consumption situating the analysis sensitivity in the picomolar range. 相似文献
10.
Mathematical Programming - Given two matroids $$\mathcal {M}_{1} = (E, \mathcal {B}_{1})$$ and $$\mathcal {M}_{2} = (E, \mathcal {B}_{2})$$ on a common ground set E with base sets $$\mathcal... 相似文献