全文获取类型
收费全文 | 667篇 |
免费 | 42篇 |
国内免费 | 2篇 |
专业分类
化学 | 346篇 |
晶体学 | 4篇 |
力学 | 23篇 |
数学 | 106篇 |
物理学 | 232篇 |
出版年
2023年 | 15篇 |
2022年 | 11篇 |
2021年 | 18篇 |
2020年 | 25篇 |
2019年 | 20篇 |
2018年 | 27篇 |
2017年 | 24篇 |
2016年 | 48篇 |
2015年 | 34篇 |
2014年 | 28篇 |
2013年 | 50篇 |
2012年 | 42篇 |
2011年 | 54篇 |
2010年 | 42篇 |
2009年 | 27篇 |
2008年 | 25篇 |
2007年 | 22篇 |
2006年 | 25篇 |
2005年 | 17篇 |
2004年 | 8篇 |
2003年 | 9篇 |
2002年 | 14篇 |
2001年 | 11篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1996年 | 9篇 |
1995年 | 3篇 |
1994年 | 9篇 |
1993年 | 16篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 11篇 |
1989年 | 5篇 |
1988年 | 1篇 |
1987年 | 4篇 |
1986年 | 6篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1959年 | 2篇 |
排序方式: 共有711条查询结果,搜索用时 421 毫秒
1.
A sharp‐interface immersed boundary framework for simulations of high‐speed inviscid compressible flows 下载免费PDF全文
Shuvayan Brahmachary Ganesh Natarajan Vinayak Kulkarni Niranjan Sahoo 《国际流体数值方法杂志》2018,86(12):770-791
A new finite‐volume flow solver based on the hybrid Cartesian immersed boundary (IB) framework is developed for the solution of high‐speed inviscid compressible flows. The IB method adopts a sharp‐interface approach, wherein the boundary conditions are enforced on the body geometry itself. A key component of the present solver is a novel reconstruction approach, in conjunction with inverse distance weighting, to compute the solutions in the vicinity of the solid‐fluid interface. We show that proposed reconstruction leads to second‐order spatial accuracy while also ensuring that the discrete conservation errors diminish linearly with grid refinement. Investigations of supersonic and hypersonic inviscid flows over different geometries are carried out for an extensive validation of the proposed flow solver. Studies on cylinder lift‐off and shape optimisation in supersonic flows further demonstrate the efficacy of the flow solver for computations with moving and shape‐changing geometries. These studies conclusively highlight the capability of the proposed IB methodology as a promising alternative for robust and accurate computations of compressible fluid flows on nonconformal Cartesian meshes. 相似文献
2.
Bamadev Sahoo 《Nonlinear dynamics》2020,99(2):945-979
This paper investigates nonlinear combined parametric transverse vibrations of a traveling viscoelastic beam. The combined parametric excitations originate from the time dependency of axial velocity as well as axial tension. Two parametric excitations are enforced into the system amid the internal resonance. Two-frequency parametric resonance is assumed to be comprised of combination parametric resonance of first two modes due to the time dependency of axial velocity, and the principal parametric resonance of first mode due to the variable tension in the axial direction in the presence of internal resonance for viscoelastic beam is considered for the first time. The higher-order integro-partial differential equation of motion is solved through direct method of multiple scales. Continuation algorithm is employed to explore the stability and various bifurcations of the nonlinear dynamic system. Focus has been made to study the effect of variations of fluctuating tension component, fluctuating velocity component independently and when combined, internal and parametric frequency detuning parameters and damping on the system response. Frequency response equilibrium curves are complex and unique in shapes which are embodied with various bifurcations. Such steady-state behavior is not seen in the existent literature. With variation in fluctuating velocity component, the number of steady-state nontrivial equilibrium curves increases to three and with variation in fluctuating axial tension, they become four. In this process, significant changes in stability, number and position of various bifurcations like supercritical and subcritical pitchfork, Hopf and saddle node are observed. Unlike the previous study, the shape, stability and bifurcations of equilibrium curves under the combined effect of axial velocity and tension closely match with the case of fluctuating axial tension component. The effect of variation in internal and parametric frequency detuning parameter is more realized for second mode compared to first mode. A comparison of the present work with a previous one where axial tension is variable reveals many qualitative and quantitative similarities and dissimilarities. But when compared with earlier work where axial velocity is constant, significant dissimilarities are surfaced. The system displays a wide ranging dynamic behavior including stable periodic, quasiperiodic and unstable chaotic behavior. The numerical computation depicts various nonlinear characteristics and oscillatory behaviors which are not found so far in the existent literature. 相似文献
3.
4.
In this article, the analysis of Tsallis holographic dark energy(which turns into holographic dark energy for a particular choice of positive non-additivity parameter δ) in modified f(T, B) gravity with the validity of thermodynamics and energy conditions for a homogeneous and isotropic FLRW Universe has been studied. The enlightenment of the field equation towards f(T,B)=αT~m+βB~n, made possible by the fact that the model is purely accelerating,corresponds to q=-0.54(Mamon and Das 2017 Eur. Phys.J.C 77 49). The generalized second law of thermodynamics is valid not only for the same temperature inside the horizon, but also for the apparent horizon for a change in temperature. The essential inspiration driving this article is to exhibit the applicability that the holographic dark energy achieved from standard Tsallis holographic dark energy and the components acquired from f(T, B) gravity are identical for the specific bounty of constants. The analysis of energy conditions confirms that the weak energy condition and the null energy condition are fulfilled throughout the expansion, while violation of the strong energy condition validates the accelerated expansion of the Universe.With the expansion, the model becomes a quintessence dominated model. The dominant energy condition is not observed initially when the model is filled with genuine baryonic matter,whereas it appears when the model is in the quintessence dominated era. 相似文献
5.
ABSTRACTWe study the effect of the external electric field Fext on the low-temperature electron mobility μ in an asymmetrically doped AlxGa1-xAs based V-shaped double quantum well (VDQW) structure. We show that nonlinearity of µ occurs under double subband occupancy on account of intersubband effects. The field Fext alters the VDQW potential leading to transfer of subband wave functions between the wells, which affects the scattering potentials and hence μ. In the VDQW structure, due to the alloy channel layer, the alloy disorder (Al-) scattering happens to be significant along with the ionised impurity (Imp-) scattering. The non-linear behaviour of μ is because of μImp, while the overall magnitude of μ is mostly due to μAl. The increase of difference in the doping concentrations of the outer barriers increases the nonlinearity of μ. The oscillatory character of μ is amended by varying the width of the well and barrier and also the height of the VDQW. Our results can be used to study VDQW based nanoscale field effect transistor structures. 相似文献
6.
Khalid Naim Manjeet Singh Sachin Sharma Dr. Rajesh V. Nair Prof. Paloth Venugopalan Dr. Subash Chandra Sahoo Dr. Prakash P. Neelakandan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(52):11979-11984
The design of molecular compounds that exhibit flexibility is an emerging area of research. Although a fair amount of success has been achieved in the design of plastic or elastic crystals, realizing multidimensional plastic and elastic bending remains challenging. We report herein a naphthalidenimine–boron complex that showed size-dependent dual mechanical bending behavior whereas its parent Schiff base was brittle. Detailed crystallographic and spectroscopic analysis revealed the importance of boron in imparting the interesting mechanical properties. Furthermore, the luminescence of the molecule was turned-on subsequent to boron complexation, thereby allowing it to be explored for multimode optical waveguide applications. Our in-depth study of the size-dependent plastic and elastic bending of the crystals thus provides important insights in molecular engineering and could act as a platform for the development of future smart flexible materials for optoelectronic applications. 相似文献
7.
Dr. Thangavel Vijayakanth Supriya Sahoo Premkumar Kothavade Vijay Bhan Sharma Prof. Dr. Dinesh Kabra Dr. Jan K. Zaręba Dr. Kadhiravan Shanmuganathan Prof. Dr. Ramamoorthy Boomishankar 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(3):e202214984
Hybrid materials possessing piezo- and ferroelectric properties emerge as excellent alternatives to conventional piezoceramics due to their merits of facile synthesis, lightweight nature, ease of fabrication and mechanical flexibility. Inspired by the structural stability of aminophosphonium compounds, here we report the first A3BX6 type cyanometallate [Ph2(iPrNH)2P]3[Fe(CN)6] ( 1 ), which shows a ferroelectric saturation polarization (Ps) of 3.71 μC cm−2. Compound 1 exhibits a high electrostrictive coefficient (Q33) of 0.73 m4 C−2, far exceeding those of piezoceramics (0.034–0.096 m4 C−2). Piezoresponse force microscopy (PFM) analysis demonstrates the polarization switching and domain structure of 1 further confirming its ferroelectric nature. Furthermore, thermoplastic polyurethane (TPU) polymer composite films of 1 were prepared and employed as piezoelectric nanogenerators. Notably, the 15 wt % 1 -TPU device gave a maximum output voltage of 13.57 V and a power density of 6.03 μW cm−2. 相似文献
8.
Dr. Shubham Dutta Dr. Rajendra K. Mallick Prof. Dr. Akhila K. Sahoo 《Angewandte Chemie (International ed. in English)》2023,62(30):e202300816
The use of ynamides in organic synthesis has gained significant attention due to their ability to provide access to complex molecular structures through transformations such as 1,2-difunctionalization and annulation reactions. These reactions enable the formation of highly functionalized N-bearing olefins and unusual N-bearing heterocycles. In this minireview, we present a systematic overview of the regioselective difunctionalization and annulation reactions of ynamides. We discuss the multi-component reactions, and radical-triggered functionalizations across the ynamides carbon–carbon multiple bonds and the use of bifunctional reagents in annulation of ynamides, highlighting their potential in expanding the substrate scope. Furthermore, we provide insights into the mechanistic breakthroughs that have been achieved in recent years in the development of these reactions. Finally, we emphasize the promising future prospects of ynamides as versatile building blocks for the synthesis of complex molecular architectures. 相似文献
9.
Dr. Anoop Kumar Kushwaha Sushri Soumya Jena Dr. Mihir Ranjan Sahoo Dr. Debashish Das Prof. Saroj Kumar Nayak 《Chemphyschem》2023,24(18):e202300032
High-voltage alkali metal-ion batteries (AMIBs) require a non-hazardous, low-cost, and highly stable electrolyte with a large operating potential and rapid ion conductivity. Here, we have reported a halogen-free high-voltage electrolyte based on SiB11(BO)12−. Because of the weak π-orbital interaction of −BO as well as the mixed covalent and ionic interaction between SiB11-cage and −BO ligand, SiB11(BO)12− has colossal stability. SiB11(BO)12− possesses extremely high vertical detachment energy (9.95 eV), anodic voltage limit (∼10.05 V), and electrochemical stability window (∼9.95 V). Furthermore, SiB11(BO)12− is thermodynamically stable at high temperatures, and its large size allows for faster cation movement. The alkali salts MSiB11(BO)12 (M=Li, Na, and K) are easily dissociated into ionic components. Electrolytes based on SiB11(BO)12− greatly outperform commercial electrolytes. In short, SiB11(BO)12−-based compound is demonstrated to be a high-voltage electrolyte for AMIBs. 相似文献
10.
Palladium(II)‐Catalyzed meta‐CH Olefination: Constructing Multisubstituted Arenes through Homo‐Diolefination and Sequential Hetero‐Diolefination 下载免费PDF全文
Dr. Milan Bera Arun Maji Dr. Santosh K. Sahoo Prof. Debabrata Maiti 《Angewandte Chemie (International ed. in English)》2015,54(29):8515-8519
Divinylbenzene derivatives represent an important class of molecular building blocks in organic chemistry and materials science. Reported herein is the palladium‐catalyzed synthesis of divinylbenzenes by meta‐C? H olefination of sulfone‐based arenes. Successful sequential olefinations in a position‐selective manner provided a novel route for the synthesis of hetero‐dialkenylated products, which are difficult to access using conventional methods. Additionally, 1,3,5‐trialkenylated compounds can be generated upon successful removal of the directing group. 相似文献