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排序方式: 共有349条查询结果,搜索用时 15 毫秒
1.
界面是由复杂的界面相简化而成的,界面破坏实际是界面相材料的破坏。数值计算为了方便,如经典模型和内聚力模型等,都把很薄的界面相作无厚度化处理。导致只能考虑界面的面力,而无法考虑界面相内的应力(平行于界面方向的应力)。使界面失效准则先天性地排除了界面相内部应力的影响,从界面相材料失效机理的角度来看这是不够严谨的。本文将界面相材料等效为一种弹性连续体,由界面本构关系推导得到了一种新的界面单元。该单元具有界面参数易确定、对界面相物性可以进行等效描述等优点。通过商用有限元软件ABAQUS和用户子程序UEL实现了数值分析,并与直接物理模型的数值模拟结果进行对比,证明了本方法的简便及准确性。通过对不同界面相厚度结构的进一步分析,探讨了本文方法的可行范围。 相似文献
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Ionic liquid and aqueous two‐phase extraction based on salting‐out coupled with high‐performance liquid chromatography for the determination of seven rare ginsenosides in Xue‐Sai‐Tong injection 下载免费PDF全文
Lan‐Jie Li Yong‐Ri Jin Xiao‐Zhong Wang Ying Liu Qian Wu Xiao‐Lei Shi Xu‐Wen Li 《Journal of separation science》2015,38(17):3055-3062
A method of ionic liquid salt aqueous two‐phase extraction coupled with high‐performance liquid chromatography has been developed for the analysis of seven rare ginsenosides including Rg6, F4, 20(S)‐Rg3, 20(R)‐Rg3, Rk3, Rk1, and Rg5 in Xue‐Sai‐Tong injection. The injection was mixed with ionic liquid 1‐butyl‐3‐methylimidazolium bromide aqueous solution, and a mixture was obtained. With the addition of sodium dodecyl sulfate and dipotassium phosphate into the mixture, the aqueous two‐phase mixture was formed after ultrasonic treatment and centrifuged. Rare ginsenosides were extracted into the upper phase. To obtain a high extraction factors, various influences were considered systematically, such as the volume of ionic liquid, the category and amount of salts, the amount of sodium dodecyl sulfate, the pH value of system, and the time of ultrasonic treatment. Under the optimal condition, rare ginsenosides in Xue‐Sai‐Tong injection were enriched and detected, the recoveries of seven rare ginsenosides ranged from 90.05 to 112.55%, while relative standard deviations were lower than 2.50%. The developed method was reliable, rapid and sensitive for the determination of seven rare ginsenosides in the injections. 相似文献
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Ki Dong Yang Woo Ri Ko Jun Ho Lee Prof. Sung Jae Kim Prof. Hyomin Lee Prof. Min Hyung Lee Prof. Ki Tae Nam 《Angewandte Chemie (International ed. in English)》2017,56(3):796-800
The electrocatalytic conversion of CO2 to value-added hydrocarbons is receiving significant attention as a promising way to close the broken carbon-cycle. While most metal catalysts produce C1 species, such as carbon monoxide and formate, the production of various hydrocarbons and alcohols comprising more than two carbons has been achieved using copper (Cu)-based catalysts only. Methods for producing specific C2 reduction outcomes with high selectivity, however, are not available thus far. Herein, the morphological effect of a Cu mesopore electrode on the selective production of C2 products, ethylene or ethane, is presented. Cu mesopore electrodes with precisely controlled pore widths and depths were prepared by using a thermal deposition process on anodized aluminum oxide. With this simple synthesis method, we demonstrated that C2 chemical selectivity can be tuned by systematically altering the morphology. Supported by computational simulations, we proved that nanomorphology can change the local pH and, additionally, retention time of key intermediates by confining the chemicals inside the pores. 相似文献
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Wen‐Hao Chen Chang‐Ri Han Yang Hui Da‐Shuai Zhang Xin‐Ming Song Guang‐Ying Chen Xiao‐Ping Song 《Helvetica chimica acta》2015,98(5):724-730
Two new eremophilane‐type sesquiterpenoids, 1α‐hydroxyeremophila‐6,9,11‐trien‐8‐one ( 1 ), 4α‐hydroxyeremophila‐1,9‐diene‐3,8‐dione ( 2 ), and a new friedelane‐type triterpenoid, friedelane‐3α,16β‐diol ( 4 ), along with six known terpenoids, 3 and 5 – 9 , have been isolated from the stems of Drypetes congestiflora. Their structures and relative configurations were elucidated on the basis of detailed spectroscopic analyses and by comparison of their NMR data with those reported in the literature. All of the compounds, 1 – 9 , were isolated for the first time from this species. Compound 3 exhibited moderate cytotoxic activities against the A549 and B16F10 cell lines. 相似文献
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A facile method for solid‐phase organic synthesis of 1‐substituted‐4‐vinyl‐1,2,3‐triazoles from polystyrene‐supported but‐3‐ynyl selenide has been developed. This sequential [3+2] cycloaddition and oxidation–elimination reactions could be carried out under mild reaction conditions with straightforward operation and good yield and purity of the products, and broad scope of substrates, and could be applied in this reaction system in generation of a small library of title compounds. 相似文献
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SongIl Ri 《Indagationes Mathematicae》2018,29(3):962-971
The aim of this paper is to present a new idea to construct the nonlinear fractal interpolation function, in which we exploit the Matkowski and the Rakotch fixed point theorems. Our technique is different from the methods presented in the previous literatures. 相似文献
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Christopher Jainski Martin Rißmann Suad Jakirlic Benjamin Böhm Andreas Dreizler 《Flow, Turbulence and Combustion》2018,100(1):177-196
The presence of a turbulent premixed flame strongly influences the properties of the adjacent velocity boundary layer. This influence is studied here using a generic configuration where at atmospheric pressure turbulent premixed methane/air flames interact with a temperature stabilized wall. The experiment is optimized for well-defined boundary conditions and optical accessibility in the zone where the flame impinges at the wall. Laser based diagnostic methods are used to measure two components of the velocity field by particle image velocimetry simultaneously with the flame front position using laser induced fluorescence of the OH molecule. Two measurement planes are selected that are aligned perpendicularly to the surface of the wall. Based on this data, the flow field near the wall is analyzed by different methodologies using laboratory-fixed and flame-conditioned statistics, a quadrant splitting analysis of the Reynolds stresses and an evaluation of the production term of the turbulent kinetic energy. The results of chemically reactive cases are compared to their corresponding non-reactive flows for otherwise identical inflow conditions. In the zone of flame-wall interactions the boundary layer structure and its turbulence are dominated by the turbulent flame. Important features are that the flame compresses the boundary layer already upstream the location where the flame is finally quenched and that ejection and sweeps are no longer the dominant mechanisms as in non-reactive boundary layers. This experimental data may serve additionally as a database for model development for near wall reactive flows. 相似文献
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