Et2Zn-mediated stoichiometric C(sp)-H silylation of 1-alkynes and chlorosilanes

A first example of an Et₂Zn mediated silylation of 1-aklynes is reported. A series of functional groups are tolerated in this reaction. Mechanistic studies support Zn alkynilides as intermediates in the reaction. This reaction protocol provides a practical method for the preparation of alkynylsilanes and expands the application of organometallic zinc in organic synthesis.     

Two Projection Algorithms for Solving the Split Common Fixed Point Problem

Journal of Optimization Theory and Applications - We study the split common fixed point problem for Bregman relatively nonexpansive operators in real reflexive Banach spaces. Using Bregman...     

An Alternative Way to Generalize the Pentagon

We introduce the concept of a pentagonal geometry as a generalization of the pentagon and the Desargues configuration, in the same vein that the generalized polygons share the fundamental properties of ordinary polygons. In short, a pentagonal geometry is a regular partial linear space in which for all points x, the points not collinear with the point x, form a line. We compute bounds on their parameters, give some constructions, obtain some nonexistence results for seemingly feasible parameters and suggest a cryptographic application related to identifying codes of partial linear spaces.     

Finite element approximations of a nonlinear diffusion model with memory

The convergence of a finite element scheme approximating a nonlinear system of integro-differential equations is proven. This system arises in mathematical modeling of the process of a magnetic field penetrating into a substance. Properties of existence, uniqueness and asymptotic behavior of the solutions are briefly described. The decay of the numerical solution is compared with both the theoretical and finite difference results.     

The EPR Spectra of Manganese(II) on Sulfonated Polystyrene Resins Cross-linked with Pure Divinylbenzene Isomers

The EPR spectra of manganese(II) ions on sulfonated polystyrene cross-linked with either pure meta or pure para divinylbenzene show distinctions indicative of ionic environments of different symmetry.     

Efficient numerical integration of arbitrarily broken cells using the moment fitting approach

The finite cell method is based on a fictitious domain approach, providing a simple and fast mesh generation of structures with complex geometries. However, this simplification leads to intersected cells where the standard Gauss quadrature does not perform well. To perform the numerical integration of these cells, we use the moment fitting approach that generates an individual quadrature rule for every broken cell. In this paper, we will perform a non-linear optimization approach to find the optimal position and number of the integration points. The findings show that the proposed method leads to efficient quadrature rules that require less integration points than other existing integration methods. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)