全文获取类型
收费全文 | 1299篇 |
免费 | 43篇 |
国内免费 | 7篇 |
专业分类
化学 | 983篇 |
晶体学 | 13篇 |
力学 | 12篇 |
数学 | 82篇 |
物理学 | 259篇 |
出版年
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 16篇 |
2019年 | 21篇 |
2018年 | 18篇 |
2017年 | 11篇 |
2016年 | 35篇 |
2015年 | 28篇 |
2014年 | 28篇 |
2013年 | 64篇 |
2012年 | 82篇 |
2011年 | 78篇 |
2010年 | 47篇 |
2009年 | 49篇 |
2008年 | 82篇 |
2007年 | 73篇 |
2006年 | 73篇 |
2005年 | 79篇 |
2004年 | 77篇 |
2003年 | 67篇 |
2002年 | 55篇 |
2001年 | 19篇 |
2000年 | 15篇 |
1999年 | 10篇 |
1998年 | 12篇 |
1997年 | 8篇 |
1996年 | 12篇 |
1995年 | 11篇 |
1994年 | 19篇 |
1993年 | 22篇 |
1992年 | 16篇 |
1991年 | 11篇 |
1990年 | 10篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 16篇 |
1984年 | 15篇 |
1983年 | 17篇 |
1982年 | 11篇 |
1981年 | 11篇 |
1980年 | 11篇 |
1979年 | 15篇 |
1978年 | 10篇 |
1977年 | 11篇 |
1976年 | 6篇 |
1975年 | 11篇 |
1974年 | 7篇 |
1973年 | 6篇 |
排序方式: 共有1349条查询结果,搜索用时 15 毫秒
1.
Feng Cheng Shuqi Wu Wenwei Zheng Shengqun Su Takumi Nakanishi Wenhuang Xu Pritam Sadhukhan Hibiki Sejima Shimon Ikenaga Kaoru Yamamoto Kaige Gao Shinji Kanegawa Prof. Osamu Sato 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(59):e202202161
The crystallization of a complex having electron transfer properties in a polar space group can induce the polarization switching of a crystal in a specific direction, which is attractive for the development of sensors, memory devices, and capacitors. Unfortunately, the probability of crystallization in a polar space group is usually low. Noticing that enantiopure compounds crystallize in Sohncke space groups, this paper reports a strategy for the molecular design of non-ferroelectric polarization switching crystals based on the use of intramolecular electron transfer and chirality. In addition, this paper describes the synthesis of a mononuclear valence tautomeric (VT) cobalt complex bearing an enantiopure ligand. The introduction of enantiomer enables the crystallization of the complex in the polar space group (P21). The polarization of the crystals along the b-axis direction is not canceled out and the VT transition is accompanied by a change in the macroscopic polarization of the polar crystal. Polarization switching via electron transfer is realized at around room temperature. 相似文献
2.
3.
4.
Prof. Shinji Toyota Dr. Eiji Tsurumaki 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(28):6878-6890
Saturn-like systems consisting of nanoscale rings and spheres are fascinating motifs in supramolecular chemistry. Several ring molecules are known to include spherical molecules at the center of the cavity via noncovalent attractive interactions. In this Minireview, we generalize the molecular design, the structural features, and the supramolecular chemistry of such “nano-Saturns”, which consist of monocyclic rings and fullerene spheres (mainly C60), on the basis of previous experimental and theoretical studies. Ring molecules are classified into three types (loop, belt, and disk) according to their shapes and possible interactions. Whereas typical belt-shaped rings tend to form tight complexes due to the wide contact area via π–π interactions, flat disk-shaped rings generally form weak complexes due to the narrow contact area mainly via CH–π interactions. In spite of the small association energies, disk-shaped rings are attractive because such rings can mimic the planet Saturn precisely as exemplified by an anthracene cyclic hexamer–C60 complex. 相似文献
5.
Hirao Shigekazu Kakiuchi Hideki Akata Naofumi Tamari Toshiya Sugihara Shinji Shima Nagayoshi Yokoyama Sumi Tanaka Masahiro 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(7):3077-3083
Journal of Radioanalytical and Nuclear Chemistry - This paper discusses the spatiotemporal variation in atmospheric tritiated water (HTO) concentration near the Fukushima Daiichi Nuclear Power... 相似文献
6.
Salt‐Free Reduction of Nonprecious Transition‐Metal Compounds: Generation of Amorphous Ni Nanoparticles for Catalytic C–C Bond Formation 下载免费PDF全文
Dr. Taiga Yurino Yohei Ueda Dr. Yoshiki Shimizu Dr. Shinji Tanaka Haruka Nishiyama Prof. Dr. Hayato Tsurugi Prof. Dr. Kazuhiko Sato Prof. Dr. Kazushi Mashima 《Angewandte Chemie (International ed. in English)》2015,54(48):14437-14441
A salt‐free procedure for the generation of a wide variety of metal(0) particles, including Fe, Co, Ni, and Cu, was achieved using 2,3,5,6‐tetramethyl‐1,4‐bis(trimethylsilyl)‐1,4‐diaza‐2,5‐cyclohexadiene ( 1 ), which reduced the corresponding metal precursors under mild conditions. Notably, Ni particles formed in situ from the treatment of Ni(acac)2 (acac=acetylacetonate) with 1 in toluene exhibited significant catalytic activity for reductive C? C bond‐forming reactions of aryl halides in the presence of excess amounts of 1 . By examination of high‐magnification transmission electron microscopy images and electron diffraction patterns, we concluded that amorphous Ni nanoparticles (Ni aNPs) were essential for the high catalytic activity. 相似文献
7.
Caesaljaponins A and B: New Cassane‐Type Furanoditerpenoids from the Seeds of Caesalpinia decapetala var. japonica 下载免费PDF全文
Two new cassane‐type furanoditerpenoids, designated caesaljaponin A and caesaljaponin B ( 1 and 2 , resp.), were isolated from seeds of Caesalpinia decapetala var. japonica. The structures were elucidated by spectroscopic data, and the absolute configuration of 1 was determined by X‐ray crystallographic analysis using the anomalous scattering of CuKα radiation. 相似文献
8.
Ruthenium‐Immobilized Periodic Mesoporous Organosilica: Synthesis,Characterization, and Catalytic Application for Selective Oxidation of Alkanes 下载免费PDF全文
Nobuhiro Ishito Dr. Hirokazu Kobayashi Dr. Kiyotaka Nakajima Yoshifumi Maegawa Dr. Shinji Inagaki Dr. Kenji Hara Prof. Dr. Atsushi Fukuoka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(44):15564-15569
Periodic mesoporous organosilica (PMO) is a unique material that has a crystal‐like wall structure with coordination sites for metal complexes. A Ru complex, [RuCl2(CO)3]2, is successfully immobilized onto 2,2’‐bipyridine (BPy) units of PMO to form a single‐site catalyst, which has been confirmed by various physicochemical analyses. Using NaClO as an oxidant, the Ru‐immobilized PMO oxidizes the tertiary C?H bonds of adamantane to the corresponding alcohols at 57 times faster than the secondary C?H bonds, thereby exhibiting remarkably high regioselectivity. Moreover, the catalyst converts cis‐decalin to cis‐9‐decalol in a 63 % yield with complete retention of the substrate stereochemistry. The Ru catalyst can be separated by simple filtration and reused without loss of the original activity and selectivity for the oxidation reactions. 相似文献
9.
We studied, experimentally, the pattern dynamics and free surface deformation in Bénard–Marangoni convection, in a circular
container (aspect ratio = 6). The free surface deformation fields were visualized by interferometry and temperature fields
by infrared thermography. We considered the influence of the Marangoni (up to 2,623), Biot and Prandtl numbers. More dynamics
are induced by increasing the Biot number and transition to a time-dependent flow has been observed. Conversely, increasing
the Prandtl number reduces the dynamics. The deformation increases as a function of the Marangoni number until it reaches
asymptotic values, which are functions of the Biot and Prandtl numbers. 相似文献
10.
ABSTRACTThe objective of this study was to determine whether sodium caseinate can inhibit the aggregation of whey protein induced by pressure treatment. Solutions of β-lactoglobulin (β-Lg, 0.2%, w/v) and mixtures containing 0.2% (w/v) β-Lg and 0–0.5% (w/v) sodium caseinate (NaCas) were pressurized at 400–800?MPa. NaCas suppressed the aggregation of β-Lg induced by pressure treatment, and this function was dependent on the concentration of NaCas. Furthermore, NaCas altered the aggregation process of β-Lg by suppressing the transition of the aggregate from the soluble phase to the insoluble phase and, as a result, the fraction of insoluble aggregates was decreased. During this process, NaCas formed stable complexes with the denatured β-Lg, and the formation of complexes prevented further aggregation of β-Lg. These results indicate that NaCas exhibits a chaperone-like activity under high pressure. 相似文献