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1.
Kojima Kunihiko Miyazaki Mitsuharu Mizukami Fujio Maeda Kazuyuki 《Journal of Sol-Gel Science and Technology》1997,8(1-3):77-81
The structure of iron oxide was controlled by regulating the hydrolytic polymerization of aquo iron complexes with organic
polydentate ligands such as diols. Iron oxides were prepared by calcining the precursor polymers obtained from iron nitrate
nonahydrate and diols. When the diols were 1,2-pentanediol, 1,2-hexanediol and 1,2-octanediol, α-Fe2O3 with corundum structure appeared exclusively or as the main crystalline phase, in spite of the amount of diol used and the
calcination temperature. In the case of 1,2-decanediol and 1,2-dodecanediol, when five moles of the diols were used to one
mole of iron nitrate and the calcination temperatures were below 400°C, ψ-Fe2O3 with spinel structure appeared as the main phase and, when less than five moles of the diols were used, α-Fe2O3 appeared exclusively or as the main phase, irrespective of the calcination temperature. This tendency was also observed in
thin films. Thus, a transparent magnetic film composed of γ-Fe2O3 could be prepared by applying a benzene solution of the iron polymer, obtained with 5 equivalents of 1,2-decanediol, on quartz
and calcining the gel film at 350°C. 相似文献
2.
Wakako Tsugawa Shuichi Horiuchi Mitsuharu Tanaka Hitoshi Wake Koji Sode 《Applied biochemistry and biotechnology》1996,56(3):301-310
A novel glucose dehydrogenase (GDH) from a marine bacteriumCytophaga marinoflava IFO 14170 was isolated from its membrane fraction. This GDH catalyzes the oxidation of a hydroxy group of glucose, but does
not react in its C-l position. This enzyme is composed of a single peptide with a mol wt of 67,000. The GDH can react under
high salinity. The optimum pH is around 8.0, showing a typical property of marine bacterial enzymes. Using this novel enzyme,
an enzymatic determination of 1,5-anhydro-D-glucitol (1,5AG) utilizing 2,6-dichrolophenolindophenol (DCIP) and phenazine methosulfate
(PMS) as electron mediators was caried out. A good linear correlation was observed from 0.5 mM to 4 mM of 1,5AG. 相似文献
3.
Mizukami Fujio Maeda Kazuyuki Toba Makoto Sano Tsuneji Niwa Shu-ich Miyazaki Mitsuharu Kojima Kunihiko 《Journal of Sol-Gel Science and Technology》1997,8(1-3):101-106
The preparation of mullite by the sol-gel method using organic polydentate ligands and the effect of the raw materials and
organic polydentate ligands on the formation of mullite were investigated. Two series of samples were prepared using tetraethoxyorthosilicate
(TEOS) and aluminum nitrate nonahydrate, or dibutoxyethylacetoacetatoaluminum (Al(OBu)2(AcAcEt)) as the silica and alumina sources, respectively, and using ethylene glycol (EG), 1,3-propanediol (PD), 1,3-butanediol
(BD), 2-methyl-2, 4-pentanediol (MPD), diethlene glycol monoethyl ether (DEME) and ethoxyethanol as the ligands. When the
alumina source was aluminum nitrate nonahydrate, mullite was apt to appear in the order of EG>PD>MPD. When Al(OBu)2(AcAcEt) was the alumina source, the tendency toward the appearance of mullite crystalline phase was EG>BD>DEME>MPD. Between
the two alumina sources, aluminum nitrate nonahydrate gave mullite much easier than Al(OBu)2(AcAcEt). These relationships were discussed from the viewpoints of the coordination ability of the ligands and the miscibility
between the silica and alumina. 相似文献
4.
Toru Minami Ryoji Kouno Tatsuo Okauchi Mitsuharu Nakamura Junji Ichikawa 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):689-692
The α-phosphonovinyl anions, generated in situ from treatment of β-hetero-substituted vinyl-phosphonates 1a-c with LDA (or LTMP), were trapped with various electrophiles such as chlorotriorganosilanes, chlorotrimethylgermane, chlorotriorganotins, dimethyl disulfide, and halogen to afford the corresponding β-hetero-substituted α-functionalized vinylphosphonates 2–14 in good to excellent yields. The Friedel-Crafts reaction of α-(silyl) or α-(germyl)phosphonoketene dithioacetals 2, 9 or 4 with acid chlorides gave α-acylated phosphonoketene dithioacetals 15–19 in 53–91 % yields. The palladium-catalyzed cross-coupling reaction of β-ethoxy-α-(tributylstannyl)vinylphosphonate 13 with a variety of organic halides (R = acyl, allyl, aryl etc.) provided β-ethoxy-α-substituted vinylphosphonates 20–25 in good to moderate yields. The palladium-mediated cross-coupling reaction of α-(iodo)-vinyl-phosphonates 7, 14 with terminal acetylenes afforded α-alkynylated vinylphosphonates 26–29 in 69–83 % yields. 相似文献
5.
Messoud A. Efendiev Mitsuharu Ôtani 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2011,28(4):565
In this paper we give a detailed study of the global attractors for parabolic equations governed by the p-Laplacian in a heterogeneous medium. Not only the existence but also the infinite dimensionality of the global attractors is presented by showing that their ε-Kolmogorov entropy behaves as a polynomial of the variable 1/ε as ε tends to zero, which is not observed for non-degenerate parabolic equations. The upper and lower bounds for the Kolmogorov ε-entropy of infinite-dimensional attractors are also obtained. 相似文献
6.
7.
We propose and demonstrate an OCT optical probe using eccentric optics. This probe enabled both forward imaging and side imaging by dividing a circular scanning area into two semicircular scanning areas using an external motor to rotate the flexible tube. The outer diameter of the probe was 2.6 mm, and its rigid portion length was 10 mm. The lateral resolution was 23 μm, and the eccentric radius was 1.1 mm. The circumferential length in scanning was 6.9 mm, and the working distance was 5 mm. OCT images of 1.5 mm × 6.9 mm (in tissue, axial × circumference), including forward image and side image, were measured with the axial resolution of 19 μm in air and a frame rate of one frame per second. The epidermis, dermis, and sweat gland of in vivo human ventral finger tips were observed. 相似文献
8.
Abe T Matsumoto M Hashimoto S 《The Journal of the Acoustical Society of America》2007,122(5):2697-2705
A time-domain epsilon-filter (TD epsilon-filter) is a nonlinear filter that can reduce noise while preserving a signal that varies drastically, such as a speech signal. Although the filter design is simple, it can effectively reduce noise. It is applicable not only to stationary noise but also to nonstationary noise. It cannot, however, be applied when the amplitude of noise is relatively large. This paper introduces an advanced method for noise reduction that applies an epsilon-filter to complex spectra, namely a time-frequency epsilon-filter (TF epsilon-filter). This paper also introduces noise reduction combining a TD epsilon-filter and a TF epsilon-filter. An advanced method called a variable time-frequency epsilon-filter is also proposed. First, the algorithm of the TD epsilon-filter is explained to clarify the problem. Then, the algorithms of the proposed methods are explained. By utilizing an epsilon-filter in the frequency domain, the proposed method can reduce not only noise that has a relatively small amplitude but also noise that has a relatively large amplitude. Experimental results are also given to demonstrate the performance of the proposed methods in comparison to the results of some conventional methods. 相似文献
9.
Tetrabenzoperipentacene: Stable Five‐Electron Donating Ability and a Discrete Triple‐Layered β‐Graphite Form in the Solid State 下载免费PDF全文
Akinobu Matsumoto Dr. Mitsuharu Suzuki Dr. Daiki Kuzuhara Dr. Hironobu Hayashi Prof. Dr. Naoki Aratani Prof. Dr. Hiroko Yamada 《Angewandte Chemie (International ed. in English)》2015,54(28):8175-8178
An oxidative ring‐closure reaction of a tetranaphthylpyrene derivative led to the synthesis of a 56 all‐carbon conjugated tetrabenzoperipentacene. In the single‐crystal X‐ray structure, three molecules make a triple‐layered cluster by π‐stacking, wherein each layer rotates by 120°, and is thus considered a petit β‐graphite. As for the optical properties, the Stokes shift is extremely small (10 cm?1), thus indicating its remarkably rigid framework. The tetrabenzoperipentacene exhibits reversible five‐electron oxidation waves in cyclic voltammetry, and is regarded as a counterpart to the fullerene C60 in terms of stable multicharge‐storage nanocarbon materials. 相似文献
10.
Halim M Kennedy RD Suzuki M Khan SI Diaconescu PL Rubin Y 《Journal of the American Chemical Society》2011,133(17):6841-6851
Gold(I), silver(I), and copper(I) phosphine complexes of 6,9,12,15,18-pentaaryl[60]fullerides 1a and 1b, namely, [(4-MeC(6)H(4))(5)C(60)]Au(PPh(3)) (2a), [(4-t-BuC(6)H(4))(5)C(60)]Au(PPh(3)) (2b), [(4-MeC(6)H(4))(5)C(60)]Ag(PCy(3)) (3a), [(4-t-BuC(6)H(4))(5)C(60)]Ag(PPh(3)) (3b), [(4-t-BuC(6)H(4))(5)C(60)]Ag(PCy(3)) (3c), [(4-MeC(6)H(4))(5)C(60)]Cu(PPh(3)) (4a), and [(4-t-BuC(6)H(4))(5)C(60)]Cu(PPh(3)) (4b), have been synthesized and characterized spectroscopically. All complexes except for 3c were also characterized by single-crystal X-ray diffraction. Several coordination modes between the cyclopentadienyl ring embedded in the fullerene and the metal centers are observed, ranging from η(1) with a slight distortion toward η(3) in the case of gold(I), to η(2)/η(3) for silver(I), and η(5) for copper(I). Silver complexes 3a and 3b are rare examples of crystallographically characterized Ag(I) cyclopentadienyls whose preparation was possible thanks to the steric shielding provided by fullerides 1a and 1b, which stabilizes these complexes. Silver complexes 3a and 3b both display unexpected coordination of the cyclopentadienyl portion of the fulleride anion with Ag(I). DFT calculations on the model systems (H(5)C(60))M(PH(3)) and CpMPH(3) (M = Au, Ag, or Cu) were carried out to probe the geometries and electronic structures of these metal complexes. 相似文献