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1.
Mariia Svyntkivska Tomasz Makowski Ewa Piorkowska Marek Brzezinski Agata Herc Anna Kowalewska 《Molecules (Basel, Switzerland)》2021,26(5)
Electrospun nonwovens of poly(L-lactide) (PLLA) modified with multiwall carbon nanotubes (MWCNT) and linear ladder-like poly(silsesquioxane) with methoxycarbonyl side groups (LPSQ-COOMe) were obtained. MWCNT and LPSQ-COOMe were added to the polymer solution before the electrospinning. In addition, nonwovens of PLLA grafted to modified MWCNT were electrospun. All modified nonwovens exhibited higher tensile strength than the neat PLA nonwoven. The addition of 10 wt.% of LPSQ-COOMe and 0.1 wt.% of MWCNT to PLLA increased the tensile strength of the nonwovens 2.4 times, improving also the elongation at the maximum stress. 相似文献
2.
Prof. Piotr Bałczewski Dr. Emilia Kowalska Dr. Ewa Różycka-Sokołowska Dr. Joanna Skalik Dr. Krzysztof Owsianik Dr. Marek Koprowski Dr. Bernard Marciniak Dr. Dariusz Guziejewski Prof. Witold Ciesielski 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(62):14148-14161
The highly substituted mono-aryl/alkylthio-(hetero)acenes prepared in this study have been found to be thermally more stable (Tdecomp.=331–354 °C) than the known di-aryl/alkylthio-substituted acenes by an average of 25 °C. They are also much more photostable at 254 and 365 nm (in both argon and air) than the parent anthracene and other reported anthracenes. The most photostable aryl/alkylthio-anthracenes at 254 nm were found to be 60–70 (in air) and 130 (in argon) times more stable in solution than the unsubstituted anthracene, and much more stable than known EDG/EWG-substituted anthracenes (EDG=electron-donating group, EWG=electron-withdrawing group) with an extended aromatic core. Furthermore, the acenes showed significantly higher photostability at 365 nm in both air and argon. The anthracenes were obtained by the novel thio-Friedel–Crafts/Bradsher cyclization reaction of hitherto unknown [o-(1,3-dithian-2-yl)aryl](aryl)methyl thioethers. The developed approach provides a general access to mono-aryl/alkylthio-substituted (hetero)acene frameworks containing at least three fused (hetero)aromatic rings. The characteristic feature of this approach, which leads to highly substituted acenes, is that the substituents, unlike in other methods, may be introduced at an early stage of the synthesis. DFT and TD-DFT calculations confirmed the stabilizing role of the aryl/alkylthio substituent in the mono-aryl/alkylthio-substituted anthracenes, which are the most stable anthracenes prepared to date. Their high photostability is mainly due to the quenching of singlet oxygen by the acene and the quenching of the acene S1 state by molecular oxygen. 相似文献
3.
We discuss an error estimation procedure for the global error of collocation schemes applied to solve singular boundary value problems with a singularity of the first kind. This a posteriori estimate of the global error was proposed by Stetter in 1978 and is based on the idea of Defect Correction, originally due to Zadunaisky. Here, we present a new, carefully designed modification of this error estimate which not only results in less computational work but also appears to perform satisfactorily for singular problems. We give a full analytical justification for the asymptotical correctness of the error estimate when it is applied to a general nonlinear regular problem. For the singular case, we are presently only able to provide computational evidence for the full convergence order, the related analysis is still work in progress. This global estimate is the basis for a grid selection routine in which the grid is modified with the aim to equidistribute the global error. This procedure yields meshes suitable for an efficient numerical solution. Most importantly, we observe that the grid is refined in a way reflecting only the behavior of the solution and remains unaffected by the unsmooth direction field close to the singular point. 相似文献
4.
Lance Nielsen 《Acta Appl Math》2002,74(3):265-292
Stability properties of Feynman's operational calculus are addressed in the setting of exponential functions of noncommuting operators. Applications of some of the stability results are presented. In particular, the time-dependent perturbation theory of nonrelativistic quantum mechanics is presented in the setting of the operational calculus and application of the stability results of this paper to the perturbation theory are discussed. 相似文献
5.
We use the adiabatic hyperspheric expansion and the Faddeev decomposition of the wave function with only s-waves. We derive for a fixed hyperradius an integro-differential equation for the angular eigenvalue and wave function. The
correlations lower the interaction energy for N = 20 by about a factor of 5.
Received October 22, 2001; accepted for publication November 5, 2001 相似文献
6.
7.
Kristian Hougaard Frederik D. Nielsen 《Journal of Optical and Fiber Communications Reports》2004,1(1):63-83
In this paper we will present an overview of the use
of photonic crystal fibers as fiber amplifiers. We
will describe the basic concepts of optical
amplification, and how to do numerical modelling of
such components. We will then identify advantages
and disadvantages of amplifiers based on PCF
technology compared to conventional fibers, and then
go into greater detail on some of these specific
applications, such as low pump power amplifiers, and
high-power double-clad amplifiers and lasers. 相似文献
8.
Sajewicz Mieczysław Hauck Heinz-E. Drabik Gabriela Namysło Ewa Głód Bronisław Kowalska Teresa 《平面色谱法杂志一现代薄层色谱法》2006,19(4):278-281
JPC – Journal of Planar Chromatography – Modern TLC - We have previously described unexpected two-dimensionality in the thin-layer chromatographic separation of pairs of enantiomers of... 相似文献
9.
Malene Steen Nielsen Flagga Frank Antonsen 《International Journal of Theoretical Physics》2004,43(9):1917-1930
We show that stable causality is related to the vanishing of the top Stiefel–Whitney class of a space-time manifold M, and that if M is a stably causal space-time manifold, then it is the boundary of a five-dimensional space-time. We then propose a scheme for making it both a necessary and sufficient condition. 相似文献
10.
Ewa Stró?yna 《Journal of Differential Equations》2003,193(1):239-259
We solve completely the problem of classification of germs of complex planar vector fields with nilpotent singularity with respect to formal orbital equivalence. 相似文献