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Patel Chirag N. Kumar Sivakumar Prasanth Pandya Himanshu A. Rawal Rakesh M. 《Molecular diversity》2021,25(1):421-433
Molecular Diversity - The pandemic outbreak of the Corona viral infection has become a critical global health issue. Biophysical and structural evidence shows that spike protein possesses a high... 相似文献
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Heteroatom‐Guided,Palladium‐Catalyzed,Site‐Selective CH Arylation of 4H‐Chromenes: Diastereoselective Assembly of the Core Structure of Myristinin B through Dual CH Functionalization 下载免费PDF全文
Govind Goroba Pawar Virendra Kumar Tiwari Dr. Himanshu Sekhar Jena Dr. Manmohan Kapur 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(27):9905-9911
A highly site‐selective, heteroatom‐guided, palladium‐catalyzed direct arylation of 4H‐chromenes is reported. The C?H functionalization is driven not only by the substituents and structure of the substrate but also by the coupling partner being used. The diastereoselective assembly of the core structure of Myristinin B has been achieved by using a dual C?H functionalization strategy for regioselective direct arylation. 相似文献
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Tuning CO2 Uptake and Reversible Iodine Adsorption in Two Isoreticular MOFs through Ligand Functionalization 下载免费PDF全文
Srinivasulu Parshamoni Suresh Sanda Dr. Himanshu Sekhar Jena Prof. Dr. Sanjit Konar 《化学:亚洲杂志》2015,10(3):653-660
The synthesis and characterization of two isoreticular metal–organic frameworks (MOFs), {[Cd(bdc)(4‐bpmh)]}n?2 n(H2O) ( 1 ) and {[Cd(2‐NH2bdc)(4‐bpmh)]}n?2 n(H2O) ( 2 ) [bdc=benzene dicarboxylic acid; 2‐NH2bdc=2‐amino benzene dicarboxylic acid; 4‐bpmh=N,N‐bis‐pyridin‐4‐ylmethylene‐hydrazine], are reported. Both compounds possess similar two‐fold interpenetrated 3D frameworks bridged by dicarboxylates and a 4‐bpmh linker. The 2D Cd‐dicarboxylate layers are extended along the a‐axis to form distorted square grids which are further pillared by 4‐bpmh linkers to result in a 3D pillared‐bilayer interpenetrated framework. Gas adsorption studies demonstrate that the amino‐functionalized MOF 2 shows high selectivity for CO2 (8.4 wt % 273 K and 7.0 wt % 298 K) over CH4, and the uptake amounts are almost double that of non‐functional MOF 1 . Iodine (I2) adsorption studies reveal that amino‐functionalized MOF 2 exhibits a faster I2 adsorption rate and controlled delivery of I2 over the non‐functionalized homolog 1 . 相似文献
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Prof. Dr. Jie Shen Deepa R Zhongyan Li Hyeonji Oh Harekrushna Behera Dr. Himanshu Joshi Prof. Dr. Manish Kumar Prof. Dr. Aleksei Aksimentiev Prof. Dr. Huaqiang Zeng 《Angewandte Chemie (International ed. in English)》2023,62(39):e202305623
Unlike many other biologically relevant ions (Na+, K+, Ca2+, Cl−, etc) and protons, whose cellular concentrations are closely regulated by highly selective channel proteins, Li+ ion is unusual in that its concentration is well tolerated over many orders of magnitude and that no lithium-specific channel proteins have so far been identified. While one naturally evolved primary pathway for Li+ ions to traverse across the cell membrane is through sodium channels by competing with Na+ ions, highly sought-after artificial lithium-transporting channels remain a major challenge to develop. Here we show that sulfur-containing organic nanotubes derived from intramolecularly H-bonded helically folded aromatic foldamers of 3.6 Å in hollow cavity diameter could facilitate highly selective and efficient transmembrane transport of Li+ ions, with high transport selectivity factors of 15.3 and 19.9 over Na+ and K+ ions, respectively. 相似文献
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Soumava Biswas Himanshu Sekhar Jena Suresh Sanda Prof. Dr. Sanjit Konar 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(39):13793-13801
Three isostructural lanthanide‐based two‐ dimensional coordination polymers (CPs) {[Ln2(L)3(H2O)2]n ? 2n CH3OH) ? 2n H2O} (Ln=Gd3+ ( 1 ), Tb3+ ( 2 ), Dy3+ ( 3 ); H2L=cyclobutane‐1,1‐dicarboxylic acid) were synthesized by using a low molecular weight dicarboxylate ligand and characterized. Single‐crystal structure analysis showed that in complexes 1 – 3 lanthanide centers are connected by μ3‐bridging cyclobutanedicarboxylate ligands along the c axis to form a rod‐shaped infinite 1D coordination chain, which is further linked with nearby chains by μ4‐connected cyclobutanedicarboxylate ligands to form 2D CPs in the bc plane. Viewing the packing of the complexes down the b axis reveals that the lattice methanol molecules are located in the interlayer space between the adjacent 2D layers and form H‐bonds with lattice and coordinated water molecules to form 1D chains. Magnetic properties of complexes 1 – 3 were thoroughly investigated. Complex 1 exhibits dominant ferromagnetic interaction between two nearby gadolinium centers and also acts as a cryogenic magnetic refrigerant having a significant magnetic entropy change of ?ΔSm=32.8 J kg?1 K?1 for ΔH=7 T at 4 K (calculated from isothermal magnetization data). Complex 3 shows slow relaxation of magnetization below 10 K. Impedance analysis revealed that the complexes show humidity‐dependent proton conductivity (σ=1.5×10?5 S cm?1 for 1 , σ=2.07×10?4 S cm?1 for 2 , and σ=1.1×10?3 S cm?1 for 3 ) at elevated temperature (>75 °C). They retain the conductivity for up to 10 h at high temperature and high humidity. Furthermore, the proton conductivity results were correlated with the number of water molecules from the water‐vapor adsorption measurements. Water‐vapor adsorption studies showed hysteretic and two‐step water vapor adsorption (182000 μL g?1 for 1 , 184000 μL g?1 for 2 , and 1874000 μL g?1 for 3 ) in the experimental pressure range. Simulation of water‐vapor adsorption by the Monte Carlo method (for 1 ) confirmed the high density of adsorbed water molecules, preferentially in the interlayer space between the 2D layers. 相似文献
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Chandola H 《Linear algebra and its applications》2010,433(11-12):2147-2151
We obtain the lower bound on a variant of the common problem of dimensionality reduction. In this version, the dataset is projected on to a k dimensional subspace with the property that the first k-1 basis vectors are fixed, leaving a single degree of freedom in terms of basis vectors. 相似文献
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Cooperative relaying is considered as an effective technique to enlarge the coverage area and enhance the system capacity for the future wireless systems. In this paper, an infrastructure based multi-antenna cooperative relay network has been investigated. Closed form expressions of outage probability and average error rate have been derived, when the relay and the destination perform selection combining of the signals. The relay is assumed to operate in the adaptive decode and forward mode. The effect of number of antennas installed on the relay and their placement has also been studied. 相似文献