New Achievements in the Field of Intramolecular Phenolic Coupling Reactions,Using Hypervalent (III) Iodine Reagent: Synthesis of Galanthamine

Our investigations on the oxidative possibilities of the hypervalent iodine(III) reagent established that phenyliodine(III)bis(trifluoroacclate) (PIFA) can provide one-pot contiguous coupling-cyclization reaction giving a product with narwedine skeleton, when used in a phenolic coupling reaction of p'-bromonorbelladine derivatives. A suitably selected precursor gave up to 60% yield of the coupled product.     

A Factorization Theorem for Topological Abelian Groups

Using the nice properties of the w-divisible weight and the w-divisible groups, we prove a factorization theorem for compact abelian groups K; namely, K = K _tor  × K _d , where K _tor is a bounded torsion compact abelian group and K _d is a w-divisible compact abelian group. By Pontryagin duality this result is equivalent to the same factorization for discrete abelian groups proved in [9 Galindo , J. , Macario , S. ( 2011 ). Pseudocompact group topologies with no infinite compact subsets . J. Pure and Appl. Algebra 215 : 655 – 663 .[Crossref], [Web of Science ®] , [Google Scholar]].     

Quasi-convex sequences in the circle and the 3-adic integers

In this paper, we present families of quasi-convex sequences converging to zero in the circle group T, and the group J₃ of 3-adic integers. These sequences are determined by increasing sequences of integers. For an increasing sequence , put gn=an+1−an. We prove that

(a)

the set {0}∪{±³−(an+1)|n∈N} is quasi-convex in T if and only if a₀>0 and gn>1 for every n∈N;

(b)

the set {0}∪{±an³|n∈N} is quasi-convex in the group J₃ of 3-adic integers if and only if gn>1 for every n∈N.

Moreover, we solve an open problem from [D. Dikranjan, L. de Leo, Countably infinite quasi-convex sets in some locally compact abelian groups, Topology Appl. 157 (8) (2010) 1347-1356] providing a complete characterization of the sequences such that {0}∪{±²−(an+1)|n∈N} is quasi-convex in T. Using this result, we also obtain a characterization of the sequences such that the set {0}∪{±²−(an+1)|n∈N} is quasi-convex in R.     

CLP-compactness for topological spaces and groups

We study CLP-compact spaces (every cover consisting of clopen sets has a finite subcover) and CLP-compact topological groups. In particular, we extend a theorem on CLP-compactness of products from [J. Steprāns, A. Šostak, Restricted compactness properties and their preservation under products, Topology Appl. 101 (3) (2000) 213-229] and we offer various criteria for CLP-compactness for spaces and topological groups, that work particularly well for precompact groups. This allows us to show that arbitrary products of CLP-compact pseudocompact groups are CLP-compact. For every natural n we construct:

(i)

a totally disconnected, n-dimensional, pseudocompact CLP-compact group; and

(ii)

a hereditarily disconnected, n-dimensional, totally minimal, CLP-compact group that can be chosen to be either separable metrizable or pseudocompact (a Hausdorff group G is totally minimal when all continuous surjective homomorphisms G→H, with a Hausdorff group H, are open).

     

Essential subgroups of topological groups

We study the class Wof Hausdorff topological groups Gfor which the following two cardinal invariants coincide

ES(G)=min{|H|:H≤ Gdense and essential}

TD(G)=min{|H|:H≤ Gtotally dense}

We prove that W contains the following classes:locally compact abelian groups, compact connected groups, countably compact totally discon¬nected abelian groups, topologically simple groups, locally compact Abelian groups when endowed with their Bohr topology, totally minimal abelian groups and free Abelian topological groups. For all these classes we are also able to giv ean explicit computation of the common value of ESand TD.     

Updating Insights into the Catalytic Domain Properties of Plant Cellulose synthase (CesA) and Cellulose synthase-like (Csl) Proteins

The wall is the last frontier of a plant cell involved in modulating growth, development and defense against biotic stresses. Cellulose and additional polysaccharides of plant cell walls are the most abundant biopolymers on earth, having increased in economic value and thereby attracted significant interest in biotechnology. Cellulose biosynthesis constitutes a highly complicated process relying on the formation of cellulose synthase complexes. Cellulose synthase (CesA) and Cellulose synthase-like (Csl) genes encode enzymes that synthesize cellulose and most hemicellulosic polysaccharides. Arabidopsis and rice are invaluable genetic models and reliable representatives of land plants to comprehend cell wall synthesis. During the past two decades, enormous research progress has been made to understand the mechanisms of cellulose synthesis and construction of the plant cell wall. A plethora of cesa and csl mutants have been characterized, providing functional insights into individual protein isoforms. Recent structural studies have uncovered the mode of CesA assembly and the dynamics of cellulose production. Genetics and structural biology have generated new knowledge and have accelerated the pace of discovery in this field, ultimately opening perspectives towards cellulose synthesis manipulation. This review provides an overview of the major breakthroughs gathering previous and recent genetic and structural advancements, focusing on the function of CesA and Csl catalytic domain in plants.     

Relative minimality and co-minimality of subgroups in topological groups

We study two properties of subgroups of a topological group (relative minimality and co-minimality), that generalize minimality. Many applications, mostly related to semidirect products and generalized Heisenberg groups are given.     

Quasi‐convexly dense and suitable sets in the arc component of a compact group

Let G be an abelian topological group. The symbol $\widehat{G}Let G be an abelian topological group. The symbol $\widehat{G}$ denotes the group of all continuous characters $\chi :G\rightarrow {\mathbb T}$ endowed with the compact open topology. A subset E of G is said to be qc‐dense in G provided that χ(E)?φ([? 1/4, 1/4]) holds only for the trivial character $\chi \in \widehat{G}$, where $\varphi : {\mathbb R}\rightarrow {\mathbb T}={\mathbb R}/{\mathbb Z}$ is the canonical homomorphism. A super‐sequence is a non‐empty compact Hausdorff space S with at most one non‐isolated point (to which S converges). We prove that an infinite compact abelian group G is connected if and only if its arc component G_a contains a super‐sequence converging to 0 that is qc‐dense in G. This gives as a corollary a recent theorem of Außenhofer: For a connected locally compact abelian group G, the restriction homomorphism $r:\widehat{G}\rightarrow \widehat{G}_a$ defined by $r(\chi )=\chi \upharpoonright _{G_a}$ for $\chi \in \widehat{G}$, is a topological isomorphism. We show that an infinite compact group G is connected if and only if its arc component G_a contains a super‐sequence converging to the identity that is qc‐dense in G and generates a dense subgroup of G. We also offer a short alternative proof of the result of Hofmann and Morris on the existence of suitable sets of minimal size in the arc component of a compact connected group.     

Characterizing sequences for precompact group topologies

Motivated from [31], call a precompact group topology τ on an abelian group G ss-precompact (abbreviated from single sequence precompact  ) if there is a sequence u=(_un)$\mathbf{u}=(u_n)$ in G such that τ is the finest precompact group topology on G   making u=(_un)$\mathbf{u}=(u_n)$ converge to zero. It is proved that a metrizable precompact abelian group (G,τ)$(G,\tau )$ is ss-precompact iff it is countable. For every metrizable precompact group topology τ on a countably infinite abelian group G there exists a group topology η such that η is strictly finer than τ   and the groups (G,τ)$(G,\tau )$ and (G,η)$(G,\eta )$ have the same Pontryagin dual groups (in other words, (G,τ)$(G,\tau )$ is not a Mackey group in the class of maximally almost periodic groups).