Biomass-derived dibasic acids to diesters with inorganic ligand-supported catalyst: synthesis,optimization, characterization

Research on Chemical Intermediates - Several attempts have been made to obtain aliphatic dicarboxylic diesters from esterification reaction to develop the biomass-derived platform molecules and...     

水平圆管中受压扭作用管桩屈曲后的解析解

首先建立了考虑自重、受水平圆管约束的管柱在压担组合作用下的屈曲方程：此方程为四阶强非线性常微分方程，难以直接精确求解；通过管柱的正弦屈由分析，找到了方程中的小参数；利用小参数摄动法求解了强非线性屈曲方程，得到了管柱螺旋屈曲后的实际屈曲构形解析解，由此可进一步得到管柱发生螺旋屈曲的临界载荷；所得解析结果与数值计算结果及本文结果退化后与文献中的相关结果比较都有良好的一致性．     

井眼轨迹控制力学模型

对石油钻井中井眼轨迹控制问题进行了力学分析，给出了底部钻具组合三维受力和变形的控制方程，建立了钻头与正交各向异性地层相互作用模型，阐明了井眼轨迹预测和控制计算方法。     

Different classification algorithms and serum surface enhanced Raman spectroscopy for noninvasive discrimination of gastric diseases

In this study, surface enhanced Raman spectroscopy (SERS) was used to investigate the spectral characteristics of blood serum for the purpose of diagnosing stomach diseases. SERS spectral data was collected from patients with atrophic gastritis, both pre‐operation and post‐operation gastric cancer, and from healthy individuals. Visual differences in the SERS spectra were observed between the four groups which indicate corresponding biomolecule concentration changes in blood. To further investigate the diagnostic ability of human serum, the spectral data was analyzed with three chemometric processes. These three methods extracted features and classified from the spectral data. Principal component analysis (PCA) was first performed to reduce the dimensionality of the original spectral data. Then, the classification methods support vector machine (SVM), linear discriminant analysis (LDA) and classification and regression tree (CART) were used for the evaluation of diagnostic ability. Accuracies of 96.5%, 88.8% and 87.1% were obtained for PCA‐SVM, PCA‐LDA and PCA‐CART, respectively. Copyright © 2016 John Wiley & Sons, Ltd.     

广义F积分的表示(Ⅰ)

与Ｓｕｇｅｎｏ的Ｆ积分表示理论相比较，本文探讨了广义Ｆ积份的表示问题，给出了几个表示定理，如中值定理，重排转化定理等。