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排序方式: 共有190条查询结果,搜索用时 31 毫秒
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Vardanyan S. O. Avagyan A. S. Aghekyan A. A. Sargsyan A. B. Harutyunyan S. A. Gasparyan H. V. 《Russian Journal of Organic Chemistry》2020,56(3):436-439
Russian Journal of Organic Chemistry - The title compound was synthesized by reaction of 1,4-benzodioxane-2-carbohydrazide with phenyl isothiocyanate, followed by cyclization of the... 相似文献
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Kirill Kulish Cosimo Boldrini Dr. Marta Castiñeira Reis Dr. Juana M. Pérez Prof. Dr. Syuzanna R. Harutyunyan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(68):15843-15846
Two-step dearomative functionalization of naphthols promoted by Lewis acids and copper(I) catalysis was developed. Initially, Lewis acid complexation inverted the electronic properties of the ring and established an equilibrium with the dearomatized counterpart. Subsequent trapping of the dearomatized intermediate with organometallics as well as organophosphines was demonstrated and provided the corresponding dearomatized products. 相似文献
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Siriphong Somprasong Dr. Marta Castiñeira Reis Prof. Dr. Syuzanna R. Harutyunyan 《Angewandte Chemie (International ed. in English)》2023,62(9):e202217328
Nitrogen-bearing rings are common features in the molecular structures of modern drugs, with chiral δ-lactams being an important subclass due to their known pharmacological properties. Catalytic dearomatization of preactivated pyridinium ion derivatives emerged as a powerful method for the rapid construction of chiral N-heterocycles. However, direct catalytic dearomatization of simple pyridine derivatives are scarce and methodologies yielding chiral δ-lactams are yet to be developed. Herein, we describe an enantioselective C4-dearomatization of methoxypyridine derivatives for the preparation of functionalised enantioenriched δ-lactams using chiral copper catalysis. Experimental 13C kinetic isotope effects and density functional theory calculations shed light on the reaction mechanism and the origin of enantioselectivity. 相似文献
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Karine A. Eliazyan Aram M. Knyazyan Vergush A. Pivazyan Emma A. Ghazaryan Siranush V. Harutyunyan Aleksandr P. Yengoyan 《Journal of heterocyclic chemistry》2013,50(5):1083-1088
By interaction of N‐methyl(ethyl)‐dithiocarbamate sodium salt with 3‐chloro‐pentane‐2,4‐dion the 1‐(3‐alkyl‐4‐methyl‐2‐thioxo‐2,3‐dihydro‐thiazol‐5‐yl)‐ethanones 1 , 2 and corresponding oximes 7 , 8 were synthesized. On the basis of the mentioned compounds hydrazono ( 3 , 4 ), ureayl and thioureayl ( 5 , 6 ) derivatives, substituted oximes ( 9 , 10 ) and azinyl oximes ( 11 , 12 ) were obtained. The structures of synthesized compounds were confirmed by proton nuclear magnetic resonance spectroscopy and elemental analysis. The pesticidal activities of synthesized compounds were studied. Some of the synthesized compounds simultaneously have shown growth stimulant and fungicidal activity. 相似文献
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Several modem methods of nanowires fabrication and their characterization are presented and discussed. Electronic and thermal transport measurement techniques ofnanowire arrays as well as of an individual nanowire in the wide temperature range are presented. 相似文献
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