全文获取类型
收费全文 | 149篇 |
免费 | 5篇 |
专业分类
化学 | 113篇 |
晶体学 | 3篇 |
力学 | 2篇 |
数学 | 11篇 |
物理学 | 25篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2020年 | 5篇 |
2019年 | 2篇 |
2017年 | 1篇 |
2016年 | 2篇 |
2015年 | 7篇 |
2014年 | 2篇 |
2013年 | 12篇 |
2012年 | 8篇 |
2011年 | 7篇 |
2010年 | 5篇 |
2009年 | 4篇 |
2008年 | 6篇 |
2007年 | 5篇 |
2006年 | 1篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 5篇 |
2002年 | 6篇 |
2001年 | 3篇 |
2000年 | 7篇 |
1999年 | 2篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 7篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 4篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1975年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有154条查询结果,搜索用时 203 毫秒
1.
Criado Francisco Joswig Michael Santos Francisco 《Foundations of Computational Mathematics》2022,22(6):1923-1960
Foundations of Computational Mathematics - In this paper we initiate the study of tropical Voronoi diagrams. We start out with investigating bisectors of finitely many points with respect to... 相似文献
2.
3.
4.
Pedro E. Sánchez-Jiménez Luis A. Pérez-MaquedaAntonio Perejón José M. Criado 《Polymer Degradation and Stability》2011,96(5):974-981
This paper explores the relationship between the shapes of temperature-time curves obtained from experimental data recorded by means of constant rate thermal analysis (CRTA) and the kinetic model followed by the thermal degradation reaction. A detailed shape analysis of CRTA curves has been performed as a function of the most common kinetic models. The analysis has been validated with simulated data, and with experimental data recorded from the thermal degradation of polytetrafluoroethylene (PTFE), poly(1,4-butylene terephthalate) (PBT), polyethylene (PE) and poly(vinyl chloride) (PVC). The resulting temperature-time profiles indicate that the studied polymers decompose through phase boundary, random scission, diffusion and nucleation mechanisms respectively. The results here presented demonstrate that the strong dependence of the temperature-time profile on the reaction mechanism would allow the real kinetic model obeyed by a reaction to be discerned from a single CRTA curve. 相似文献
5.
In this paper we show that there is a complete parallelism between the Foucault pendulum and the Thomas rotation phenomena by using the concept of parallel transport in a surface. In the case of the Foucault pendulum the surface is the ordinary sphere corresponding to the Earth sphere, whereas in the case of the Thomas rotation the surface is the pseudosphere corresponding to the space of relativistic velocities. Moreover, in both cases we use a simple method that reduces the problem to the parallel transport in a conical surface, and so, to the plane. 相似文献
6.
P. Budrugeac J. M. Criado F. J. Gotor J. Malek L. A. Prez‐Maqueda E. Segal 《国际化学动力学杂志》2004,36(6):309-315
The isoconversional method suggested by Friedman and the invariant kinetic parameters method (IKP) were used in order to examine the kinetics of the nonisothermal crystallization of (GeS2)0.3(Sb2S3)0.7. The objective of the paper is to show the usefulness of the IKP method both for determining the activation parameters as well as the model of the investigated process. It was shown that the kinetic triplet [(E, A, f(α), where E is the activation energy, A is the preexponential factor, and f(α) is the differential function of conversion], which results through the application of the IKP method, depends on the set of kinetic models considered. For different sets of kinetic models, proportional values of f(α) are obtained. A criterion for the selection of this set, the use of which lead to the true kinetic triplet corresponding to the analyzed process (E = 163.2 kJ mol?1; A = 2.47 × 1012 min?1 and the Avrami‐Erofeev model, Am, for m = 2.5–2.6 was suggested. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 309–315, 2004 相似文献
7.
This paper deals with two types of non-local problems for the Poisson equation in the disc. The first of them deals with the situation when the function value on the circle is given as a combination of unknown function values in the disc. The other type deals with the situation when a combination of the value of the function and its derivative by radius on the circle are given as a combination of unknown function values in the disc. The existence and uniqueness of the classical solution of these problems is proved. The solutions are constructed in an explicit form. 相似文献
8.
J. M. Criado L. A. Pérez-Maqueda M. J. Diánez P. E. Sánchez-Jiménez 《Journal of Thermal Analysis and Calorimetry》2007,87(1):297-300
The SCTA method implies to control the temperature in such a way that
the reaction rate changes with the time according to a function previously
defined by the user. Constant Rate Thermal Analysis (CRTA) is one of the most
commonly used SCTA methods and implies achieving a temperature profile at
which the reaction rate remains constant all over the process at a value previously
selected by the user. This method permits to minimize the influence of heat
and mass transfer phenomena on the forward reaction. The scope of this work
is to develop a universal CRTA temperature controller that could be adapted
to any thermoanalytical device. The thermoanalytical signal is programmed
to follow a preset linear trend by means of a conventional controller that
at the time controls a second conventional temperature programmer that forces
the temperature to change for achieving the trend programmed for the thermoanalytical
signal. Examples of the performance of this control system with a Thermobalance
and a Thermomechanical Analyser (TMA) are given. 相似文献
9.
J.M. Criado 《Thermochimica Acta》1978,24(1):186-189
10.
Susana Criado Arnaldo T. Soltermann Juan M. Marioli Norman A. Garcia 《Photochemistry and photobiology》1998,68(4):453-458
This paper studies the dye-sensitized photooxidation of tyrosine (tyr) and tyr di- and tripeptides (tyr-tyr and tyr-tyr-tyr) mediated by singlet molecular oxygen (O,[l]) in alkaline media. Photooxidation quantum efficiencies (φr) were obtained by determining the overall and reactive rate constants of interaction with the oxidative species, employing the time-resolved O,(l) phosphorescence detection method and static-photolysis actinometric method, respectively. The interaction of O,(l)-tyr derivatives occurs through an intermediate encounter complex with polar character. Ionization of the phenolic OH group of tyr derivatives and the polarity of the solvent favors the overall interaction. Nevertheless, & values decrease when changing from water to MeCN-water medium. This indicates that the reactive deactivation of the encounter complex, probably an entropy-controlled step, may be affected by solvent polarity in the same way as those processes in which charg- es are neutralized along the reaction pathway. Photooxidation quantum efficiencies indicate that the contribution to O,(′) physical quenching (a second alternative deactivation route for the encountered complex [O,(′)-tyr derivatives]) increases with the complexity of the peptide. As a result, the selfprotection of the peptidic entity against physical quenching also increases. The information obtained from the fractional consumption mol OJmol tyr derivative (in tyr, the di- and tripeptides and the respective methyl ester of tyr and the tripeptide), together with the evolution (either consumption and/or generation) of primary amino groups upon photosensitized irradiation of the same compounds clearly indicates that the photooxidation of di- and tri-tyr peptides proceeds with the breakage of peptidic bonds. As a consequence, in the final balance each tyr unity behaves as an independent photooxidizable target. 相似文献