Asymptotic Behavior of the Solutions of a Functional-Differential Equation with Linearly Transformed Argument

Ukrainian Mathematical Journal - We establish new properties of the solutions of a functional-differential equation with linearly transformed argument.     

The First One‐Pot Synthesis of Metal–Organic Frameworks Functionalised with Two Transition‐Metal Complexes

The synthesis of a metal–organic framework (UiO‐67) functionalised simultaneously with two different transition metal complexes (Ir and Pd or Rh) through a one‐pot procedure is reported for the first time. This has been achieved by an iterative modification of the synthesis parameters combined with characterisation of the resulting materials using different techniques, including X‐ray absorption spectroscopy (XAS). The method also allows the first synthesis of UiO‐67 with a very wide range of loadings (from 4 to 43 mol %) of an iridium complex ([IrCp*(bpydc)(Cl)Cl]^2?; bpydc=2,2′‐bipyridine‐5,5′‐dicarboxylate, Cp*=pentamethylcyclopentadienyl) through a pre‐functionalisation methodology.     

Photoswitching the Cytotoxic Properties of Platinum(II) Compounds

The photoactivation of potential anticancer metal complexes is a hot topic of current research as it may lead to the development of more selective drugs. Photoactivated chemotherapy (PACT) with coordination compounds is usually based on a (photo)chemical reaction taking place at the metal center. Herein, a new strategy is exploited that consists of “photomodifying” a ligand coordinated to metal ions. Platinum(II) complexes from photoswitchable 1,2‐dithienylethene‐containing ligands have been prepared, which exhibit two interconvertible photoisomeric forms that present distinct DNA‐interacting properties and cytotoxic behaviors.     

Anisotropic parameter identification using inhomogeneous tensile test

In this contribution, an inverse identification strategy of constitutive laws for elastoplastic behaviour is presented. The proposed inverse algorithm is composed on an appropriate finite element calculation combined with an optimisation procedure. It is applied to identify material anisotropic coefficients using a set up of easy performed laboratory tests. The used experimental data are the plane tensile test and the off axes tensile tests. The identified behaviour models are mainly based on Hill's quadratic yield criterion. Two cases of this yield criterion have been considered: the transverse isotropic and the orthotropic one under an associated and non-associated flow rule assumptions for each case. The yield surface has been assumed to expand isotropically (isotropic strain hardening law) as a function of the plastic work.In order to better describe anisotropic plastic properties of the studied materials, a recently planar anisotropic yield function is used. It is a non-quadratic yield criterion which takes account of anisotropic yield stresses as well as anisotropic strain ratios. It is subsequently shown that the agreement between inverse identification results and experimental measurements were improved.We prove also that the presented strategy is a good alternative to the simplified homogeneous tests assumption, especially for the plane tensile test.     

On asymptotic properties of solutions of linear differential functional equations with linearly transformed argument

We establish new properties of C ¹[−1, +∞)-solutions of the linear functional differential equation ẋ(t) = ax(t) + bx(qt) + hx(t−1) + cẋ(qt) + rẋ(t−1) in the neighborhood of the singular point t = +∞. __________ Translated from Neliniini Kolyvannya, Vol. 9, No. 2, pp. 170–177, April–June, 2006.     

Structural Analysis of Defects in Layered Double Hydroxides and Related Mixed Oxides

Russian Journal of General Chemistry - Results of studying the structural defects in MgAl and NiAl layered double hydroxides and in the products of their thermal decomposition to 1000°C,...     

Synthesis of lupane triterpenoids with triphenylphosphonium substituents and studies of their antitumor activity

New derivatives of lupane triterpenoids, viz., 20,29-dihydrobetulinic and 3-epi-20,29-dihydrobetulinic acid derivatives containing triphenylphosphonium fragments as substituents were synthesized. These compound considerably exceed betulinic acid in antitumor activity.