The First One‐Pot Synthesis of Metal–Organic Frameworks Functionalised with Two Transition‐Metal Complexes |
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| Authors: | Dr Ana E Platero‐Prats Dr Antonio Bermejo?Gómez Dr Louise Samain Prof Xiaodong Zou Prof Belén Martín‐Matute |
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| Affiliation: | 1. Berzelii Center EXSELENT on Porous Materials, Stockholm University, 10691 Stockholm (Sweden);2. Department of Organic Chemistry, Stockholm University, 10691 Stockholm (Sweden);3. Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden) |
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| Abstract: | The synthesis of a metal–organic framework (UiO‐67) functionalised simultaneously with two different transition metal complexes (Ir and Pd or Rh) through a one‐pot procedure is reported for the first time. This has been achieved by an iterative modification of the synthesis parameters combined with characterisation of the resulting materials using different techniques, including X‐ray absorption spectroscopy (XAS). The method also allows the first synthesis of UiO‐67 with a very wide range of loadings (from 4 to 43 mol %) of an iridium complex (IrCp*(bpydc)(Cl)Cl]2?; bpydc=2,2′‐bipyridine‐5,5′‐dicarboxylate, Cp*=pentamethylcyclopentadienyl) through a pre‐functionalisation methodology. |
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| Keywords: | functionalisation metal– organic frameworks microporous materials synthesis design transition metal complexes |
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