Adamantyl Side Chains as Anti-Aggregating Moieties in Dyes for Dye-Sensitized Solar Cells

Designing and evaluating novel dye concepts is crucial for the development of the field of dye-sensitized solar cells (DSSCs). In our recent report, the novel concept of tethering the anti-aggregation additive chenodeoxycholic acid (CDCA) to dyes for DSSC was introduced. Based on the performance improvements seen for this modification, the aim of this study is to see if a simplified anti-aggregation unit could achieve similar results. The following study reports the synthesis and photovoltaic characterization of two novel dyes decorated with the steric ethyladamantyl moiety on the π-spacer, and on the triarylamine donor. This modification is demonstrated to be successful in increasing the photovoltages in devices employing copper-based electrolytes compared to the non-modified reference dye. The best photovoltaic performance is achieved by a device prepared with the adamantyl decorated donor dye and CDCA, this device achieves a power conversion efficiency of 6.1 % (Short-circuit current=8.3 mA cm⁻², Open-circuit voltage=1054 mV, Fill factor=0.69). The improved photovoltaic performance seen for the adamantyl decorated donor demonstrate the potential of ethyladamantyl side chains as a tool to ensure surface protection of TiO₂.     

The geometric and numerical properties of duality in projective algebraic geometry

In this paper we investigate some fundamental geometric and numerical properties ofduality for projective varieties inP _k ^N =P ^N . We take a point of view which in our opinion is somewhat moregeometric and lessalgebraic andnumerical than what has been customary in the literature, and find that this can some times yield simpler and more natural proofs, as well as yield additional insight into the situation. We first recall the standard definitions of thedual variety and theconormal scheme, introducing classical numerical invariants associated with duality. In section 2 we recall the well known duality properties these invariants have, and which was noted first byT. Urabe. In section 3 we investigate the connection between these invariants andChern classes in the singular case. In section 4 we give a treatment of the dual variety of a hyperplane section of X, and the dual procedure of taking the dual of a projection of X. This simplifies the proofs of some very interesting theorems due toR. Piene. Section 5 contains a new and simpler proof of a theorem ofA. Hefez and S. L. Kleiman. Section 6 contains some further results, geometric in nature.     

Codimension 2 subvarieties of projective space

The motivation for the present paper is theHartshorne Conjecture on complete intersections inP ⁿ , forn6, and in the codimension 2 case: Any smooth codimension 2 subvarietyX ofP ⁿ is conjectured to be a complete intersection forn6. We prove this conjecture for all varieties with degree below a certain bound, which represents an improvement of the numerical information available untill now.This research has been supported by a grant from theStefi andLars Fylkesaker Foundation     

Single crystals of L-O-serine phosphate X-irradiated at low temperatures: EPR, ENDOR, EIE, and DFT studies

Single crystals of the phosphorylated amino acid L-O-serine phosphate were X-irradiated and studied at 10 K and at 77 K using EPR, ENDOR, and EIE techniques. Two radicals, R1(10 K) and R1(77 K), were detected and characterized as two different geometrical conformations of the protonated reduction product >CH-C(OH)(2). R1(10 K) is only observed after irradiation at 10 K, and upon heating to 40 K, R1(10 K) transforms rapidly and irreversibly into R1(77 K). The transition from R1(10 K) to R1(77 K) strongly increases the isotropic hyperfine coupling of the C-CH(beta) coupling (Delta = 32 MHz) and the major C-OH(beta) coupling (Delta = 47 MHz), in sharp contrast to the their much reduced anisotropic hyperfine couplings after the transition. An umbrella-like inversion of the carboxylic acid center, accompanied by minor geometrical adjustments, explains the changes of these observed isotropic and anisotropic couplings. DFT calculations were done on the reduced and protonated L-O-serine phosphate radical at the B3LYP/6-311+G(2df,p)//B3LYP/6-31+G(d) level of theory in order to support the experimental observations. Two different conformations of the anion radical, related by an inversion at the carboxylic center, could be found within the single molecule partial energy-optimization scheme. These two conformations reproduce the experimental hyperfine couplings from radicals R1(10 K) and R1(77 K). A third radical, radical R2, was observed experimentally at both 10 and 77 K and was shown to be due to the decarboxylated L-O-serine phosphate oxidation product, a conclusion fully supported from the DFT calculations. Upon thermal annealing from 77 to 295 K, radicals R1(77 K) and R2 disappeared and all three previously observed room-temperature radicals could be observed. No phosphate-centered radicals could be observed at any temperatures, indicating that the phosphate-ester bond break for one of the room-temperature radicals does not occur by dissociative electron capture at the phosphate group.     

Use of the equivalent attribute technique in multi-criteria planning of local energy systems

This paper discusses how the equivalent attribute technique (EAT) can be used to improve the comprehensibility of a multi-attribute utility theory study. When using EAT, ‘vague’ expected total utility values are converted into equivalent values for one of the attributes being considered, often an economic attribute. Two models are considered: a simplified linear model, and a more advanced non-linear model that includes the DM’s strength-of-preference and risk attitude. EAT is particularly useful in distinguishing between alternatives with similar utility values. When the difference between utility values is larger, the choice among the alternatives should be clear, and EAT therefore becomes less useful. The technique can still be used, although extra care is needed when choosing the equivalent attribute. A local energy-planning problem is used as a case study to illustrate and exemplify the EAT approach.     

Amphiphilic Lipopeptide Microparticles as Contrast Agents for Medical Ultrasound Imaging

In this study we investigated the utility of complementary amphiphilic lipopeptides as a new membrane formulation suitable for the preparation of gas‐filled microbubbles. Through primarily ion pairing and hydrophobic interactions we rationalized that the stacking of synthetic lipopeptides into the surface of microbubbles would make bubble suspensions useful as ultrasound contrast agents. By mixing charged lipopeptides in propylene glycol/glycerol solutions in the presence of a perfluorocarbon gas followed by vigorous shaking, microbubble suspensions were formed in good yield with a size distribution spanning the range 1–7 × 10^?6 m. The microbubbles were studied in an in vivo model and provided imaging efficacy comparable with conventional ultrasound contrast agents.

Crude sample (before flotation) of Formulation A analyzed at ×40 magnification. The solid bar indicates 10 × 10^?6 m.     

On the construction of hourly price forward curves for electricity prices

Computational Management Science - There are several approaches in the literature for the derivation of price forward curves (PFCs) which distinguish among each other by the procedure employed for...