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1.
Gunawan Gunawan Tito Viswanathan Shawn Bourdo Alexandru S. Biris 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):768-777
Abstract A novel, fast, and easy method for synthesizing a carbon-supported Ni2P nanocomposite (C/Ni2P) is described. The process involves a reaction between a nickel salt, phosphoric acid, and a carbon source by utilizing microwave irradiation. The carbon source for the nanocomposite is from renewable supplies, namely, tannin and lignin. The method has successfully synthesized Ni2P nanoparticles dispersed in a carbon matrix with a particle size ranging from 20 to 50 nm in diameter. During the microwave process, tannin and lignin provided a reducing environment in the microwave irradiation process. The synthesized products are characterized by several characterization methods. The method showed that phosphoric acid, which is a nontoxic compound, could be used as an alternative P source for synthesizing Ni2P. The method is fast, easy, and an economical process to synthesize the carbon-coated Ni2P nanocomposite. 相似文献
2.
Enhancement of Solar Hydrogen Evolution from Water by Surface Modification with CdS and TiO2 on Porous CuInS2 Photocathodes Prepared by an Electrodeposition–Sulfurization Method 下载免费PDF全文
Dr. Jiao Zhao Dr. Tsutomu Minegishi Li Zhang Dr. Miao Zhong Gunawan Dr. Mamiko Nakabayashi Dr. Guijun Ma Dr. Takashi Hisatomi Dr. Masao Katayama Prof. Dr. Shigeru Ikeda Prof. Dr. Naoya Shibata Prof. Dr. Taro Yamada Prof. Dr. Kazunari Domen 《Angewandte Chemie (International ed. in English)》2014,53(44):11808-11812
Porous films of p‐type CuInS2, prepared by sulfurization of electrodeposited metals, are surface‐modified with thin layers of CdS and TiO2. This specific porous electrode evolved H2 from photoelectrochemical water reduction under simulated sunlight. Modification with thin n‐type CdS and TiO2 layers significantly increased the cathodic photocurrent and onset potential through the formation of a p–n junction on the surface. The modified photocathodes showed a relatively high efficiency and stable H2 production under the present reaction conditions. 相似文献
3.
The following article describes a concise synthesis of a collection of 4,5-dihydro-1H-benzo[e][1,4]diazepines fused to a hydantoin ring. Molecular complexity and biological relevance are high and structures are generated in a mere three steps, employing the Ugi reaction to assemble diversity reagents. The protocol represents a novel UDC (Ugi-deprotect-cyclize) strategy employed in the Ugi-5-component CO2-mediated condensation, followed by further cyclization under basic conditions, to afford the fused hydantoin. Mechanistic caveats, dependent on the aldehydes of choice will be revealed and a facile oxidation of the final products to imidazolidenetriones is briefly discussed. 相似文献
4.
JPC – Journal of Planar Chromatography – Modern TLC - A simple and rapid TLC-densitometric method has been developed for simultaneously determination of hydrocortisone acetate and... 相似文献
5.
Multistage Interconnection Networks (MINs) are network systems providing fast and efficient communications at a reasonable cost. A gamma network is a specific class of MINs, which provides redundant paths in the system. In a gamma network, information from source nodes is transmitted through a specific set of routes to destination nodes. Reliability of an MIN is used as a measure of system’s ability to transform information from input to output devices. Due to the complexity of network configuration and availability of redundant paths, reliability bounds to estimate the exact reliability of a gamma network is proposed. A numerical example of an 8 × 8 gamma network is presented to demonstrate the accuracy of the reliability bounds. When the lower bound reliability provides sufficient assurance that the system will be operational at some specified time and closely approximates the exact reliability, then no further effort for obtaining the exact reliability expression is necessary. 相似文献
6.
JPC – Journal of Planar Chromatography – Modern TLC - A simple and rapid densitometric method has been developed for determination of taurine and lysine in ‘energy drinks’... 相似文献
7.
It is well known that the spectral envelope is a perceptually salient attribute in musical instrument timbre perception. While a number of studies have explored discrimination thresholds for changes to the spectral envelope, the question of how sensitivity varies as a function of center frequency and bandwidth for musical instruments has yet to be addressed. In this paper a two-alternative forced-choice experiment was conducted to observe perceptual sensitivity to modifications made on trumpet, clarinet and viola sounds. The experiment involved attenuating 14 frequency bands for each instrument in order to determine discrimination thresholds as a function of center frequency and bandwidth. The results indicate that perceptual sensitivity is governed by the first few harmonics and sensitivity does not improve when extending the bandwidth any higher. However, sensitivity was found to decrease if changes were made only to the higher frequencies and continued to decrease as the distorted bandwidth was widened. The results are analyzed and discussed with respect to two other spectral envelope discrimination studies in the literature as well as what is predicted from a psychoacoustic model. 相似文献
8.
Dienone—phenol rearrangement in (CD3CO)2O/BF3 of 1-acetoxy cyclohexadienones derived from benzene yields mainly monoacetoxy monotrideuteroacetoxy derivatives of benzene. The implications of these results on the reaction mechanism are discussed. 相似文献
9.
Gunawan O Gokmen T Shkolnikov YP De Poortere EP Shayegan M 《Physical review letters》2008,100(3):036602
An AlAs two-dimensional electron system patterned with an antidot lattice exhibits a giant piezoresistance effect at low temperatures, with a sign opposite to the piezoresistance observed in the unpatterned region. We suggest that the origin of this anomalous giant piezoresistance is the nonuniform strain in the antidot lattice and the exclusion of electrons occupying the two conduction-band valleys from different regions of the sample. This is analogous to the well-known giant magnetoresistance effect, with valley playing the role of spin and strain the role of magnetic field. 相似文献
10.
Gunawan O Shkolnikov YP Vakili K Gokmen T De Poortere EP Shayegan M 《Physical review letters》2006,97(18):186404
We report direct measurements of the valley susceptibility, the change of valley population in response to an applied symmetry-breaking strain, in an AlAs two-dimensional electron system. As the two-dimensional density is reduced, the valley susceptibility dramatically increases relative to its band value, reflecting the system's strong electron-electron interaction. The increase has a remarkable resemblance to the enhancement of the spin susceptibility and establishes the analogy between the spin and valley degrees of freedom. 相似文献