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The title compound 3,9-bis(pyridin-2-yl)-2,4,8,10-tetraoxaspiro[5.5]undecane 4(C17H18N2O4) has been synthesized by the reaction of 2,2-bis(hydroxymethyl)propane-1,3-diol with pyridine-2-carbaldehyde in the presence of p-toluenesulfonic acid,and characterized by IR,1H-NMR and X-ray single-crystal diffraction.The crystal belongs to monoclinic system,space group C2/c with a = 25.133(2),b = 5.7219(5),c = 21.942(2) ,β = 99.145(2)°,V = 3115.3(5)3,Z = 8,Dc = 1.340 g/cm3,Mr = 314.33,F(000) = 1328,μ = 0.097 mm-1,MoKa radiation(λ = 0.71073),R = 0.0352 and wR = 0.1022 for 2486 observed reflections with I > 2σ(I).X-ray analysis reveals that the two 1,3-dioxane rings passing through the central spiro-C atom both adopt chair conformation.Intermolecular C-H…π,C-H…O and C-H…N weak interactions link the molecules to form a three-dimensional samdwich,which are effective in the stabilization of the crystal structure. 相似文献
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变量选择控制图是高维统计过程监控的重要方法。针对传统变量选择控制图较少考虑高维过程空间相关性而造成监控效率低的问题,提出一种基于Fused-LASSO的高维空间相关过程监控模型。首先,利用Fused LASSO算法对似然比检验进行改进;然后,推导出基于惩罚似然比的监控统计量;最后,通过仿真模拟和真实案例分析所提监控模型的性能。仿真实验和真实案例均表明:在高维空间相关过程中,当相邻监控变量同时发生异常时,利用所提监控方法能够准确识别潜在异常变量,取得较好的监控效果。 相似文献
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