两种新型芴类Schiff碱的合成及其溶剂效应和聚集诱导发光性质

2-氨基-9,9-二甲基芴分别与2-羟基-1-萘甲醛和4-二乙胺基水杨醛经Schiff碱反应合成了两种新型芴类Schiff碱 (4和5),其结构经¹H NMR, ¹³C NMR, ESI-MS和元素分析表征。通过紫外-可见吸收光谱和荧光发射光谱初步研究了4和5的溶剂效应和聚集诱导发光性质。结果表明： 4和5的紫外吸收和荧光光谱受质子性溶剂的影响明显高于非质子性溶剂,同时两者具有良好的聚集诱导发光增强效应。THF-H₂-O体系中含水量分别达到60%和70%时, 4和5的荧光强度最大。     

构造高分辨率格式的反扩散混合法

In this paper we study a kind of mixed anti-diffusion method for partial differntial equations. Firstly, we use the method to construct some difference schemes for the conservation laws. The schemes are of second order accuracy and are total variation decreasing (TVD). In particular, there are only three knots involved in the schemes. Secondly, we extend the method to construct a few high accuracy difference schemes for elliptic and parabolic equations. Numerical experiments are carried out to illustrate the efficiency of the method.