Projected SD-pair shell model study for even-even Xe isotopes

Projected SD-pair shell model is used to study the collectivity of low-lying state for even-even Xe isotopes. It is found that the collectivity can be reproduced in term of a three-parameter Hamiltonian.     

三元掺杂改性锂离子电池正极材料Li3V2(PO4)3

以柠檬酸为螯合剂和还原剂, NH₄VO₃为钒源,通过溶胶-凝胶法制备了锂离子电池正极材料Li₃V₂(PO₄)₃及其三元掺杂体系Li_2.85Na_0.15V_1.9Al_0.1(PO₄)_2.9F_0.1.分别采用X射线衍射(XRD)、高分辨透射电子显微镜(HRTEM)、能量损失谱(EELS)、拉曼(Raman)光谱、扫描电子显微镜(SEM)、X射线能谱(EDS)、恒流充放电、循环伏安(CV)和交流阻抗谱(EIS)等技术对材料的微观结构、颗粒形貌和电化学性能进行分析.结果表明:在残余碳包覆的基础上, Na、Al、F三元掺杂有利于稳定Li₃V₂(PO₄)₃的晶体结构,进一步减少颗粒团聚和提升材料导电特性,促进第三个锂离子的脱出和嵌入,从而显著改善Li₃V₂(PO₄)₃的实用电化学性能.未经掺杂的Li₃V₂(PO₄)₃原粉在1/9C、1C和6C倍率下的可逆比容量分别为141、119和98 mAh·g^-1,而三元掺杂改性材料在1/9C、1C、8C和14C倍率下的比容量分别为172、139、119和115 mAh·g^-1.在1C倍率下循环300圈后,掺杂体系的比容量依然高达118 mAh·g^-1,比原粉高出32.6%.值得注意的是,这种三元掺杂还使Li₃V₂(PO₄)₃的多平台放电曲线近似转变为一条斜线,显示出可能不同的储锂机制.     

基于灰色关联度的多目标规划解法

分析了几种多目标规划解法的不足之处,在考虑多个目标之间的关联性的基础上,提出了一种新的求解多目标规划的方法.引入了灰色速率关联度来刻画目标函数之间的关联程度,定义了多目标转化为单目标的规则,利用此规则生成了新的目标函数,重新构建了约束条件.使用3种方法对同一多目标规划进行了求解,通过结果分析说明了基于灰色关联度的多目标规划解法的优越性.     

Computationally predicting spin semiconductors and half metals from doped phosphorene monolayers

First-principles computations are performed to investigate phosphorene monolayers doped with 30 metal and nonmetal atoms. The binding energies indicate the stability of all doped configurations. Interestingly, the magnetic atom Co doping induces the absence of the magnetism while the magnetism is realized in phosphorene with substitutional doping of nonmagnetic atoms (O, S, Se, Si, Br, and Cl). The magnetic moment of transition metal (TM)-doped systems is suppressed in the range of 1.0-3.97 μ_B. The electronic properties of the doped systems are modulated differently; O, S, Se, Ni, and Ti doped systems become spin semiconductors, while V doping makes the system a half metal. These results demonstrate potential applications of functionalized phosphorene with external atoms, in particular to spintronics and dilute magnetic semiconductors.     

Phase transition in finite density and temperature lattice QCD

We investigate the behavior of the chiral condensate in lattice QCD at finite temperature and finite chemical potential. The study was done using two flavors of light quarks and with a series of β and ma at the lattice size 24×12²×6. The calculation was done in the Taylor expansion formalism. We are able to calculate the first and second order derivatives of <ψψ> in both isoscalar and isovector channels. With the first derivatives being small, we find that the second derivatives are sizable close to the phase transition and that the magnitude of ψψ decreases under the influence of finite chemical potential in both channels.     

夸克数密度敏感性的格点研究

应用格点QCD理论对电荷涨落和夸克数密度敏感性进行了研究. 研究选取了 两个轻味夸克, 应用staggered作用量, 并选取了16×8²×4格点. 对电荷涨落和夸克数密度敏感性在V=(2a)³～(8a)³(这里a=\kou\dfrac{1}{4T})区间进行了数值计算. 结果显示, 在相变温度以下的区域内, 上述参数对体积V具有依赖性, 这表明了可以通过对上述参数的研究来确定强子的尺度. 在高于相变温度的区域内, 对体积V没有表现出依赖性.