Cu3V2O8 Nanoparticles as Intercalation‐Type Anode Material for Lithium‐Ion Batteries

Cu₃V₂O₈ nanoparticles with particle sizes of 40–50 nm have been prepared by the co‐precipitation method. The Cu₃V₂O₈ electrode delivers a discharge capacity of 462 mA h g^?1 for the first 10 cycles and then the specific capacity, surprisingly, increases to 773 mA h g^?1 after 50 cycles, possibly as a result of extra lithium interfacial storage through the reversible formation/decomposition of a solid electrolyte interface (SEI) film. In addition, the electrode shows good rate capability with discharge capacities of 218 mA h g^?1 under current densities of 1000 mA g^?1. Moreover, the lithium storage mechanism for Cu₃V₂O₈ nanoparticles is explained on the basis of ex situ X‐ray diffraction data and high‐resolution transmission electron microscopy analyses at different charge/discharge depths. It was evidenced that Cu₃V₂O₈ decomposes into copper metal and Li₃VO₄ on being initially discharged to 0.01 V, and the Li₃VO₄ is then likely to act as the host for lithium ions in subsequent cycles by means of the intercalation mechanism. Such an “in situ” compositing phenomenon during the electrochemical processes is novel and provides a very useful insight into the design of new anode materials for application in lithium‐ion batteries.     

The Experimental Approach to Effective Stress Law of Coal Mass by Effect of Methane

Effective stress law of all kinds of coal samples, including steam coal, fat coal, corking coal, thin coal and anthracite, under pore pressure of gas, is experimentally studied using a newly developed test machine. These samples are taken from Coal Mines in Wuda, Hebi, Yanzhou, Yangquan, Qingshui, and Gujiao in China. The experiment results show that, under pore pressure of gas, the tested coal samples comply with Biots effective stress law, where the Biots coefficient is not a constant, and is bilinear function of volumetric stress () and pore pressure (p), that is, We define four areas according to the numerical feature of , that is, functionless area of pore pressure, normal function area, fracturing function area, and quasi-soil function area. The effective stress law of coal mass introduced by this paper is a constitutive equation in the study of coupled solid and fluid. This has significance in the drainage and outburst of methane in coal seam.     

Synthesis and Antitumor Evaluation of Novel Hybrids of Phenylsulfonylfuroxan and Estradiol Derivatives

Fifteen novel furoxan-based nitric oxide (NO) releasing hybrids of estradiol derivatives were synthesized and evaluated in vitro anti-proliferative activity in MDA-MB-231, A2780, Hela and HUVEC cell lines. Most of them displayed potent anti-proliferative effects. Among the compounds, 4-bromo-3-((phenylsulfonyl)-1,2,5-oxadiazole 2-oxide)-oxy-propoxy-estradiol ( 11 b ) exhibited the best activity with IC₅₀ values of 3.58–0.0008 μM. Preliminary pharmacological studies showed that 11 b induced apoptosis and hardly affected the cell cycle of MDA-MB-231 cell line. NO-releasing capacity and inhibition of ERK/MAPK pathway signaling might explain the potent antineoplastic activity of these compounds. The preliminary structure-activity relationship (SAR) showed that steroidal scaffolds with a linker in 3-position were favorable moieties to evidently increase the bioactivities of these hybrids. Overall, these results implied that 11 b merited to be further investigated as a promising anti-cancer candidate.     

Effects of Ultra-sonification Assisting Polyethylene Glycol Pre-treatment on the Crystallinity and Accessibility of Cellulose Fiber

In order to prepare the advanced cellulosic super-absorbent polymer with high grafting level, we tried the novel ultrasound wave assisting polyethylene glycol (PEG) pre-treatment method to decrease the crystallinity and increase the accessibility of cellulose fiber. The effects of ultrasonification assisting PEG method on the crystallinity and swelling capacity of cellulose fiber were investigated. To optimize the experimental condition, the Taguchi method was employed in the treatment process. The influence factors such as ultrasonic wave power, ultrasonic wave time and PEG molecular weight relative to the crystallinity of cellulose fiber were studied systematically. The degree of crystallinity of cellulose fiber was measured by wide-angle X-ray diffraction (WAXD). The morphology of cellulose fiber was observed by environment scanning electron microscopy (ESEM). The effects of pre-treatment variables on the water absorbency and water retention values of cellulose fiber were also investigated. The research results revealed that, under the optimal experimental condition (ultrasonic powder, 500 W; ultrasonic time, 150 s; PEG molecular weight, 600 g/mol), the crystallinity of cellulose fiber decreased from 72.16 to 42.95%. Accordingly, the absorbency of cellulose fiber increased from 1.436 to 2.063 g/g, and the water retention value increased from 47.21 to 113.4%. However, the morphology of cellulose fiber did not change thoroughly compared with the original cellulose fiber. It can be hypothesized that the original inter- and intra-macromolecular hydrogen bonds in cellulose network were weakened, resulting from the high level dispersion of PEG within cellulose network without breaking the surface morphology of fiber.     

Cp—Groups and SOme Results on the p—nilpotency

Let P∈SylpG,ch(P) be any characteristic subgroup of P. A group C is called a Cp-group if G satisfies the condition "NG(ch(P)) is p-nilpotent implies that G is p-nilpotent". In this paper some properties on Gp-groups and some suffcient conditions for a group to be p-nilpotent are obtained.     

有限π-拟幂零群

本文把有限幂零群的概念推广为有限π-拟幂零群,证明了这类群的一系列性质。文中定理9推广了[1]的两个主要结果。 本文涉及的群G均指有限群。 定义1 设π为某素数集合。N≤G。若(?)P_i∈π,G的Sylow p_i-子群均与N可换,则称N为G的一个π-拟正规子群。(当p_i(?)°(G)时,G的Sylow p_i-子群理解为G的单位元群1;若π为空集,则1是G的唯一的π-子群。此时G的每个子群是π-拟正规的)[2]。     

有限群极大子群的θ-子群偶

N.P.Mukherjee和 P.Bhattacharya在“On theta pairs for a maximal sub-group”(Proc.Amer.Math.Soc,Vl09N3(1990))一文中定义了有限群的极大子群的θ-子群偶概念,研究了极大子群的极大θ-子群偶对群结构的影响,得到了一系列结果.本文在进一步探究θ-子群偶性质的基础上,对该文中一系列主要结果作出了本质性的改进,并给出了可解性、幂零性的一些新刻划.     

Main-chain biodegradable liquid crystal based on diosgenyl end-capped poly(trimethylene carbonate)

Main-chain biodegradable liquid crystal based on c diosgenyl end-capped poly(trimethylene carbonate) [Dios-(TMC)n] was investigated. The novel liquid crystal was synthesized through ring-opening polymerization of trimethylene carbonate initiated by diosgenin, without adding any catalyst. The chemical structure of resulting polymers was confirmed by ¹H NMR. The liquid crystalline properties were validated by X-ray diffraction, differential scanning calorimetry, and polarising optical microscopy. The results showed that the synthesized Dios-(TMC)n exhibited liquid crystallinity in particular temperature ranges because of the incorporation of the diosgenin moieties.     

On the desking completions,theta completions and theta pairs for maximal subgroups *

Given a maximal subgroup M of a finite group G,a θ completion of M in G is any subgroup C such that C is not contained in M while M_G , the core of M in G, is contained in C and C/M_G has no propor normal subgroup of G/M_G . By using this concept we can reveal the relationship between the concepts of completions and θ-pairs introduced respectively by Deskins, Mukherjee and Bhattacharya. The concept of maximal θ-completions offers a convenience for us to study the Deskins completions in inductions. We obtain in this paper several results which imply a group to be solvable, supersolvable and nilpotent.     

开口厚壁截面短构件的约束扭转1）

为了分析开口厚壁截面短构件的约束扭转问题,采用统一分析梁模型与有限节线法,对T形和L形厚壁截面短构件约束扭转时横截面的翘曲和应力分布情况等问题进行了分析研究.算例计算结果表明：开口厚壁截面短构件存在与其横截面形心位置不一致的扭转（弯曲）中心,构件在不过扭转中心的外力作用下会产生弯扭耦合变形,其横截面将产生不均匀翘曲,横截面上的翘曲正应力和扭转剪应力均呈非线性分布.