Laser speckle reduction using motionless image conduits

We have demonstrated a speckle reduction method using motionless image conduits (MICs). Different experimental conditions by introducing the high-coherence HeNe laser and the low-coherence laser diode (LD) as the illumination light sources, by employing the straight MIC and the curved MIC as the speckle reduction components, and by recording speckle images without (objective speckle) and with (subjective speckle) the imaging lens mounted on the CCD camera are conducted, respectively. The most efficient speckle reduction condition is found by the combination of using the LD and the curved MIC, where the objective speckle contrast ratio is reduced from 0.7378 to 0.1725. Experimental results are discussed, and the causes for these speckle reduction efficiency changes are given.     

Divergent Total Synthesis of Euphoranginol C,Euphoranginone D,ent-Trachyloban-3β-ol,ent-Trachyloban-3-one,Excoecarin E,and ent-16α-Hydroxy-atisane-3-one

A divergent synthetic approach to biogenetically related diterpenoids such as ent-kauranes, ent-trachylobanes, ent-beyerane, and ent-atisane has been developed. The unified synthetic route involves the De Mayo reaction to rapidly generate the bicyclo[3.2.1]-octane moiety of ent-kaurane. The key reactions also include bioinspired nucleophilic cyclopropanation generating the [3.2.1.0^2,7]-tricyclic core of ent-trachylobane and regioselective cyclopropane fragmentation furnishing ent-beyerane and ent-atisane through the nucleophilic attack and protonation of the cyclopropane ring. This strategy enables the asymmetric total syntheses of six diterpenoids from the commercially available geraniol.     

Nonlinear vibration isolation via an innovative active bionic variable stiffness adapter (ABVSA)

Nonlinear Dynamics - During the process of spacecraft launch, the extreme vibration environment is the major influence factor that induces the failure of the mission. Inspired by the smooth motions...     

Synthesis of β-phenyl-δ,ε-unsaturated amino acids and stereoselective introduction of side chain groups into [4,3,0]-bicyclic β-turn dipeptides

(2S,3S)- and (2R,3R)-2-amino-3-phenyl-5-hexenoic acids have been synthesized in large scale by using Ni(II)-complexes as a template. The amino acids were used in the synthesis of [4,3,0]-bicyclic β-turn mimetics by a convergent methodology. The unique advantage of this strategy is the convenience of introducing side chain groups with predetermined chiralities on both the five- and six-membered heterocyclic rings.     

钙钛矿型La_((1 x)/2)Sr_((1-x)/2)Co_(1-x)Cu_xO_3催化CO氧化活性与表征

研究了钙钛矿型LaSrCoCu_xO_3催化剂对CO氧化反应的催化活性及其表面氧的催化作用．结果表明，x＝0．4的催化剂对CO氧化具有最高催化活性，常压及本实验条件下CO完全氧化的最低温度为168℃；催化剂均为氧缺陷化合物，吸附于表面晶格氧缺陷上的吸附氧是CO氧化反应的活性氧物种；并发现催化剂中存在有非常价态的C04 ，认为CO氧化反应是通过吸附氧调变Co3 和Co4 价态而进行．     

Asymmetric Eschenmoser-Claisen rearrangement for anti-beta-substituted gamma,delta-unsaturated amino acids

Optically active anti-beta-substituted gamma,delta-unsaturated amino acids are important synthetic building blocks in organic synthesis and for peptidomimetics. A novel asymmetric Eschenmoser-Claisen rearrangement with use of a C2-symmetric chiral auxiliary was developed to generate this type of amino acid. Excellent diastereoselectivities and high enantioselectivities (87-93% ee) were obtained after the chiral auxiliary was removed via iodolactonization/zinc reduction.     

Modified Fowler–Nordheim tunnelling for modelling charge injection into Si3N4 in an Al/Si3N4/Si structure

Charge injection behaviours in silicon nitride of an Al/Si₃N₄/n-Si metal?Cinsulator?Csemiconductor (MIS) device are systematically studied before and after applying different high constant DC bias conditions with the aim of controlling charge accumulation in the dielectric when a high actuation voltage is applied. We found that both polarity and magnitude of charge accumulation in silicon nitride depend on the biasing direction. Charge injection from the semiconductor to the silicon nitride always dominates over charge injection from the Al electrode to the silicon nitride. Negative charge accumulation happens in silicon nitride when the Al electrode is positively biased, and positive charge accumulation occurs in silicon nitride when the Al electrode is negatively biased. The positive charge accumulation is much bigger than the negative charge accumulation under the same magnitude of stress voltage. Furthermore, the experimental results also show that the charge injection level exponentially increases with the applied voltage across the silicon nitride. These observed experimental results can be well explained by a modified Fowler?CNordheim tunnelling charge injection model, which takes into account the roles of both electrons and holes in the process of charge injection.     

Frequency response measurement of high-speed photodetectors using the spectrum power method in a delay self-heterodyne system

We report on a photoionization scheme for controlled loading of ⁸⁸Sr⁺ ions into a radio-frequency (rf) ion trap. The two-step doubly-resonant process drives the ⁸⁸Sr atom on the 5s^{2 1} S ₀ – 5s5p¹ P ₁ transition at 461 nm using a frequency-doubled diode laser, and then excites the atom to the autoionizing (4d²+5p²) ¹ D ₂ state with 405 nm light from a free-running diode laser. This method of trap loading is quantitatively compared to electron bombardment loading, and shown to reduce the Sr vapour pressure required to load by four orders of magnitude. It also provides more than an order of magnitude reduction in the day-to-day variation of the voltages required to compensate micromotion. We additionally introduce a two-step atomic source consisting of an oven and hotplate, which reduces the number of impurities evaporated towards the trap. This is shown to significantly reduce fluctuations in required micromotion compensation voltages. The demonstrated reduction in flux and increased source purity are expected to improve the reliability of trap operation for precision ion-trap experiments. PACS 32.80.Fb; 32.80.Pj; 39.10.+j     

Large scale enantiomeric synthesis, purification, and characterization of ω-unsaturated amino acids via a Gly-Ni(II)-BPB-complex

The enantiomeric syntheses of ω-unsaturated amino acids and β-substituted ω-unsaturated amino acids were accomplished by using Gly-Ni-2[N-(N′-benzylprolyl)amino]benzophenone (BPB) as a chiral auxiliary. The synthesis provides excellent yields and high diastereoselectivities. The product crystallization followed by isomer epimerization strategy makes the reaction practical and useful for large-scale preparations. Dialkylation of the Ni(II)-complex, which was designed for mechanistic considerations, revealed that high diastereoselectivity is obtained due to the thermodynamic conformational stability of the Ni(II)-complex. The assignment of absolute configuration was accomplished by NMR, which is supported by corresponding X-ray structure and optical rotation data. Both enantiomerically pure amino acids can be synthesized in this alkylation-hydrolysis two-step strategy in multi gram scales.