基于微腔效应增强单层二硫化钨光吸收

提出基于金属薄膜-分布式布拉格反射器微腔效应增强单层二硫化钨光吸收的多层薄膜结构.运用光学传输矩阵理论研究了其输运特性,发现由于金属薄膜-分布式布拉格反射器的微腔效应,在间隔层和覆盖层之间形成电场强度极大值,有效促进入射光与单层二硫化钨的相互作用.综合优化金属层、间隔层和覆盖层厚度,单层二硫化钨在612 nm处的光吸收提高了38倍,达到78.42;.进一步探讨了光入射角、分布式布拉格反射器周期、间隔层折射率与单层二硫化钨光吸收的关系.研究结果表明,上述结构参数的变化可有效调控单层二硫化钨的吸收峰值.研究结果为制备高性能单层二硫化钨光电探测器等新型光电子器件提供了新思路.     

Self-Healable Polyelectrolytes with Mechanical Enhancement for Flexible and Durable Supercapacitors

The practical application of advanced personalized electronics is inseparable from flexible, durable, and even self-healable energy storage devices. However, the mechanical and self-healing performance of supercapacitors is still limited at present. Herein, highly transparent, stretchable, and self-healable poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPSA)/poly(vinyl alcohol) (PVA)/LiCl polyelectrolytes were facilely prepared by one-step radical polymerization. The cooperation of PAMPSA and PVA significantly increased the mechanical and self-healing capacity of the polyelectrolyte, which exhibited superior stretchability of 938 %, stress of 112.68 kPa, good electrical performance (ionic conductivity up to 20.6 mS cm⁻¹), and high healing efficiency of 92.68 % after 24 h. After assembly with polypyrrole-coated single-walled carbon nanotubes, the resulting as-prepared supercapacitor had excellent electrochemical properties with high areal capacitance of 297 mF cm⁻² at 0.5 mA cm⁻² and good rate capability (218 mF cm⁻² at 5 mA cm⁻²). Besides, after cutting in two the supercapacitor recovered 99.2 % of its original specific capacitance after healing for 24 h at room temperature. The results also showed negligible change in the interior contact resistance of the supercapacitor after ten cutting/healing cycles. The present work provides a possible solution for the development of smart and durable energy storage devices with low cost for next-generation intelligent electronics.     

Development,validation and application of a UHPLC–MS/MS method for quantification of the adiponectin-derived active peptide ADP355 in rat plasma

A UHPLC–MS/MS method for the quantification of ADP355, an adiponectin-derived active peptide, was developed and validated. The extraction method employed simple protein precipitation using methanol and chromatographic separation was achieved on anAccucore™ RP-MS C₁₈ column (100 × 2.1 mm, 2.6 μm, 80 Å), using 0.1% formic acid in both water and acetonitrile with gradient elution at the flow rate of 400 μl/min within 4.0 min. Detections were performed under positive ion mode with multiple reaction monitoring ion transitions m/z 1109.2 → 309.8 and 871.4 → 310.1 for ADP355 and Jt003 respectively at unit resolution. The linearity range of the calibration curve was 2–1,000 ng/ml with a lower limit detection of 0.5 ng/ml. The selectivity, linearity, precision, accuracy, recovery, matrix effect and stability were validated, and all items met the requirement of US Food and Drug Administration guidance. This method was successfully applied to an intravenous pharmacokinetic study of ADP355 in rats and the in-vitro stability in rat serum, plasma and whole blood was also assessed.     

Solvothermal synthesis of transition metal (iron/copper) and nitrogen co−doped carbon nanomaterials: comparing their peroxidase−like properties

Journal of Nanoparticle Research - Polycrystalline metallic copper nanoparticle samples with the average particle sizes ranging from 53 to 80 nm were controllably prepared by the wet...     

Preparation of copper ferrite by sol–gel method and the synergistic catalytic for the thermal decomposition of ammonium perchlorate

Journal of Sol-Gel Science and Technology - In the present work, copper ferrite was prepared by a simple and mild sol–gel method followed by low-temperature calcination, and characterized by...     

非惯性系下柔性悬臂梁的振动主动控制

采用变结构控制方法对非惯性系下柔性悬臂梁的振动主动控制进行研究．重点通过算例揭示一次近似模型与传统的零次近似模型的巨大差异，以及变结构方法在控制非惯性系下柔性悬臂梁的稳态振动的有效性．结果表明，当大范围旋转运动角速度较大时，传统零次近似模型不能对动力系统进行正确的数学描述；变结构控制方法能够使得非惯性系下梁的稳态振动得到完全镇定，且该方法对转动角速度变化具有较好的鲁棒性；采用零次近似模型进行控制设计的控制效果将在某一临界角速度条件下出现失效，该临界角速度值大于静止悬臂梁的基频．     

绕旋转圆柱流动涡尾流结构和临界状态特性

采用作者提出的基于区域分解，有限差分法与涡法杂交的数值方法，结合高阶隐式差分格式，和以修正的不完全ＬＵ分解为预处理器的共轭梯度法作求解器，系统地研究了雷诺数Ｒｅ＝１０００，旋转速度比α∈（０．５，３．２５）范围内，绕旋转圆柱从突然起到充分发展，长时间内尾流旋涡结构和阻力，升力系数的变化规律，计算所得流动图案与实验流场显示符合很好。数值试验证帝了临界状态的存在，并首次给出了临界状态时的旋涡结构特性。     

线性系统模态控制及其时滞补偿

对线性系统模态控制及其时滞补偿进行研究。模态控制分控制全部模态和控制有限模态两种情况 ,时滞补偿采用移相补偿。最后结合算例对两种控制模态下的控制效果和控制有限模态时的时滞补偿进行了数值计算和结果对比     

船舶流体力学中若干逆问题的研究

在船舶流体力学中，给定物体（船、桨、附体或其组合体），要求确定其在不同的运行状态和环境条件下的某种性能（如阻力、运动等等）或周围的流场，这种问题称为正问题．与此相反，若给定物体的性能要求或场的信息，寻求满足要求的物体，就是逆问题．本文通过船舶流体力学中若干逆问题（如给定表面速度分布时螺旋桨桨叶剖面设计、轴对称物体设计等等）的介绍和讨论，对逆问题研究的特殊性、实用性及可能的发展方向作简要的评述．