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1.
Manuel
Bernard Ghislain Lartigue Guillaume Balarac Vincent Moureau Guillaume Puigt 《国际流体数值方法杂志》2020,92(11):1551-1583
In this article, a new framework to design high-order approximations in the context of node-centered finite volumes on simplicial meshes is proposed. The major novelty of this method is that it relies on very simple and compact differential operators, which is a critical point to achieve good performances in the High-performance computing context. This method is based on deconvolution between nodal and volume-average values, which can be conducted to any order. The interest of the new method is illustrated through three different applications: mesh-to-mesh interpolation, levelset curvature computation, and numerical scheme for convection. Higher order can also be achieved within the present framework by introducing high-rank tensors. Although these tensors feature much symmetries, their manipulation can quickly become an overwhelming task. For this reason and without loss of generality, the present articles are limited to third-order expansion. This method, although tightly connected to the k-exact schemes theory, does not rely on successive corrections: the high-order property is obtained in a single operation, which makes them more attractive in terms of performances. 相似文献
2.
Corrigendum: Crystallographic Snapshot of an Arrested Intermediate in the Biomimetic Activation of CO2 下载免费PDF全文
3.
Zeina Al Masry Sophie Mercier Ghislain Verdier 《Methodology and Computing in Applied Probability》2017,19(1):213-235
In reliability theory, many papers use a standard Gamma process to model the evolution of the cumulative deterioration of a system over time. When the variance-to-mean ratio of the system deterioration level varies over time, the standard Gamma process is not convenient any more because it provides a constant ratio. A way to overcome this restriction is to consider the extended version of a Gamma process proposed by Cinlar (J Appl Probab 17:467–480, 1980). However, based on its technicality, the use of such a process for applicative purpose requires the preliminary development of technical tools for simulating its paths and for the numerical assessment of its distribution. This paper is devoted to these two points. 相似文献
4.
Nicolas Illy Mike Robitzer Rémi Auvergne Sylvain Caillol Ghislain David Bernard Boutevin 《Journal of polymer science. Part A, Polymer chemistry》2014,52(1):39-48
A novel, straightforward and versatile chemical pathway has been studied to functionalize water‐soluble chitosan oligomers. This metal‐free methodology is based on the epoxy‐amine reaction of the allyl glycidyl ether with chitosan, followed by thiol‐ene radical coupling reaction of ω‐functional mercaptans, using 4,4′‐Azobis(4‐cyanovaleric acid) as a free radical initiator. Both reactions were entirely carried out in water. In a preliminary step, chitosan depolymerization was carried out using H2O2 in an acetic medium under 100 W microwave irradiation, optimizing the yield of water‐soluble oligomers. Functionalization by six different thiols bearing alcohol, carboxylic acid, ester, and amino groups was then performed, leading to a range of functional oligochitosans with different grafting efficiencies. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 39–48 相似文献
5.
Ghislain R. Franssens 《Mathematical Methods in the Applied Sciences》2013,36(9):1014-1027
The set of associated homogeneous distributions (AHDs) with support in R is an important subset of the tempered distributions because it contains the majority of the (one‐dimensional) distributions typically encountered in physics applications (including the δ distribution). In a previous work of the author, a convolution and multiplication product for AHDs on R was defined and fully investigated. The aim of this paper is to give an easy introduction to these new distributional products. The constructed algebras are internal to Schwartz’ theory of distributions and, when one restricts to AHDs, provide a simple alternative for any of the larger generalized function algebras, currently used in non‐linear models. Our approach belongs to the same class as certain methods of renormalization, used in quantum field theory, and are known in the distributional literature as multi‐valued methods. Products of AHDs on R, based on this definition, are generally multi‐valued only at critical degrees of homogeneity. Unlike other definitions proposed in this class, the multi‐valuedness of our products is canonical in the sense that it involves at most one arbitrary constant. A selection of results of (one‐dimensional) distributional convolution and multiplication products are given, with some of them justifying certain distributional products used in quantum field theory. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
6.
Fadela Iftene Ghislain David Bernard Boutevin Rémi Auvergne Ali Alaaeddine Rachid Meghabar 《Journal of polymer science. Part A, Polymer chemistry》2012,50(12):2432-2443
Three new vinyl ether monomers containing phosphonate moieties were synthesized from transetherification reaction. We showed that the yield was dependent on the spacer length between the vinyl oxy group and the phosphonate moieties: when the spacer is a single methylene side reaction may occur, leading to the formation of acetal compounds. Free‐radical copolymerizations of phosphonate‐containing vinyl ether monomers with maleic anhydride were carried out, leading to alternated copolymers of rather low molecular weights (from 1000 to 7000 g/mol). Both gel permeation chromatography and 31P NMR analyses enhanced possible intramolecular transfer reactions occurring from the phosphonate moieties. Kinetic investigation showed that the electron‐withdrawing character of the phosphonate moieties tends to decrease the rate of copolymerization. Nevertheless, almost complete monomers conversion was reached after 30 min of reaction with dimethyl vinyloxyethylphosphonate (VEC2PMe). Then, radical copolymerization of VEC2PMe with a series of electron‐accepting monomers, that is, dibutyl maleate, dibutylitaconate, itaconic anhydride, butyl maleimide, and methyl maleimide, led to a series of alternated copolymers. From kinetic investigation, we showed that the higher the electron‐accepting effect, the faster the vinyl ether consumption and the higher the molecular weights. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
7.
Hossein Vahabi Laurent Ferry Claire Longuet Rodolphe Sonnier Claire Negrell-Guirao Ghislain David José-Marie Lopez-Cuesta 《European Polymer Journal》2012,48(3):604-612
The influence of phosphonated groups on thermal degradation and flammability has been investigated in the case of two chemically modified PMMA. Thermogravimetric analysis as well as pyrolysis combustion flow calorimetry have been used to define the efficiency of phosphorus in both condensed and vapor phases. A theoretical study was also performed to determine the contribution of phosphonated groups to the effective heat of combustion, residue content and heat release capacity. Empirical and theoretical approaches agreed to highlight that PMMA modified with monophosphonated comonomer is more efficient in both condensed and vapor phases in terms of flammability and char formation. These results were attributed to the ability of phosphonate groups to interact with ester groups and also to the weakness of the P–C–N bonds. Moreover, this study proposes a method for designing the chemical environment of phosphonate group in polymers to achieve better flame retardancy. 相似文献
8.
Ghislain Blanquet Jacques Walrand Irne Hilgers Daniel Lambot 《Journal of Molecular Spectroscopy》1990,140(2)
A tunable diode laser was used to perform measurements of absolute lines intensities in the ν1 fundamental of carbonyl sulfide. Spectra have also been recorded for the following isotopic species: 16O12C34S, 16O13C32S and 16O12C33S. The vibrational band strength Sv0 was calculated at 298 K. The absolute intensity for 100% of 16O12C32S species is found to be Sv0 = 29.69 ± 0.15 cm−2 atm−1 with the uncertainty covering three times the standard deviation. We have tried to determine the α-coefficient involved in the Hermann-Wallis factor F = (1 + αm + )2 and the value is found to be negligible (−5 ± 8) × 10−5. The Sv0 value obtained for the other isotopic species is very close to the normal one. 相似文献
9.
N2-broadening coefficients are measured for 61 transitions of PH3 in the QR branch of the ν2 band and the PP, RP, SP, and PQ branches of the ν4 band, using a tunable diode-laser spectrometer. The recorded lines with J values ranging from 1 to 16 and K from 0 to 11 are located between 1008 and 1106 cm−1. The collisional widths are determined by fitting each spectral line with a Voigt profile, a Rautian profile, and a speed-dependent Rautian profile. The latter models provide larger broadening coefficients than the Voigt model. These coefficients have also been calculated on the basis of a semiclassical model of interacting linear molecules by considering an atom-atom Lennard-Jones potential in addition to the electrostatic contributions. The theoretical results are in good agreement with the experimental data and reproduce the J dependence of the broadenings, but their decrease at high J values is overestimated for the QR (J, K) transitions. 相似文献
10.
T. Martínez F. Aguilar J. Lartigue M. Navarrete L. A. Cuapio C. López O. Y. Morales 《Journal of Radioanalytical and Nuclear Chemistry》2008,278(2):365-370
Due to large consumption of tobacco in Mexico and in order to complement previous work performed by total reflection X-ray
fluorescence, the present study has determined 15 elements by INAA in 9 cigarettes brands being marketed in Mexico. As a part
of a Quality Control Program, NIST standard reference materials (SRM) and an IAEA reference material were analyzed to confirm
the accuracy and reproducibility. Average of As and Cd were 0.56 and 1.15 μg·g−1, respectively, in the range of those of foreign brands. 相似文献