煤系地层岩石渗透特性试验研究

基于MTS815.02型岩石伺服渗透试验系统,应用两种实验方法测定了岩石的渗透特性,给出煤系地层中多种岩石全应力-应变过程中渗透率变化范围,对几种岩石的渗透特征进行了分析和讨论。研究表明:1)煤系地层岩石全应力-应变过程的渗透率通常在10-9到10-4Darcy量级之间;2)不同岩石在应力峰值前后其渗透性呈现不同的变化趋势;3)岩石渗透率的离散性很大,即使在相同的试验条件下,渗透率变异系数大多在0.65以上,其离散性按粗砂岩、泥岩、砂质页岩、中砂岩、细砂岩、砾岩、石灰岩顺序逐渐增大;4)在MTS815.02系统上,当所测岩样渗透率小于10-4Darcy量级时,应采用瞬态法,当渗透率量级大于10-4Darcy时,可改用稳态法测定。岩石变形过程中应力场和渗流场的耦合作用十分复杂,渗透率受孔隙压力、围压、试件尺寸、饱和程度等因素影响。     

聚氯乙烯接近玻璃化转变温度时的蠕变行为研究

利用动态力学分析仪,详细研究了小应力作用下聚氯乙烯（PVC）接近玻璃化转变温度（63℃）时的短期蠕变性能．根据Struik-Kohlrausch (SK)方程及Struik移位方法,分析了物理老化对PVC瞬时蠕变柔量的影响,并提出了基于多松弛机制的新模型定量描述初始蠕变柔量、松弛时间和形状因子．结果表明:SK方程虽可表征不同老化时间下PVC的蠕变性能,但通过Struik移位方法却无法获得理想的主曲线,且初始蠕变柔量、松弛时间、形状因子和蠕变率均受物理老化显著影响,并在双对数坐标下随老化时间呈明显的非线性变化;新模型不仅揭示了物理老化控制参量的演化规律,而且极好地预测了PVC在物理老化进程中的高温蠕变行为．     

Creep performance of PVC aged at temperature relatively close to glass transition temperature

In order to predict the mechanical performance of the polyvinyl chloride(PVC) at a high operating temperature,a series of short-term tensile creep tests(onetenth of the physical aging time) of the PVC are carried out at 63 C with a small constant stress by a dynamic mechanical analyzer(DMA).The Struik-Kohlrausch(SK) formula and Struik shifting methods are used to describe these creep data for various physical aging time.A new phenomenological model based on the multiple relaxation mechanisms of an amorphous polymer is developed to quantitatively characterize the SK parameters(the initial creep compliance,the characteristic retardation time,and the shape factor) determined by the aging time.It is shown that the momentary creep compliance curve of the PVC at 63 C can be very well fitted by the SK formula for each aging time.However,the SK parameters for the creep curves are not constant during the aging process at the elevated temperatures,and the evolution of these parameters and the creep rate versus aging time curves at the double logarithmic coordinates have shown a nonlinear phenomenon.Moreover,the creep master curves obtained by the superposition with the Struik shifting methods are unsatisfactory in such a case.Finally,the predicted results calculated from the present model incorporating with the SK formula are in excellent agreement with the creep experimental data for the PVC isothermally aged at the temperature relatively close to the glass transition temperature.