Synthesis,Crystal Structure and Photoluminescence of a Three-coordinate Ag(Ⅰ) Complex

A three-coordinate Ag(I) complex, [Ag(Mepzpy)(PAr3)]BF4·H2O(1, Mepzpy = 3-methyl-1-(2-pyridyl)pyrazole, PAr3 = tri(o-tolyl)phosphine), was synthesized from the reaction of Ag(CH3CN)4BF4, PAr3 and Mepzpy in CH3 CN at room temperature. The compound was characterized by UV-vis, NMR and X-ray single-crystal structure analysis. It crystallizes in triclinic space group P1 with a = 10.2251(5), b = 10.6014(5), c = 15.7012(5) , α = 92.963(3), β = 92.641(3), γ = 114.647(4)o, V = 1540.6(1) 3, Z = 2, Mr = 676.24, Dc = 1.458 g/cm3, F(000) = 688, μ = 6.187 mm-1, GOOF = 1.038, the final R = 0.0530 and w R = 0.1493 for 6371 observed reflections with I 2σ(I). Compound 1 is ionic. It is composed of a BF4- anion and a [Ag(Mepzpy)(PAr3)]+ cation. The Ag(I) ion adopts a distorted trigonal pyramidal coordination geometry defined by two nitrogen atoms and a phosphorous atom. The complex emits blue luminescence with maximum peaks at 470 nm in solid state at room temperature.     

含预制单裂隙石膏裂纹孕育与能量演化的应变率效应研究

基于高速相机和MTS万能试验机对含预制裂纹石膏样品进行了单轴压缩应变率效应试验研究,在应变率10~(-5)/s～10~(-3)/s之间选取6种应变率进行单轴压缩试验,对应力应变曲线、裂纹扩展路径、起裂应力、起裂角、弹性模量、峰值强度等与裂纹扩展相关的信息进行了应变率效应分析,并基于岩石材料破坏能量演化原理对其进行解释。试验表明:应变率在10~(-5)/s～2×10~(-4)/s范围时,石膏样品应力应变曲线台阶式上升或回落,波动较多,翼型裂纹发展充分,起裂应力、弹性模量、峰值强度等相差不大,裂纹起裂角82°左右,验证了最小应变能密度因子理论;应变率在5×10~(-4)/s、 10~(-3)/s时,石膏样品应力应变曲线峰前斜率较大,峰后跌落快,表现出岩石类材料典型的脆性特征,起裂应力、弹性模量、峰值强度等力学参数明显增大,起裂角为105°,此时应变能密度因子理论不再适用。