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<正>Properties of two LiFePO_4/C composites with low carbon content synthesized from precursors dried by spray drying and blast drying are investigated by scanning electron microscopy, X-ray diffraction, Raman spectroscopy and electrochemical measurements. The two samples have a different morphology and particle size, while the structure of LiFePO_4 is unaffected. The LiFePO_4/C composite prepared from the precursor dried by blast drying has a much lower surface resistance and a much better rate capability because the deposited carbon is more graphite-like and more conductive. The cycling performance is also much better for the LiFePO_4/C composite prepared from the precursor dried by blast drying because only a slight impedance growth is involved upon cycling. These results suggest that the precursor drying process has a significant impact on the properties of LiFePO_4/C composite, and its effect is highly dependent on the carbon content. 相似文献
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Ran Zhang Shi-Bin Wang Wen-Guo Wu Ranjith Kumar Kankala Ai-Zheng Chen Yuan-Gang Liu Jing-Qian Fan 《Journal of nanoparticle research》2017,19(6):224
Recently, targeted drug delivery systems (TDDS) have offered a great potential and benefits towards the anti-tumor drug delivery. In this work, we designed the TDDS using a biocompatible poly(ethylene glycol)-poly(β-amino esters) amphiphilic block copolymer (PEG-PAEs) synthesized by Michael addition polymerization for combinatorial therapy. Further, the chemotherapeutic agents’ doxorubicin (DOX) and AS1411 DNA aptamer (Apt) are encapsulated in the PEG-PAEs NPs (PDANs) for co-delivery therapeutics. PDANs have shown the monodisperse spherical shape, smooth surface with a net positive charge (average diameter—183.1 ± 27.2 nm, zeta potential—31.2 ± 6.3 mV), and good colloidal stability (critical micelle concentration of PEG-PAEs is about 6.3 μg/mL). The pH-sensitive PAEs endowed PDANs both pH-triggered drug release characteristics and enhanced endo/lysosomal escape ability, thus improving the localization and cytotoxicity of DOX. AS1411 Apt conjugated PDANs precisely targeted nucleolin and their uptake correlates to a significant activity enhancement only in tumor cells (MCF-7) but not in normal cells (MCF-10A). Thus, PDANs can be a very promising targeted drug delivery platform for effective breast cancer therapy. 相似文献
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报道了δ掺杂赝形高电子迁移率晶体管结构Al_(0.30)Ga_(0.70)As/In_(0.15)Ga_(0.85)As/GaAs的光致发光光谱研究的实验结果,除了观察到n=1电子子带到n=1重空穴子带,n=2电子子带到n=1重空穴子带间的强发光峰,还观察到了n=1电子子带到n=1轻空穴子带的弱发光峰,通过变化掺杂浓度来改变费密能级的位置,在这种δ掺杂的HEMTs系统中观察到了费密边奇异性,并把它归结为费密海与费密边附近未占据的第二电子子带之间的近共振散射作用所致。 相似文献
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针对关键生命线系统,如电网、供水网、供气网、交通网、通信网等的一些共性特征,建立一个普适性的灾害蔓延动力学模型. 这个模型考虑网络结点的自修复功能、灾害蔓延机制和内部随机噪声,并研究自修复因子、延迟时间因子和噪声强度三个重要特征参数对三种网络(随机网络、无标度网络和小世界网络)结点修复率和崩溃结点数的影响. 模拟结果与这些实际生命线系统的特征一致,表明所建立的模型可以有效地模拟生命线系统的灾害演化动力学.
关键词:
复杂网络
生命线系统
灾害蔓延 相似文献
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We report the long time dynamical behaviour of ac Stark effect in a simple quantum model in which two level atoms interact with quantized coherent radiation field. A new phenomenon of periodic quantum collapse and revival of the ac Stark shift of energy level due to ac Stark effect is expressed accurately by analysing the phase of transition probability amplitude. The analytic prediction is confirmed by the numerical results. 相似文献
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选用四种不同的密度泛函理论方法(B3LYP,B3P86,BLYP,BP86),在全电子的双ξ加极化加弥散函数基组(DZP )下,对SinH/SinH^-(n=3~8)体系进行研究,获得它们的基态结构和电子亲合能。预测Si3H/Si3H^-,Si4H/Si4H^-,Si5H/Si5H^-,Si6H/Si6H^-,Si7H/Si7H^-和Si8H/Si8H^-的基态结构分别为C2v(^2B2)/C2v(1^A1)氢桥结构,Cs(^2A’)/C(^1A’),C2v(^2B2)/C2v(^1A1),C2v(^2B2或^2B1)/C4v(^1A1),C5v(^2A1)/C5v(^1A1)和C5(^2A‘‘)/C3v(^1A1)。在电子亲合能方面,B3LYP方法预测的电子亲合能是最可靠的,预测Si3H,Si4H,Si5H,Si6H,Si7H和Si8H的电子亲合能分别为2.56,2.59,2.84,2.86,3.19和3.14eV。 相似文献
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高硅沸石骨架结构及其稳定性的模拟计算(I)* 总被引:2,自引:0,他引:2
The lattice energy of a series of high-silica zeolites was determined using the lattice energy minimization method. The results were compared to the lattice energy of dense polymorphs of SiO2. All high-silica zeolites frameworks are only 30~67kJ•mol-1 less stable than α-quartz This may imply that there is little energy barrier to the formation of high-silica zeolites frame-works and explain the structural diversity observed for high-silica zeolites. The relationships of calculated lattice energies and framework Structures was disscussed. The results revealed a good linear relationship between framework density of these molecular sieves and all-silica framework lattice energies. 相似文献
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稀土磷酸盐发光材料的微波合成 总被引:5,自引:0,他引:5
稀土磷酸盐发光材料的微波合成徐文国,田一光,刘淼,刘海堂,方光华,庞文琴(吉林大学化学系,环境科学系,长春,130023)关键词微波合成,稀土磷酸盐,微晶玻璃,玻璃态,发光材料稀土磷酸盐发光材料的研究是当前材料科学的热门研究课题。它们一般通过高温固相... 相似文献
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采用对掺入La_2O_3的石墨棒原位活化并结合交换电极回放方法制备了产率较高的金属富勒烯,并用甲苯高温热提取的方法有效地提取出La@C_(2n),其中La@C_(74)为可溶性金属富勒烯增加了新成员.同时,首次采用解吸电子轰击质谱对提取物进行了表征,讨论了提取物的ESR谱. 相似文献