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E. I. Klimova E. A. Vazquez Lopez T. Klimova M. Martinez Garcia N. N. Meleshonkova L. Ruiz Ramirez 《Russian Journal of General Chemistry》2004,74(12):1830-1835
Monocyclic 3- and 5-ferrocenyl-4,5-dihydropyrazoles with a free NH group in the molecule react with acetylacetone to form the corresponding enaminocarbonyl compounds. The latter were isolated as a single isomer, presumably E. 3-Ferrocenyldihydropyrazoles and 5-ferrocenyl-3-(p-methoxyphenyl)-4,5-dihydropyrazole analogously react with acetoacetic ester. 5-Ferrocenyl-3-phenyl-, 3-(p-bromophenyl)-5-ferrocenyl, and 3,5-diferrocenyl-4,5-dihydropyrazoles react with acetoacetic ester to form acetoacetylpyrazolides.Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 12, 2004, pp. 1942–1947.Original Russian Text Copyright © 2004 by E. Klimova, Vazquez Lopez, T. Klimova, Martinez Garcia, Meleshonkova, Ruiz Ramirez.This revised version was published online in April 2005 with a corrected cover date. 相似文献
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Klimova-Berestneva T. Martinez Garcia M. Meleshonkova N. N. Klimova E. I. 《Russian Journal of General Chemistry》2001,71(10):1626-1631
The asymmetric induction in the synthesis of 3,4,5-trisubstituted 4,5-dihydropyrazoles with ferrocenyl substituents, starting from the E and Z isomers of ,-unsaturated ketones was studied. A high diastereoselectivity was revealed at the 1,2 chiral center chiral center induction, which is independent of the configuration of the starting chalcones. 相似文献
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E. I. Klimova M. Martinez Garcia T. Klimova L. Ruiz Ramirez J. M. Mendez Stivalet N. N. Meleshonkova 《Russian Chemical Bulletin》2000,49(3):514-519
3,5-Bis(ferrocenylmethylene)-1-methyl-4-methylenepiperidine, a diferrocenyltriene with a fixeds-cisoid conformation of the exocyclic double bonds, was synthesized. On heating, this compound cyclodimerizes according to
the [4+2]-cycloaddition scheme; it forms Diels-Alder adducts with azodicarboxylic and maleic acidN-phenylimides. The compound easily cyclodimerizes in the presence of acids by a proton cyclodimerization mechanism to give
a spiro cyclodimer. The triene also adds a 3,5-bis(ferrocenylmethylene)-1,4-dimethyl-1-azonia-4-cyclohexyl salt to the terminal
methylene group yielding linear and cyclic addition products.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 511–516, March, 2000. 相似文献
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E. I. Klimova L. Ruiz Ramirez M. Martinez Garcia R. G. Espinosa N. N. Meleshonkova 《Russian Chemical Bulletin》1996,45(11):2602-2609
Biologically active nitrogen heterocycles (1–7) containing ferrocene and quinuclidine fragments were synthesized. 3-Methylene-2-ferrocenylmethylenequinuiclidine forms adducts withN-phenylimides of azodicarboxylic (the structure was established by X-ray structural analysis) and malefic acids. 3-Methylene-2-fer-rocenylmethylenequinticlidine also undergoes [4+2]-cyclodimerization when heated and adds salts of the 3-methyl-2-ferrocenylmethyleneI-azoniabicyclo[2.2.2]oct-3-yl cation at the terminal methylene group to form a linear addition product.Instituto de Quimica, Universidad Nacional Autonoma de Mexico (UNAM), Circuito Exterior, Ciudad Universitaria, Coyoacan.Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 11, pp 2743–2750, November, 1996. 相似文献
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Martinez M. G. Klimova-Berestneva T. Damian-Zea K. Meleshonkova N. N. Klimova E. I. 《Russian Journal of General Chemistry》2002,72(7):1132-1140
8-Acetyl-7-aryl-2-arylmethylene-8,9-diaza- and 4,8,9-triazabicyclo[4.3.0]non-9-enes react with4-phenyl-4,5-dihydro-3H-1,2,4-triazole-3,5-dione, following the ene addition pattern. Under similar conditons 7-aryl-2-arylmethylene-8-methyl-8,9-diazabicyclo[4.3.0]non-9-enes give rise to both mono- and polyadditionproducts. The product structures were studied by 1H and 13C NMR, IR, and UV spectroscopy and singlecrystal X-ray diffraction. 相似文献
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Prishchenko A. A. Livantsov M. V. Novikova O. P. Meleshonkova N. N. Livantsova L. I. Petrosyan V. S. 《Russian Journal of General Chemistry》2017,87(8):1879-1881
Russian Journal of General Chemistry - Convenient methods of synthesis of functionalized phosphonic acids and their trimethylsilyl esters containing quinuclidine, adamantine, and bornane (camphane)... 相似文献
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V. Yu. Tyurin N. N. Meleshonkova A. V. Dolganov A. P. Glukhova E. R. Milaeva 《Russian Chemical Bulletin》2011,60(4):647-655
Electrochemical method for the evaluation of antioxidative activity of compounds based on their reaction with the stable radical,
2,2-diphenyl-1-picrylhydrazyl, was suggested with monitoring of the reaction by cyclic voltammetry (CVA). Antioxidative properties
of new ferrocene derivatives Fc(L)R (where Fc is the ferrocenyl, R is the fragment of 2,6-di-tert-butylphenol or its aromatic analog, L is the spacer) were studied. Anodic oxidation of the compounds Fc(L)R, which contain
azomethine and 2,6-di-tert-butylphenol moities, proceeds in three steps, that suggests a possibility of intramolecular proton-coupled electron transfer
process. Conjugates of ferrocene and 2,6-di-tert-butylphenol are efficient antioxidants. 相似文献