排序方式: 共有149条查询结果,搜索用时 14 毫秒
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Ag改性提高TiO2对Cr(VI)的光催化还原活性机理 总被引:14,自引:0,他引:14
在消除了质子缺乏、光生电子-空穴复合对Cr6+光催化还原负效应影响下,比较了TiO2和Ag/TiO2(Ag质量分数 1.0%)光催化还原活性.结果表明,相同条件下Ag/TiO2表现出比TiO2更高的催化活性. EPR分析表明,对于Ag/TiO2,UV照射后Ag表面有活性物种生成,在TiO2上有活性中心表相Ti3+生成.光生电子通过表相Ti3+向Cr6+传递电子是Cr6+光催化还原的速度控制步骤.较多的表相Ti3+参与还原反应是Ag/TiO2表现出较高催化活性的主要原因,担载Ag上积聚光生电子的较强流动性对反应也起到一定促进作用. 相似文献
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采用浸渍法制备了CuO/TiO2负载型催化剂,并将其用于CO2加氢制甲醇反应。重点考察了铜的负载量对催化剂性能的影响,并对其物化性能和催化性能之间的关系进行了讨论。结果发现,随着铜负载量的增加,催化剂中金属铜的比表面先增加后减小,当铜的负载量为10%(质量百分数)时达到最大值。催化剂的表面碱性位数量随铜含量的增加持续减小,中等碱位和强碱位的强度下降。当铜的负载量不高于10%时,CO2的转化率与铜的比表面积呈线性关系。甲醇选择性与催化剂的表面碱位性质有关,过强的碱性位会降低甲醇选择性。 相似文献
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On the basis of the experimentally synthesized [(PY5Me2)4Mn4Re(CN)7]5+, the theoretically modeled clusters of [(PY5Me2)4V4Re(CN)7]5+ and [(PY5Me2)4Ni4Re(CN)7]5+ both have strong magnetic anisotropy energy barriers. 相似文献
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Boundedness and convergence of perturbed corrections for helium-like ions in ground states 下载免费PDF全文
Applying the improved Rayleigh SchrSdinger perturbation theory based on an integral equation to helium-like ions in ground states and treating electron correlations as perturbations, we obtain the second-order corrections to wavefunctions consisting of a few terms and the third-order corrections to energicity. It is demonstrated that the corrected wavefunctions are bounded and quadratically integrable, and the corresponding perturbation series is convergent. The results clear off the previous distrust for the convergence in the quantum perturbation theory and show a reciprocal development on the quantum perturbation problem of the ground state helium-like systems. 相似文献
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ZHAO Hong BAI Cheng-Lin 《理论物理通讯》2004,42(10)
Using the extended homogeneous balance method, we obtained abundant exact solution structures of the (3 1 )-dimensional breaking soliton equation. By means of the leading order term analysis, the nonlinear transformations of the (3t1)-dimensional breaking soliton equation are given first, and then some special types of single solitary wave solutions and the multisoliton solutions are constructed. 相似文献