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Mathieu Boiret Anna de Juan Nathalie Gorretta Yves-Michel Ginot Jean-Michel Roger 《Analytica chimica acta》2015
Raman chemical imaging provides chemical and spatial information about pharmaceutical drug product. By using resolution methods on acquired spectra, the objective is to calculate pure spectra and distribution maps of image compounds. With multivariate curve resolution-alternating least squares, constraints are used to improve the performance of the resolution and to decrease the ambiguity linked to the final solution. Non negativity and spatial local rank constraints have been identified as the most powerful constraints to be used. 相似文献
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Hanna Mouaziz Sebastian Braconnot Frédéric Ginot Abdelhamid Elaissari 《Colloid and polymer science》2009,287(3):287-297
Aminodextran containing submicron magnetic latex particles were prepared in two steps: (a) transformation of oil-in-water
magnetic emulsion into structured magnetic latex particles via combination of seed and miniemulsion-like polymerization process
and (b) immobilization (adsorption and chemical grafting) of prepared aminodextran onto negatively charged seed magnetic latex
particles. The elaborated magnetic latex particles were characterized in terms of particle size, size distribution, morphology,
surface charge density, chemical composition, magnetic properties, and also colloidal stability. The results showed that the
morphology of the prepared seed magnetic latex is core–shell like and the cationic latex particles are hydrophilic and of
high colloidal stability, irrespective of the aminodextran immobilization process. 相似文献
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Mathieu D Frapart YM Bartoli JF Boucher JL Battioni P Mansuy D 《Chemical communications (Cambridge, England)》2004,(1):54-55
Electron transfer from tetrahydropterins to iron porphyrins, with formation of intermediate tetrahydropterin cation radicals, is a very general reaction that was shown to occur not only with tetrahydrobiopterin, as originally found in NO-synthases, but also with another important biological cofactor, tetrahydrofolate, and various iron porphyrins, either in their ferric state, or in the Fe(II)O(2) state, as in the first model of the corresponding NO-synthase reaction described in this paper. 相似文献
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Grégory Ginot Thomas Tradler Mahmoud Zeinalian 《Communications in Mathematical Physics》2014,326(3):635-686
We study the higher Hochschild functor, factorization algebras and their relationship with topological chiral homology. To this end, we emphasize that the higher Hochschild complex is a functor sSet ∞ × CDGA ∞ where sSet and CDGA ∞ are the (∞,1)-categories of simplicial sets and commutative differential graded algebras, and give an axiomatic characterization of this functor. From the axioms, we deduce several properties and computational tools for this functor. We study the relationship between the higher Hochschild functor and factorization algebras by showing that, in good cases, the Hochschild functor determines a constant commutative factorization algebra. Conversely, every constant commutative factorization algebra is naturally equivalent to a Hochschild chain factorization algebra. Similarly, we study the relationship between the above concepts and topological chiral homology. In particular, we show that on their common domains of definition, the higher Hochschild functor is naturally equivalent to topological chiral homology. Finally, we prove that topological chiral homology determines a locally constant factorization algebra and, further, that this functor induces an equivalence between locally constant factorization algebras on a manifold and (local system of) E n -algebras. 相似文献
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Letters in Mathematical Physics - Let M be a differential manifold. Using different methods, Kontsevich and Tamarkin have proved a formality theorem, which states the existence of a Lie... 相似文献
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Gré gory Ginot Gilles Halbout 《Proceedings of the American Mathematical Society》2006,134(3):621-630
Let be the Hochschild complex of cochains on and let be the space of multivector fields on . In this paper we prove that given any -structure (i.e. Gerstenhaber algebra up to homotopy structure) on , and any -morphism (i.e. morphism of a commutative, associative algebra up to homotopy) between and , there exists a -morphism between and that restricts to . We also show that any -morphism (i.e. morphism of a Lie algebra up to homotopy), in particular the one constructed by Kontsevich, can be deformed into a -morphism, using Tamarkin's method for any -structure on . We also show that any two of such -morphisms are homotopic.
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Chauvin AS Frapart YM Vaissermann J Donnadieu B Tuchagues JP Chottard JC Li Y 《Inorganic chemistry》2003,42(6):1895-1900
A new tripod N(3) ligand (L), containing three imidazole rings, was synthesized in good yield. At variance with usual aromatic ligands with N(2) or N(3) donor sets such as pyridine or pyrazole derivatives, L stabilizes the Fe(III) oxidation state. The corresponding iron(III) complexes [Fe(L)Cl(3)] (1) and [Fe(L)(2)](ClO(4))(3) (2) were prepared and characterized by X-ray structural analysis and spectroscopic methods. The coordination environment around all the Fe(III) centers has a distorted octahedral geometry. [Fe(L)Cl(3)] (1) belongs to the monoclinic system, space group P2(1)/n, a = 9.7406(5) A, b = 17.207(2) A, c = 14.615(2) A, beta = 104.448(9)(o) Z = 4, V = 2372.1(4) A(3); R = 0.044, R(w) = 0.055. [Fe(L)(2)](ClO(4))(3) (2) belongs to the monoclinic system, space group P2(1)/c, a = 16.1057(15) A, b = 11.1079(12) A, c = 26.283(2) A, beta = 102.062(10)(o), Z = 4, V = 4598.2(8) A(3); R = 0.0465, R(w) = 0.0902. The Fe-N((i)PrIm) bond lengths are systematically longer than the Fe-N(MeIm) ones. Compound 2 is a highly anisotropic low-spin Fe(III) complex displaying a rather unusual EPR spectrum with a sharp signal at g = 3.5 and a broad one at g approximately 1.6. The fitting of this EPR spectrum is discussed. 相似文献
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